Quantum impurities exhibit fascinating many-body phenomena when the small interacting impurity changes the physics of a large noninteracting environment. The characterisation of such strongly correlated nonperturbative effects is particularly challenging due to the infinite size of the environment, and the inability of local correlators to capture the buildup of long-ranged entanglement in the system. Here, we harness an entanglement-based observable---the purity of the impurity---as a witness for the formation of strong correlations. We showcase the utility of our scheme by exactly solving the open Kondo box model in the small box limit, and thus describe all-electronic dot-cavity devices. Specifically, we conclusively characterize the metal-to-insulator phase transition in the system and identify how the (conducting) dot-lead Kondo singlet is quenched by an (insulating) intraimpurity singlet formation. Furthermore, we propose an experimentally feasible tomography protocol for the measurement of the purity, which motivates the observation of impurity physics through their entanglement build up.
Quantum impurities exhibit fascinating many-body phenomena when the small interacting impurity changes the physics of a large noninteracting environment. The characterisation of such strongly correlated nonperturbative effects is particularly challenging due to the infinite size of the environment, and the inability of local correlators to capture the buildup of long-ranged entanglement in the system. Here, we harness an entanglement-based observable---the purity of the impurity---as a witness for the formation of strong correlations. We showcase the utility of our scheme by exactly solving the open Kondo box model in the small box limit, and thus describe all-electronic dot-cavity devices. Specifically, we conclusively characterize the metal-to-insulator phase transition in the system and identify how the (conducting) dot-lead Kondo singlet is quenched by an (insulating) intraimpurity singlet formation. Furthermore, we propose an experimentally feasible tomography protocol for the measurement of the purity, which motivates the observation of impurity physics through their entanglement build up.
Quantum dots exhibit a variety of strongly correlated effects, e.g., when tuned to emulate localized magnetic impurities that form a Kondo singlet with their surrounding environment. Interestingly, in double-dots setups, the magnetic impurities couple to each other by direct Ruderman-Kittel-Kasuya-Yosida (RKKY) interaction, which wins over the Kondo physics. In this work, we investigate a double-dot device where the dots are coupled via off-resonant ballistic whispering gallery modes, dubbed electronic cavity modes. Within this cavity-double-dot system, we study, using variational matrix product state techniques, the competition between Kondo formation and the coherent RKKY-like interaction that the cavity facilitates. Specifically, we find that (i) Kondo can win and form on each dot individually, or (ii) the cavity can win and mediate between the two dots either a singlet or a novel nonlocal Kondo-like effect phase, which we call "cat Kondo". We systematically study the quantum phase transitions between the different many-body states. Our discoveries lay the foundation for the experimental observation of unconventional nonlocal magnetic impurities.
Quantum dots exhibit a variety of strongly correlated effects, e.g., they can emulate localized magnetic impurities that form a Kondo singlet with their surrounding environment. Interestingly, in double-dot setups, such magnetic impurities couple to each other by direct Ruderman-Kittel-Kasuya-Yosida (RKKY) interaction, which wins over the Kondo physics. In this work, we investigate a double-dot device where the dots are coupled via off-resonant ballistic modes, dubbed electronic cavity modes. Within this cavity-double-dot system, we study, using variational matrix product state techniques, the competition between Kondo formation and the combined coherent orbital hybridization and RKKY-like interaction that the cavity facilitates. Specifically, we find that Kondo can form on each dot individually whereby the cavity can either (i) destroy the Kondo via the RKKY that mediates a singlet state on the two dots, or (ii) lead to an exotic orbital macrsoscopic superposition of the Kondo forming on each of the dots. We dub the latter “Kondo cat”. En route to this key finding, we rigorously study the many-body phase diagram of the system, as well as compare it with the case of coupling the dots via an incoherent RKKY channel. The realization of a Kondo cat can facilitate applications in metrology, and reveal the spin coherence length in mesoscopic devices. Published by the American Physical Society 2024
Quantum impurity models are a fundamental paradigm in the study of many-body quantum matter. They describe metals with actual magnetic impurities, quantum circuits with quantum dots, and are the local effective theories within dynamical mean field theory for correlated materials. They have gained prominence in recent years as a platform for treating non-Markovian open quantum systems exactly in strong coupling, and as a means for accurate simulations of quantum nanoelectronics devices. The work presented in this thesis focuses on the characterization of quantum matter through this lens. Two recurring themes are characterizing systems by their entropy signatures, and through their quench dynamics. Firstly, we investigate the non-equilibrium physics of an interacting quantum dot circuit following a sudden, externally-driven change in the dot potential. We do this by mapping the interacting problem onto a simpler Gaussian theory, which we show is exact for single-particle dynamics in equilibrium. Perhaps surprisingly, we establish that such a mapping is still possible following a quench; although this comes at the cost of numerical optimization of the effective non-interacting auxiliary fermion problem, starting from a tensor network treatment. The method provides a new way of viewing impurity quench dynamics. Secondly, we focus on entropy measurements in quantum dot circuits using a charge sensor. The equilibrium thermodynamic entropy can be extracted from such charge measurements by local Maxwell relations, and we study this connection in detail for a variety of experimentally-relevant quantum nanoelectronic device models, uncovering their entropic phase diagram. The underlying quantum impurity models are solved exactly using numerical renormalization group methods. We extend this to lattice models describing interacting materials, showing that the Maxwell relations provide a route to calculate the lattice entropy and give new physical insights. We go on to consider entropy production in the non-equilibrium setting of a quench, again showing that this can be related to practical charge measurements. In quantum circuit experiments, the dot charge is measured in practice using a secondary, capacitively coupling charge-sensor circuit. We investigate this by explicitly modelling the device together with the charge-sensor in a fully quantum mechanical treatment. This allows us to understand and quantify the measurement backaction. It also allows us to establish when the assumptions underpinning the Maxwell entropy extraction hold. Finally, we consider the strongly correlated electron physics of bilayer Hubbard models within dynamical mean field theory. Such models capture the essence of interface physics in heterostructures. In the basic bilayer, we revisit the phase diagram and study the change in character of the metal-insulator transition from continuous band-insulator gap opening to Mott quasiparticle collapse, as a function of interlayer coupling and local Coulomb interaction strength. For more complex interfaces involving additional correlated sites between layers, many-body quantum interference can be tuned, leading to different types of transition. While a pure impurity model version of this system features a second-order non-Fermi liquid Kondo critical point, full self-consistency on the lattice turns the transition first-order.
Entanglement is a defining feature of quantum mechanics, and its relation to quantum criticality is of considerable current interest. Here we show that measurable spin and charge fluctuations provide an entanglement witness of quantum criticality in the two-impurity Kondo model, which has experimental realizations in terms of coupled quantum dots and magnetic impurities added to surfaces. We use density-matrix renormalization group and numerical renormalization group calculations to resolve the non-Fermi-liquid critical point separating two independently Kondo-screened impurities from an inter-impurity singlet and interpret it as a change in the dominant entanglement partner of each local moment: from entanglement of the local moment with an extended set of conduction-electron degrees of freedom to entanglement with the other impurity. This reorganization is accompanied by a singular response of the impurity-bath entanglement and the inter-impurity susceptibility. We show how the same structure is encoded in the quantum Fisher information of collective spin and charge operators at zero and finite temperatures, connecting the entanglement picture to experimentally accessible dynamical response functions. Our results establish impurity systems as controlled settings in which quantum-critical entanglement can be detected through measurable correlations, and provide further insight into the possibility of understanding heavy-fermion physics in terms of entanglement.
Generalized quantum impurity models—which feature a few localized and strongly correlated degrees of freedom coupled to itinerant conduction electrons—describe diverse physical systems, from magnetic moments in metals to nanoelectronics quantum devices such as quantum dots or single-molecule transistors. Correlated materials can also be understood as self-consistent impurity models through dynamical mean-field theory. Accurate simulation of such models is challenging, especially at low temperatures, due to many-body effects from electronic interactions, resulting in strong renormalization. In particular, the interplay between local impurity complexity and Kondo physics is highly nontrivial. A common approach, which we further develop in this work, is to consider instead a simpler effective impurity model that still captures the low-energy physics of interest. The mapping from a bare to an effective model is typically done perturbatively, but even this can be difficult for complex systems, and the resulting effective model parameters can nevertheless be quite inaccurate. Here we develop a nonperturbative, unsupervised machine learning approach to systematically obtain low-energy effective impurity-type models, based on the renormalization-group framework. The method is shown to be general and flexible, as well as accurate and systematically improvable. We benchmark the method against exact results for the Anderson impurity model, and we provide an outlook for more complex models beyond the reach of existing methods. Published by the American Physical Society 2024
The Kondo effect, a hallmark of strong correlation physics, is characterized by the formation of an extended cloud of singlet states around magnetic impurities at low temperatures. While many implications of the Kondo cloud's existence have been verified, the existence of the singlet cloud itself has not been directly demonstrated. We suggest a route for such a demonstration by considering an observable that has no classical analog, but is still experimentally measurable: ``singlet weights'', or projections onto particular entangled two-particle states. Using approximate theoretical arguments, we show that it is possible to construct highly specific energy- and position-resolved probes of Kondo correlations. Furthermore, we consider a quantum transport setup that can be driven away from equilibrium by a bias voltage. There, we show that singlet weights are enhanced by voltage even as the Kondo effect is weakened by it. This exposes a patently nonequilibrium mechanism for the generation of Kondo-like entanglement that is inherently different from its equilibrium counterpart.