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arXiv:2112.15212 · Physica Scripta

Exact time-dependent solution of the Schrödinger equation, its generalization to the phase space and relation to the Gibbs distribution

E. E. Perepelkin, Б. И. Садовников, Наталья Германовна Иноземцева, I. I. Aleksandrov

Published Dec 13, 2022• 9 citations
arXivHTMLPDF

Abstract

Abstract Using the simplest but fundamental example, the problem of the infinite potential well, this paper makes an ideological attempt (supported by rigorous mathematical proofs) to approach the issue of ≪understanding≫ the mechanism of quantum mechanics processes, despite the well-known examples of the EPR paradox type. The new exact solution of the Schrödinger equation is analyzed from the perspective of quantum mechanics in the phase space. It is the phase space, which has been extensively used recently in quantum computing, quantum informatics and communications, that is the bridge towards classical physics, where understanding of physical reality is still possible. In this paper, an interpretation of time-dependent processes of energy redistribution in a quantum system, probability waves, the temperature and entropy of a quantum system, and the transition to a time-independent ≪frozen state≫ is obtained, which is understandable from the point of view of classical physics. The material of the paper clearly illustrates the solution of the problem from the standpoint of continuum mechanics, statistical physics and, of course, quantum mechanics in the phase space.

DOI
10.1088/1402-4896/acab39

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Abstract Using the simplest but fundamental example, the problem of the infinite potential well, this paper makes an ideological attempt (supported by rigorous mathematical proofs) to approach the issue of ≪understanding≫ the mechanism of quantum mechanics processes, despite the well-known examples of the EPR paradox type. The new exact solution of the Schrödinger equation is analyzed from the perspective of quantum mechanics in the phase space. It is the phase space, which has been extensively used recently in quantum computing, quantum informatics and communications, that is the bridge towards classical physics, where understanding of physical reality is still possible. In this paper, an interpretation of time-dependent processes of energy redistribution in a quantum system, probability waves, the temperature and entropy of a quantum system, and the transition to a time-independent ≪frozen state≫ is obtained, which is understandable from the point of view of classical physics. The material of the paper clearly illustrates the solution of the problem from the standpoint of continuum mechanics, statistical physics and, of course, quantum mechanics in the phase space.
Abstract After revisiting the time-dependent Schrödinger equation and introducing the Hamiltonian operator, the time-independent Schrödinger equation (TISE) is obtained. Conditions on acceptable wavefunctions are then stated. The method for solution of the TISE is laid out, and the infinite potential well is solved as an example. A discussion of the physical interpretation of the solutions — as energy eigenstates in position space — follows. This provides an opportunity to introduce overall and relative phases, and to point out that the latter are responsible for time evolution. The TISE is then applied to the important problems of scattering from a step potential and tunneling through a rectangular potential barrier. Use of the TISE for such problems greatly simplifies calculations, but it can also instill misconceptions; both aspects are discussed.
The paper addresses the problem, which quantum mechanics resolves in fact. Its viewpoint suggests that the crucial link of time and its course is omitted in understanding the problem. The common interpretation underlain by the history of quantum mechanics sees discreteness only on the Plank scale, which is transformed into continuity and even smoothness on the macroscopic scale. That approach is fraught with a series of seeming paradoxes. It suggests that the present mathematical formalism of quantum mechanics is only partly relevant to its problem, which is ostensibly known. The paper accepts just the opposite: The mathematical solution is absolute relevant and serves as an axiomatic base, from which the real and yet hidden problem is deduced. Wave-particle duality, Hilbert space, both probabilistic and many-worlds interpretations of quantum mechanics, quantum information, and the Schrödinger equation are included in that base. The Schrödinger equation is understood as a generalization of the law of energy conservation to past, present, and future moments of time. The deduced real problem of quantum mechanics is: “What is the universal law describing the course of time in any physical change therefore including any mechanical motion?”
The paper addresses the problem, which quantum mechanics resolves in fact. Its viewpoint suggests that the crucial link of time and its course is omitted in understanding the problem. The common interpretation underlain by the history of quantum mechanics sees discreteness only on the Plank scale, which is transformed into continuity and even smoothness on the macroscopic scale. That approach is fraught with a series of seeming paradoxes. It suggests that the present mathematical formalism of quantum mechanics is only partly relevant to its problem, which is ostensibly known. The paper accepts just the opposite: The mathematical solution is absolute relevant and serves as an axiomatic base, from which the real and yet hidden problem is deduced. Wave-particle duality, Hilbert space, both probabilistic and many-worlds interpretations of quantum mechanics, quantum information, and the Schrödinger equation are included in that base. The Schrödinger equation is understood as a generalization of the law of energy conservation to past, present, and future moments of time. The deduced real problem of quantum mechanics is: “What is the universal law describing the course of time in any physical change therefore including any mechanical motion?”
The paper addresses the problem, which quantum mechanics resolves in fact. Its viewpoint suggests that the crucial link of time and its course is omitted in understanding the problem. The common interpretation underlain by the history of quantum mechanics sees discreteness only on the Plank scale, which is transformed into continuity and even smoothness on the macroscopic scale. That approach is fraught with a series of seeming paradoxes. It suggests that the present mathematical formalism of quantum mechanics is only partly relevant to its problem, which is ostensibly known. The paper accepts just the opposite: The mathematical solution is absolute relevant and serves as an axiomatic base, from which the real and yet hidden problem is deduced. Wave-particle duality, Hilbert space, both probabilistic and many-worlds interpretations of quantum mechanics, quantum information, and the Schrödinger equation are included in that base. The Schrödinger equation is understood as a generalization of the law of energy conservation to past, present, and future moments of time. The deduced real problem of quantum mechanics is: “What is the universal law describing the course of time in any physical change therefore including any mechanical motion?”
In spite of outstanding achievement of the quantum theory, the theory is under never-ending judgment due to probabilistic character and certain unresolved paradoxes arising from the very fundamentals. Additionally, it is debated that a more sophisticated theory beyond the quantum theory emerges as a need for a better understanding of the atomic and sub atomic worlds. This paper, for that reason, focuses on the very fundamental structure of the quantum theory such as the physical and philosophical meanings of the wave functions, the probability and the Schrödinger Wave Equation (SWE). Specifically deals with the time evolution of the free quantum particles. The work just arises from the difference of the classical and quantum waves, specifically the comparison of the time and space dependence of classical waves and Schrödinger waves, for the free space, indicates that time dependence shows a clear dissimilarity. In order to tackle the problem, a time dependent momentum operator, for the first time, is defined and consequently an alternative TDSWE is straightforwardly derived and its philosophical implications have been discussed. Additionally, time and position dependence of the probability functions, relating free particles, have been physically and philosophically discussed and some alternative approaches and comments are forwarded. Finally, the approaches, comments and mathematical equations are in good agreement with the standard quantum theory and interestingly go further possibly tracing some signs of new pathways to resolve the mysterious quantum world. Keywords: Schrödinger wave equation, fundamentals of quantum mechanics, momentum operator, quantum probabilities, time evolution of quantum systems.
A possible generalization of quantum mechanics is examined by showing that the motion in phase space of a classical Brownian particle may be described by a complex probability amplitude depending on the phase-space coordinates and the time, and obeying a Schrödinger-like equation. However formal this result may seem, the usual dynamical operators may be defined whose physical meaning stems directly from the theory. An outstanding feature of the formalism is that ordinary quantum mechanics in configuration space may be recovered in a limiting process whereby the velocity variable, defined now through a statistical distribution, is eliminated. Therefore, it plays the role of a hidden variable. This result supports recent reinterpretations of von Neumann's theorem on the nonexistence of such variables in quantum mechanics and serves as a counterexample of the usual interpretation of his theorem.