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arXiv:2206.00704 · Physical Review Letters

Emergence of Fermi’s Golden Rule

Tobias Micklitz, Alan Morningstar, Alexander Altland, David A. Huse

Published Sep 27, 2022• 31 citations
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Abstract

Fermi's golden rule applies in the limit where an initial quantum state is weakly coupled to a continuum of other final states overlapping its energy. Here we investigate what happens away from this limit, where the set of final states is discrete, with a nonzero mean level spacing; this question arises in a number of recently investigated many-body systems. For different symmetry classes, we analytically and/or numerically calculate the universal crossovers in the average decay of the initial state as the level spacing is varied, with the golden rule emerging in the limit of a continuum. Among the corrections to the exponential decay of the initial state given by Fermi's golden rule is the appearance of the spectral form factor in the longtime regime for small but nonzero level spacing.

DOI
10.1103/physrevlett.129.140402

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Fermi's golden rule applies in the limit where an initial quantum state is weakly coupled to a continuum of other final states overlapping its energy. Here we investigate what happens away from this limit, where the set of final states is discrete, with a nonzero mean level spacing; this question arises in a number of recently investigated many-body systems. For different symmetry classes, we analytically and/or numerically calculate the universal crossovers in the average decay of the initial state as the level spacing is varied, with the golden rule emerging in the limit of a continuum. Among the corrections to the exponential decay of the initial state given by Fermi's golden rule is the appearance of the spectral form factor in the longtime regime for small but nonzero level spacing.
Abstract Fermi's Golden Rule is one of the most important results in quantum mechanics, predicting transition rates in applications ranging from beta decay to optical transitions, autoionization and photoionization. Most textbooks derive the Golden Rule only for the canonical case of a discrete state coupled by a time-independent perturbation to a continuum of final states. Here we present a unified treatment of several physical situations, including light absorption in atoms and solids, that all lead to the same Golden Rule expression. The essential ingredients are the transition matrix element and a spectral weighting function, whose physical origin need not be the density of final states, nor necessarily anything to do with the matter.The conventional discrete-to-continuum derivation introduces pedagogical complications associated with continuum normalization and the interpretation of the density of states. Among the cases considered here, the derivation for discrete transitions driven by a noisy perturbation is no more difficult mathematically but conceptually clearer, while leading directly to practical calculations. This suggests that it provides a more natural first introduction to the Golden Rule, with conventional continuum derivations better viewed later as another realization of the same underlying mathematical structure, rather than the other way around.
Abstract Fermi’s golden rule is of great importance in quantum dynamics. However, in many textbooks on quantum mechanics, its contents and limitations are obscured by the approximations and arguments in the derivation, which are inevitable because of the generic setting considered. Here we propose to introduce it by an ideal model, in which the quasi-continuum band consists of equaldistant levels extending from − ∞ to + ∞ , and each of them couples to the discrete level with the same strength. For this model, the transition probability in the first order perturbation approximation can be calculated analytically by invoking the Poisson summation formula. It turns out to be a piecewise linear function of time, demonstrating on the one hand the key features of Fermi’s golden rule, and on the other hand that the rule breaks down beyond the Heisenberg time , even when the first order perturbation approximation itself is still valid.
Many problems in quantum dynamics can be cast as the decay of a single quantum state into a continuum. The time-dependent overlap with the initial state, called the fidelity, characterizes this decay. We derive an analytic expression for the fidelity after a quench to an ergodic Hamiltonian. The expression is valid for both weak and strong quenches, and timescales before finiteness of the Hilbert space limits the fidelity. It reproduces initial quadratic decay and asymptotic exponential decay with a rate which, for strong quenches, differs from Fermi’s golden rule. The analysis relies on the statistical Jacobi approximation (SJA), which was originally applied in nearly localized systems, and which we here adapt to well-thermalizing systems. Our results demonstrate that the SJA is predictive in disparate regimes of quantum dynamics.
A simple quantum mechanical model consisting of a discrete level resonantly coupled to a continuum of finite width, where the coupling can be varied from perturbative to strong (Fano-Anderson model), is considered. The particle is initially localized at the discrete level, and the time dependence of the amplitude to find the particle at the discrete level is calculated without resorting to perturbation theory. The deviations from the exponential decay law, predicted by the Fermi's Golden Rule, are discussed. We also study analytic structure of the Green's function (GF) for the model. We analyze the GF poles, branch points and Riemann surface, and show how the Fermi's Golden Rule, valid in perturbative regime for not to large time, appears in this context. The knowledge of analytic structure of the GF in frequency representation opens opportunities for obtaining easy for numerical calculations formulas for the GF in time representation, alternative to those using the spectral density.
A simple analysis of the bound-free system shows that for a narrow continuum the Fermi golden rule can be generalised for the high-intensity regime. This generalisation has the form of a simple expression for the decay rate and helps to explain nearly perfect population trapping in the case of a narrowly peaked matrix element. Such population trapping means that the decay rate of a bound state strongly coupled to a continuum tends to zero for increasing coupling strength only if the matrix element falls off faster than the Lorentzian. The authors also find new solutions for pulsed excitation giving exact population trapping in the bound-free transition.
A quantum mechanical wave of a finite size moves like a classical particle and shows a unique decay probability. Because the wave function evolves according to the Schrodinger equation, it preserves the total energy but not the kinetic energy in the intermediate-time region of a decay process where those of the parent and daughters overlap. The decay rate computed with Fermi's golden rule requires corrections that vary with the distance between the initial and final states, and the energy distribution of the daughter is distorted from that of plane waves. The corrections have universal properties in relativistically invariant systems and reveal macroscopic quantum phenomena for light particles. The implications for precision experiments in beta decays and various radiative transitions are presented.