Quantum simulators have recently enabled experimental observations of the internal thermalization of quantum many-body systems.Often, the global energy and particle number are conserved and the system is prepared with a well-defined particle number-in a microcanonical subspace.However, quantum evolution can also conserve quantities, or charges, that fail to commute with each other.Noncommuting charges have recently emerged as a subfield at the intersection of quantum thermodynamics and quantum information.Until now, this subfield has remained theoretical.We initiate the experimental testing of its predictions, with a trapped-ion simulator.We prepare 6-21 spins in an approximate microcanonical subspace, a generalization of the microcanonical subspace for accommodating noncommuting charges, which cannot necessarily have well-defined nontrivial values simultaneously.We simulate a Heisenberg evolution using laser-induced entangling interactions and collective spin rotations.The noncommuting charges are the three spin components.We find that small subsystems equilibrate to near a recently predicted non-Abelian thermal state.This work bridges quantum many-body simulators to the quantum thermodynamics of noncommuting charges, the predictions of which can now be tested.
Quantum simulators have recently enabled experimental observations of the internal thermalization of quantum many-body systems.Often, the global energy and particle number are conserved and the system is prepared with a well-defined particle number-in a microcanonical subspace.However, quantum evolution can also conserve quantities, or charges, that fail to commute with each other.Noncommuting charges have recently emerged as a subfield at the intersection of quantum thermodynamics and quantum information.Until now, this subfield has remained theoretical.We initiate the experimental testing of its predictions, with a trapped-ion simulator.We prepare 6-21 spins in an approximate microcanonical subspace, a generalization of the microcanonical subspace for accommodating noncommuting charges, which cannot necessarily have well-defined nontrivial values simultaneously.We simulate a Heisenberg evolution using laser-induced entangling interactions and collective spin rotations.The noncommuting charges are the three spin components.We find that small subsystems equilibrate to near a recently predicted non-Abelian thermal state.This work bridges quantum many-body simulators to the quantum thermodynamics of noncommuting charges, the predictions of which can now be tested.
In statistical mechanics, a small system exchanges conserved quantities-heat, particles, electric charge, etc.-with a bath. The small system thermalizes to the canonical ensemble or the grand canonical ensemble, etc., depending on the quantities. The conserved quantities are represented by operators usually assumed to commute with each other. This assumption was removed within quantum-information-theoretic (QI-theoretic) thermodynamics recently. The small system's long-time state was dubbed "the non-Abelian thermal state (NATS)." We propose an experimental protocol for observing a system thermalize to the NATS. We illustrate with a chain of spins, a subset of which forms the system of interest. The conserved quantities manifest as spin components. Heisenberg interactions push the conserved quantities between the system and the effective bath, the rest of the chain. We predict long-time expectation values, extending the NATS theory from abstract idealization to finite systems that thermalize with finite couplings for finite times. Numerical simulations support the analytics: The system thermalizes to near the NATS, rather than to the canonical prediction. Our proposal can be implemented with ultracold atoms, nitrogen-vacancy centers, trapped ions, quantum dots, and perhaps nuclear magnetic resonance. This work introduces noncommuting conserved quantities from QI-theoretic thermodynamics into quantum many-body physics: atomic, molecular, and optical physics and condensed matter.
The eigenstate thermalization hypothesis (ETH) explains why nonintegrable quantum many-body systems thermalize internally if the Hamiltonian lacks symmetries. If the Hamiltonian conserves one quantity ("charge"), the ETH implies thermalization within a charge sector-in a microcanonical subspace. But quantum systems can have charges that fail to commute with each other and so share no eigenbasis; microcanonical subspaces may not exist. Furthermore, the Hamiltonian will have degeneracies, so the ETH need not imply thermalization. We adapt the ETH to noncommuting charges by positing a non-Abelian ETH and invoking the approximate microcanonical subspace introduced in quantum thermodynamics. Illustrating with SU(2) symmetry, we apply the non-Abelian ETH in calculating local operators' time-averaged and thermal expectation values. In many cases, we prove, the time average thermalizes. However, we find cases in which, under a physically reasonable assumption, the time average converges to the thermal average unusually slowly as a function of the global-system size. This work extends the ETH, a cornerstone of many-body physics, to noncommuting charges, recently a subject of intense activity in quantum thermodynamics.
Abstract Noncommuting conserved quantities have recently launched a subfield of quantum thermodynamics. In conventional thermodynamics, a system of interest and an environment exchange quantities—energy, particles, electric charge, etc.—that are globally conserved and are represented by Hermitian operators. These operators were implicitly assumed to commute with each other, until a few years ago. Freeing the operators to fail to commute has enabled many theoretical discoveries—about reference frames, entropy production, resource-theory models, etc. Little work has bridged these results from abstract theory to experimental reality. This paper provides a methodology for building this bridge systematically: we present a prescription for constructing Hamiltonians that conserve noncommuting quantities globally while transporting the quantities locally. The Hamiltonians can couple arbitrarily many subsystems together and can be integrable or nonintegrable. Our Hamiltonians may be realized physically with superconducting qudits, with ultracold atoms, and with trapped ions.
We extend entropy production to a deeply quantum regime involving noncommuting conserved quantities. Consider a unitary transporting conserved quantities (“charges”) between two systems initialized in thermal states. Three common formulas model the entropy produced. They respectively cast entropy as an extensive thermodynamic variable, as an information-theoretic uncertainty measure, and as a quantifier of irreversibility. Often, the charges are assumed to commute with each other (e.g., energy and particle number). Yet quantum charges can fail to commute. Noncommutation invites generalizations, which we posit and justify, of the three formulas. The noncommutation of charges, we find, breaks the equivalence of the formulas. Furthermore, different formulas quantify different physical effects of the noncommutation of charges on entropy production. For instance, entropy production can signal contextuality—true nonclassicality—by becoming nonreal. This work opens up stochastic thermodynamics to noncommuting—and so particularly quantum—charges. Published by the American Physical Society 2024
Studying noncommuting conserved quantities, or ‘charges,’ has revealed a conceptual puzzle: noncommuting charges hinder thermalization in some ways yet promote it in others. While many quantum systems thermalize according to the Eigenstate Thermalization Hypothesis (ETH), systems with ‘dynamical symmetries’ violate the ETH and exhibit non-stationary dynamics, preventing them from equilibrating, much less thermalizing. We demonstrate that each pair of dynamical symmetries corresponds to a specific charge. We find that introducing new charges that do not commute with existing ones disrupts these symmetries, thereby eliminating non-stationary dynamics and facilitating thermalization. We illustrate this behavior across various models, including the Hubbard model and Heisenberg spin chains. Our findings demonstrate that noncommuting charges can enhance thermalization by reducing the number of local observables that thermalize according to the ETH. Noncommuting charges pose a puzzle: they hinder thermalization in some ways yet promote it in others. Here, the authors demonstrate how noncommuting charges enhance thermalization by reducing the number of local observables that thermalize.
The grand canonical ensemble lies at the core of quantum and classical statistical mechanics. A small system thermalizes to this ensemble while exchanging heat and particles with a bath. A quantum system may exchange quantities represented by operators that fail to commute. Whether such a system thermalizes and what form the thermal state has are questions about truly quantum thermodynamics. Here we investigate this thermal state from three perspectives. First, we introduce an approximate microcanonical ensemble. If this ensemble characterizes the system-and-bath composite, tracing out the bath yields the system's thermal state. This state is expected to be the equilibrium point, we argue, of typical dynamics. Finally, we define a resource-theory model for thermodynamic exchanges of noncommuting observables. Complete passivity-the inability to extract work from equilibrium states-implies the thermal state's form, too. Our work opens new avenues into equilibrium in the presence of quantum noncommutation.