Work is an observable quantity associated with a process; however, there is no Hermitian operator associated with its measurement. We consider an ancilla-assisted protocol measuring the work done on a quantum system driven by a time-dependent Hamiltonian via two von Neumann measurements of the system's energy carried out by a measuring apparatus modeled as a free particle of finite localization and interaction time with the system. We consider system Hamiltonians which both commute and do not commute at different times, finding corrections to fluctuation relations like the Jarzynski equality and the Crooks relation. This measurement model allows us to quantify the effect that measuring has on the estimated work distribution and associated average work done on the system and average heat exchanged with the measuring apparatus.
Work is an observable quantity associated with a process; however, there is no Hermitian operator associated with its measurement. We consider an ancilla-assisted protocol measuring the work done on a quantum system driven by a time-dependent Hamiltonian via two von Neumann measurements of the system's energy carried out by a measuring apparatus modeled as a free particle of finite localization and interaction time with the system. We consider system Hamiltonians which both commute and do not commute at different times, finding corrections to fluctuation relations like the Jarzynski equality and the Crooks relation. This measurement model allows us to quantify the effect that measuring has on the estimated work distribution and associated average work done on the system and average heat exchanged with the measuring apparatus.
Work in the paradigm of the quantum fluctuation theorems of Crooks and Jarzynski is determined by projective measurements of energy at the beginning and end of the force protocol. In analogy to classical systems, we consider an alternative definition of work given by the integral of the supplied power determined by integrating up the results of repeated measurements of the instantaneous power during the force protocol. We observe that such a definition of work, in spite of taking account of the process dependence, has different possible values and statistics from the work determined by the conventional two energy measurement approach (TEMA). In the limit of many projective measurements of power, the system’s dynamics is frozen in the power measurement basis due to the quantum Zeno effect leading to statistics only trivially dependent on the force protocol. In general the Jarzynski relation is not satisfied except for the case when the instantaneous power operator commutes with the total Hamiltonian at all times. We also consider properties of the joint statistics of power-based definition of work and TEMA work in protocols where both values are determined. This allows us to quantify their correlations. Relaxing the projective measurement condition, weak continuous measurements of power are considered within the stochastic master equation formalism. Even in this scenario the power-based work statistics is in general not able to reproduce qualitative features of the TEMA work statistics.
Quantum measurements are known to affect the state of the measured system. Such a measurement backaction is due to the interaction of the quantum system with the measuring device. When the measured observable and the system's Hamiltonian do not commute, the backaction can lead to a mean energy change of the system. This energy change has been dubbed "quantum heat" and, in association with feedback processes and/or the interaction with thermal bath(s), proves to be a genuinely quantum resource to fuel new kinds quantum engines. We propose such a measurement powered engine exploiting the non-commutativity of local and non-local operations on a bipartite quantum system.We then investigate the origin of the quantum heat. Even if one cannot model the full dynamics of a measurement due to the collapse of the wavefunction, the energetic aspects can still be investigated by modeling the so-called pre-measurement. During this step, the system interacts and gets correlated with a quantum system which can be viewed as a small part of the measuring apparatus and called the quantum meter. Ideally, at the end of this process, the system's reduced state will be fully decohered in the measurement basis, thus corresponding to the averaged collapsed output states given by the measurement postulate. We find that the quantum heat received by the measured system corresponds to the energy necessary to turn off the coupling between the meter and the system. Using generalized definitions of heat and work, we moreover characterize the work and heat nature of these energy exchanges.Tracing the source of this energy one step further, we propose an autonomous description of a measurement. This is done by considering a flying qubit measured by the quantum field of the cavity it crosses. The interaction being position dependent, the kinetic degree of freedom is providing the required energy to switch on and off the interaction between the qubit and the meter field. A full quantum treatment allows us to evaluate the impact of the finite spatial and momentum extension of the qubit wavepacket. Since the kinetic degree of freedom can be affected by the interaction, it does not simply generate a time dependent Hamiltonian for the other degrees of freedom. We find the correction to this ideal dynamic and analyse its consequences on the nature of the energy fluxes. %spread/extension/broadnessTaking the opposite point of view, we compare the measurement cost of a qubit by a field propagating in a waveguide, depending on the initial state of the field. In the context of a circuit quantum electrodynamics setup, we find that thermal and coherent fields induce the same backaction on the qubit given the same energy constraints.The results presented and discussed in this thesis contribute to unravel the mysterious effects and mechanisms due to quantum measurements. Notably, they give an outlook to further analyse quantum measurement-based engines and to understand the energetic resource that measurements cost and constitute at the same time.
Quantum measurement is ultimately a physical process, resulting from an interaction between the measured system and a measurement apparatus. Considering the physical process of measurement within a thermodynamic context naturally raises the following question: how can the work and heat resulting from the measurement process be interpreted? In the present manuscript, we model the measurement process for an arbitrary discrete observable as a measurement scheme. Here, the system to be measured is first unitarily coupled with a measurement apparatus, and subsequently the apparatus is measured by a pointer observable, thus producing a definite measurement outcome. The work can therefore be interpreted as the change in internal energy of the compound of system-plus-apparatus due to the unitary coupling. By the first law of thermodynamics, the heat is the subsequent change in internal energy of this compound due to the measurement of the pointer observable. However, in order for the apparatus to serve as a stable record for the measurement outcomes, the pointer observable must commute with the Hamiltonian, and its implementation must be repeatable. Given these minimal requirements, we show that the heat will necessarily be a classically fluctuating quantity.
The classical Jarzynski equality establishes an exact relation between the stochastic work performed on a system driven out of thermal equilibrium and the free energy difference in a corresponding quasistatic process. This fluctuation theorem bears experimental relevance, as it enables the determination of the free energy difference through the measurement of externally applied work in a nonequilibrium process. In the quantum case, the Jarzynski equality only holds if the measurement procedure of the stochastic work is drastically changed: it is replaced by a so-called two-point measurement scheme that requires the knowledge of the initial and final Hamiltonian and therefore lacks the predictive power for the free energy difference that the classical Jarzynski equation is known for. Here, we propose a quantum fluctuation theorem that is valid for externally measurable quantum work determined during the driving protocol. In contrast to the two-point measurement case, the theorem also applies to open quantum systems and the scenario can be realized without knowing the system Hamiltonian. Our fluctuation theorem comes in the form of an inequality and therefore only yields bounds to the true free energy difference. The inequality is saturated in the quasiclassical case of vanishing energy coherences at the beginning and at the end of the protocol. Thus, there is a clear quantum disadvantage.
Thermodynamical properties of quantum systems have been the object of study from many recent papers. In this dissertation, we begin with a brief review of quantum thermodynamics papers, where we focus on the rst law. We show that there are many different denitions of work and heat on quantum systems. We focus on one of the most usual denitions andwe present a recent work from Augusto Roncaglia et al. [1]. On this paper, they propose a method to measure the variation of the internal energy of a quantum system between two instants of time with a single measure by making the system interact with an ancilla twice. This method will be used as a starting point for this dissertation. We will explain how totransform the measurement protocol into one that continuously monitors a system and we will describe some conditions that the system must obey to make this monitoring possible. We show how the ancilla, which will also serve as the measurement apparatus, work and we will dene a quality factor for the measures. At last, we will study a specic system and will show how to use the protocol to obtain the time-dependance of an unknown hamiltonian. In order to do this, we use an algorithm that simulates the measurements proposed here and show that the protocol can not only effectively reconstruct the unknown hamiltonian but also obtain the total work and heat exchanged between the system and a reservoir.
A central challenge in quantum thermodynamics is to access work fluctuations in coherent processes without distorting the energetics of the unmeasured evolution. In standard two-point schemes, the initial energy measurement dephases coherent inputs, causing the measured average work to differ from that of the unmeasured evolution. Here, we develop an operational scheme for accessing work statistics for closed quantum systems based on the abstract notion of variation in the Heisenberg picture Hamiltonian. This scheme preserves energetically relevant coherences, thereby faithfully reproducing unmeasured work, while still producing positive probabilities. We derive modified Jarzynski and Crooks relations, as well as a thermodynamic uncertainty relation, identifying coherence-induced correction terms. Furthermore, we show that this scheme can reliably quantify the performance of a coherent engine in situations where the two-point energy measurement would suppress work output. In addition, the scheme requires only a single measurement and can predict the work associated with a subsequent unitary transformation. We exploit this feature to construct a Maxwell-demon protocol that can outperform energy-based feedback engines for coherent work extraction. Our results establish this scheme as a framework for accessing coherent work fluctuations without erasing the coherence that drives quantum thermodynamic performance.