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arXiv:2112.01962

Thermodynamic length and work optimisation for Gaussian quantum states

Mohammad Mehboudi, Harry J. D. Miller

Published Dec 3, 2021• 0 citations
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Abstract

Constructing optimal thermodynamic processes in quantum systems relies on managing the balance between the average excess work and its stochastic fluctuations. Recently it has been shown that two different quantum generalisations of thermodynamic length can be utilised to determine protocols with either minimal excess work or minimal work variance. These lengths measure the distance between points on a manifold of control parameters, and optimal protocols are achieved by following the relevant geodesic paths given some fixed boundary conditions. Here we explore this problem in the context of Gaussian quantum states that are weakly coupled to an environment and derive general expressions for these two forms of thermodynamic length. We then use this to compute optimal thermodynamic protocols for various examples of externally driven Gaussian systems with multiple control parameters.

DOI
10.48550/arxiv.2112.01962

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Constructing optimal thermodynamic processes in quantum systems relies on managing the balance between the average excess work and its stochastic fluctuations. Recently it has been shown that two different quantum generalisations of thermodynamic length can be utilised to determine protocols with either minimal excess work or minimal work variance. These lengths measure the distance between points on a manifold of control parameters, and optimal protocols are achieved by following the relevant geodesic paths given some fixed boundary conditions. Here we explore this problem in the context of Gaussian quantum states that are weakly coupled to an environment and derive general expressions for these two forms of thermodynamic length. We then use this to compute optimal thermodynamic protocols for various examples of externally driven Gaussian systems with multiple control parameters.
Constructing optimal thermodynamic processes in quantum systems relies on managing the balance between the average excess work and its stochastic fluctuations. Recently it has been shown that two different quantum generalizations of thermodynamic length can be utilized to determine protocols with either minimal excess work or minimal work variance. These lengths measure the distance between points on a manifold of control parameters, and optimal protocols are achieved by following the relevant geodesic paths given some fixed boundary conditions. Here we explore this problem in the context of Gaussian quantum states that are weakly coupled to an environment and derive general expressions for these two forms of thermodynamic length. We then use this to compute optimal thermodynamic protocols for various examples of externally driven Gaussian systems with multiple control parameters.
The design of efficient quantum information processing will rely on optimal nonequilibrium transitions of driven quantum systems. Building on a recently developed geometric framework for computing optimal protocols for classical systems driven in finite time, we construct a general framework for optimizing the average information entropy for driven quantum systems. Geodesics on the parameter manifold endowed with a positive semidefinite metric correspond to protocols that minimize the average information entropy production in finite time. We use this framework to explicitly compute the optimal entropy production for a simple two-state quantum system coupled to a heat bath of bosonic oscillators, which has applications to quantum annealing.
The design of efficient quantum information processing will rely on optimal nonequilibrium transitions of driven quantum systems. Building on a recently-developed geometric framework for computing optimal protocols for classical systems driven in finite-time, we construct a general framework for optimizing the average information entropy for driven quantum systems. Geodesics on the parameter manifold endowed with a positive semi-definite metric correspond to protocols that minimize the average information entropy production in finite-time. We use this framework to explicitly compute the optimal entropy production for a simple two-state quantum system coupled to a heat bath of bosonic oscillators, which has applications to quantum annealing.
The second law of thermodynamics sets a lower bound on the work required to drive a system between thermal equilibrium states, with equality attained in the quasistatic limit. For finite-time processes, work in excess of this bound is inevitably dissipated, motivating the search for driving protocols that minimize this excess work. While classical stochastic systems have been extensively explored, quantum analyses remain limited and often rely on Markovian master equations valid only in the weak-coupling regime. Here, we study minimal work protocols for representative two-level systems coupled to a harmonic-oscillator bath using a numerically exact method. Inspired by known optimal solutions for Brownian oscillators, we introduce an impulse ansatz that incorporates possible boundary impulses and test it across a wide range of bath parameters. We find that impulse-like features remain nearly optimal in the quantum, non-Markovian regime at short times. We also identify cases in which the widely used Markovian master equation fails even at weak coupling, highlighting the necessity of going beyond standard approximations in the quantum regime for finite-time thermodynamic optimization.
Motivated by the need for precise, energy-efficient, and experimentally realistic quantum control protocols, we investigate the thermodynamic cost of performing quantum step-equilibration processes under the influence of classical stochastic control fields. Whereas purely deterministic protocols exhibit dissipation that scales inversely with the number of steps, we show that weak Gaussian noise in the control variables induces dissipative contributions that grow linearly with the number of steps. Consequently, we derive the finite optimal number of steps and minimal achievable average dissipated work and its variance using the quantum thermodynamic length. These results are demonstrated using two paradigmatic examples: a Landau-Zener sweep of a qubit strongly coupled to a thermal bath and the erasure of a transverse-field Ising model.
Differential geometry offers a powerful framework for optimising and characterising finite-time thermodynamic processes, both classical and quantum. Here, we start by a pedagogical introduction to the notion of thermodynamic length. We review and connect different frameworks where it emerges in the quantum regime: adiabatically driven closed systems, time-dependent Lindblad master equations, and discrete processes. A geometric lower bound on entropy production in finite-time is then presented, which represents a quantum generalisation of the original classical bound. Following this, we review and develop some general principles for the optimisation of thermodynamic processes in the linear-response regime. These include constant speed of control variation according to the thermodynamic metric, absence of quantum coherence, and optimality of small cycles around the point of maximal ratio between heat capacity and relaxation time for Carnot engines.