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arXiv:2205.13089 · Physical Review Letters

Demonstrating Quantum Microscopic Reversibility Using Coherent States of Light

Marco Bellini, Hyukjoon Kwon, Nicola Biagi, Saverio Francesconi, Alessandro Zavatta, M. S. Kim

Published Oct 20, 2022• 10 citations
arXivHTMLPDF

Abstract

The principle of microscopic reversibility lies at the core of fluctuation theorems, which have extended our understanding of the second law of thermodynamics to the statistical level. In the quantum regime, however, this elementary principle should be amended as the system energy cannot be sharply determined at a given quantum phase space point. In this Letter, we propose and experimentally test a quantum generalization of the microscopic reversibility when a quantum system interacts with a heat bath through energy-preserving unitary dynamics. Quantum effects can be identified by noting that the backward process is less likely to happen in the existence of quantum coherence between the system's energy eigenstates. The experimental demonstration has been realized by mixing coherent and thermal states in a beam splitter, followed by heterodyne detection in an optical setup. We verify that the quantum modification for the principle of microscopic reversibility is critical in the low-temperature limit, while the quantum-to-classical transition is observed as the temperature of the thermal field gets higher.

DOI
10.1103/physrevlett.129.170604

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The principle of microscopic reversibility lies at the core of fluctuation theorems, which have extended our understanding of the second law of thermodynamics to the statistical level. In the quantum regime, however, this elementary principle should be amended as the system energy cannot be sharply determined at a given quantum phase space point. In this Letter, we propose and experimentally test a quantum generalization of the microscopic reversibility when a quantum system interacts with a heat bath through energy-preserving unitary dynamics. Quantum effects can be identified by noting that the backward process is less likely to happen in the existence of quantum coherence between the system's energy eigenstates. The experimental demonstration has been realized by mixing coherent and thermal states in a beam splitter, followed by heterodyne detection in an optical setup. We verify that the quantum modification for the principle of microscopic reversibility is critical in the low-temperature limit, while the quantum-to-classical transition is observed as the temperature of the thermal field gets higher.
The principle of microscopic reversibility is a fundamental element in the formulation of fluctuation relations and Onsager reciprocal relations. As such, a clear description of whether and how this principle is adapted to the quantum-mechanical scenario might be essential for a better understanding of nonequilibrium quantum processes. Here, we propose a quantum generalization of this principle which highlights the role played by coherence in the symmetry relations involving the probability of observing a quantum transition and that of the corresponding time-reversed process. We study the implications of our findings in the framework of a qubit system interacting with a thermal reservoir and implement an optical experiment that simulates the dynamics. Our theoretical and experimental results show that the influence of coherence is more decisive at low temperatures and that the maximum departure from the classical case does not take place for maximally coherent states. Classical predictions are recovered in the appropriate limits.
Abstract Fluctuation theorems (FT) reveal crucial properties about the nature of non-equilibrium dynamics by constraining the statistical distribution of quantities such as heat, work and entropy production. Here, we report theoretical and experimental results regarding two FT for a new quantity, named coherent energy, which is an energy form directly associated with the coherences of a quantum state. The FT are verified using the two-point measurement protocol with an all-optical setup in which the system information is encoded in the polarization of one photon of a pair. From the outcomes of our experiment we directly assess the energy probability distributions. We also demonstrate an universal bound on the energy of thermal states under the action of unitary operations, which could be the first step to establish an arrow of time for reversible processes.
The second law of thermodynamics dictates that heat flows spontaneously from a high-temperature entity to a lower-temperature one. Yet, recent advances have demonstrated that quantum correlations between a system and its thermal environment can induce a reversal of heat flow, challenging classical thermodynamic expectations. Here, we experimentally demonstrate that internal quantum coherence in a multipartite spin system can also reverse heat flow, without relying on initial correlations with the environment. Under the collision model with cascade interaction, we verify that both the strength and the phase of the coherence term determine the direction and magnitude of energy transfer. These results enable precise control of heat flow using only local quantum properties.
The second law of thermodynamics dictates that heat flows spontaneously from a high-temperature entity to a lower-temperature one. Yet, recent advances have demonstrated that quantum correlations between a system and its thermal environment can induce a reversal of heat flow, challenging classical thermodynamic expectations. Here, we experimentally demonstrate that internal quantum coherence in a multipartite spin system can also reverse heat flow, without relying on initial correlations with the environment. Under the collision model with cascade interaction, we verify that both the strength and the phase of the coherence term determine the direction and magnitude of energy transfer. These results enable precise control of heat flow using only local quantum properties.
We prove the second law of thermodynamics and the nonequilibrium fluctuation theorem for pure quantum states. The entire system obeys reversible unitary dynamics, where the initial state of the heat bath is not the canonical distribution but is a single energy eigenstate that satisfies the eigenstate-thermalization hypothesis. Our result is mathematically rigorous and based on the Lieb-Robinson bound, which gives the upper bound of the velocity of information propagation in many-body quantum systems. The entanglement entropy of a subsystem is shown connected to thermodynamic heat, highlighting the foundation of the information-thermodynamics link. We confirmed our theory by numerical simulation of hard-core bosons, and observed dynamical crossover from thermal fluctuations to bare quantum fluctuations. Our result reveals a universal scenario that the second law emerges from quantum mechanics, and can be experimentally tested by artificial isolated quantum systems such as ultracold atoms.
Fluctuation theorems have elevated the second law of thermodynamics to a statistical realm by establishing a connection between time-forward and time-reversal probabilities, providing invaluable insight into nonequilibrium dynamics. While well established in classical systems, their quantum generalization, incorporating coherence and the diversity of quantum noise, remains open. We report the experimental validation of a quantum fluctuation theorem (QFT) in a photonic system, applicable to general quantum processes with nonclassical characteristics, including quasi-probabilistic descriptions of entropy production and multiple time-reversal processes. Our experiment confirms that the ratio between the quasi-probabilities of the time-forward and any multiple time-reversal processes obeys a generalized Crooks QFT. Moreover, coherence induced by a quantum process leads to the imaginary components of quantum entropy production, governing the phase factor in the QFT. These findings underscore the fundamental symmetry between a general quantum process and its time reversal, providing an elementary toolkit to explore noisy quantum information processing.