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arXiv:2111.10918 · Frontiers of Physics

Isotope separation of Potassium with a magneto-optical combined method

Zixuan Zeng, Shangjin Li, Bo Yan

Published Nov 19, 2021• 2 citations
arXivHTMLPDF

Abstract

Due to the similar physical and chemical properties, isotopes are usually hard to separate. On the other hand, the isotope shifts are very well separated in a high-resolution spectrum, making them possible to be addressed individually by lasers, thus separated. Here we report such an isotope separation experiment with Potassium atoms. The isotopes are independently optical pumped to the desired spin states, and then separated with a Stern-Gerlach scheme. A micro-capillary oven is used to collimate the atomic beam, and a Halbach-type magnet array is used to deflect the desired atoms. Finally, the 40K is enriched by two orders of magnitude. This magneto-optical combined method provides an effective way to separate isotopes and can be extended to other elements if the relevant optical pumping scheme is feasible.

DOI
10.1007/s11467-021-1129-y

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Due to the similar physical and chemical properties, isotopes are usually hard to separate. On the other hand, the isotope shifts are very well separated in a high-resolution spectrum, making them possible to be addressed individually by lasers, thus separated. Here we report such an isotope separation experiment with Potassium atoms. The isotopes are independently optical pumped to the desired spin states, and then separated with a Stern-Gerlach scheme. A micro-capillary oven is used to collimate the atomic beam, and a Halbach-type magnet array is used to deflect the desired atoms. Finally, the 40K is enriched by two orders of magnitude. This magneto-optical combined method provides an effective way to separate isotopes and can be extended to other elements if the relevant optical pumping scheme is feasible.
Isotope shifts among different isotopes can be effectively addressed using narrow-linewidth lasers, facilitating laser isotope separation and achieving significant enrichment at a single stage.The separation of potassium isotopes, employing optical pumping and magnetic deflection, has proven to be efficient.To further improve the enrichment of 40 K, we introduce 2D transverse cooling to minimize the divergence angle.Through this modification, we demonstrate enrichment of 40 K, elevating it from 0.012% to 12%-20%.This represents an enrichment increase by three orders of magnitude, surpassing our previous result by one order.Our method is particularly well-suited for isotope enrichment of elements with extremely low abundance.
We describe a novel method to enrich isotopes and isomers via magnetic deflection of optically polarized atomic beam. High electronic polarization with opposite signs for atoms of both isotopes respectively is achieved by selective optical pumping using lasers with different frequencies and polarizations and then the isotopes are enriched by deflecting the oppositely polarized isotopes along different directions by the inhomo-geneous magnetic field in the spin selective magnet. Separation selectivity and throughput are evaluated and the advantages, disadvantages and prospects of possible application of the present method are discussed in comparison with other existing methods. Experimental scheme with lithium or potassium is suggested.
We present a dual isotope magneto-optical trap (MOT), simultaneous sub-Doppler laser cooling, and magnetic trapping of a spin-polarized 39K-40K Bose-Fermi mixture realized in a single-chamber setup with an unenriched potassium dispenser as the source of atoms. We are able to magnetically confine more than 2.2 × 105 fermions (F = 9/2 , m F = 9/2) and 1.4 × 107 bosons (F = 2 , m F = 2) with a lifetime exceeding 1.2 s. For this work, we have developed a versatile laser tailored for sub-Doppler cooling of all naturally occurring potassium isotopes and their mixtures. This laser system incorporates innovative features, such as the capability to select an isotope by activating or deactivating specific acousto-optic modulators that control the light seeding tapered amplifiers. Switching between isotopes takes ∼1 µs without any mechanical adjustment of the components.
Separation of Li isotopes by laser deflection of atomic beams has been carried out. An atomic beam apparatus with a collimating ratio of 450/1 generates are Li atomic beam of 10/sup 9/ atoms/cm/sup 3/ at the oven temperature of 600 /sup 0/C. The CW tunable dye laser crossing the atomic beam at a right angle has a linewidth of 6 MHz and its intensity as the I-cm interaction area is about 70 mW/cm/sup 2/. When the laser frequency is tuned to coincide with /sup 7/Li2/sup 2/P/sub 3/2/F = 3-2/sup 2/S/sub 1/2/ F = 2 transition, /sup 7/Li atoms are deflected from the beam. The deflected atoms are very pure /sup 7/Li and almost do not contain /sup 8/Li. When the laser frequency coincides with any other transition of 2/sup 2/P-2/sup 5/S of both /sup 5/Li and /sup 7/Li, no apparent deflection is observed because of the optical pumping of the hyperfine levels of the 2/sup 2/S/sub 1/2/ ground state.
Ultracold quantum gases have become a frequently used tool for the investigation of a variety of physical issues within the last decade, ranging from general questions in quantum physics up to special topics, e.g. quantum simulations of the physical origin of high temperature superconductivity in condensed matter physics. In this thesis, experiments are presented on the creation of an ultracold quantum gas of the fermionic potassium isotope, 40K, by all-optical means. For this purpose, a new experimental setup was designed, which was started from the scratch, with the long term goal of creating a supersolid in an optical lattice. One focus of this work lies in identifying light-assisted losses as a main restriction for achieving higher 40K atom numbers in a magneto-optical trap and in identifying light-assisted losses as a main reason for a low atomic transfer efficiency from a magneto-optical trap into an optical, quasi-electrostatic dipole trap (further called optical dipole trap) for 40K atoms. Naturally, another focus of this work lies in the application of different techniques to reduce these from light-assisted losses dependent restrictions. A two-dimensional magneto-optical trap, located in the prechamber of a vacuum system, creates a continuous beam of 40K atoms. The atoms of this beam are recaptured in the main chamber of the vacuum system by a spatial dark spot magneto-optical trap. Here, a dark magneto-optical trap is implemented instead of a standard magneto-optical trap in order to reduce light-assisted losses. Up to 1x109 atoms at temperatures around 240 μK are trapped in the dark magneto-optical trap. This is a factor of ten higher compared to atom numbers of a 40K standard magneto-optical trap. The light-assisted losses in the 40K magneto-optical trap were measured as a function of the total trapping intensity and as a function of the repumping intensity. In both cases, the smallest observed loss coefficient was β ≈ 2.5x10-10 cm3/s. Compared to the smallest values of β of all other alkali elements (apart from the bosonic potassium isotopes), the light-assisted losses with 40K atoms are approximately two orders of magnitude larger. Up to 6x105 atoms were transferred from the spatial dark magneto-optical trap into the quasi-electrostatic dipole trap, which was created by using the trapping potential induced by radiation emitted by a CO2 laser operating at a wavelength near 10.6 μm. In order to reach the here reported atom numbers in the optical dipole trap, its trapping volume had to be increased in comparison to a simple dipole trap arrangement as induced with a single focused dipole trapping beam. Simultaneously, the strong confinement, as present in a tigthly focused single beam trap and as required for a subsequent evaporative cooling, had to be maintained. For this purpose, the trapping laser beam of the optical dipole trap was retroreflected in such a way that an overall optical dipole trap with a nearly doubled waist and a slightly deeper potential depth was created. By this trapping arrangement, the number of atoms confined in the optical dipole trap could be nearly doubled compared to a simple dipole trapping arrangement consisting of a single tightly focused trapping beam. The atomic transfer process itself, from the magneto-optical trap into the optical dipole trap, was organized in two steps. In a first step, the dark magneto-optical trap was transformed into a compressed magneto-optical trap by increasing the field gradient and bringing the cooling laser closer to resonance as compared to the detuning of the usual magneto-optical trap. In contrast to other experiments, the repumping laser of the magneto-optical trap was detuned to the blue of the used repumping transition. As a consequence, atoms were optically pumped into the upper hyperfine ground state |S1/2, F=7/2〉, realizing a temporal dark, compressed magneto-optical trap in analogy to the operation of a temporal dark magneto-optical trap. By this approach, light-assisted losses were reduced. In the second step of the transfer process, the light fields of the magneto-optical trap and the optical dipole trap were alternately switched on and off. In this way, a spatially inhomogeneous ac Stark shift of the cooling transitions due to the spatially inhomogeneous intensity distribution of the dipole trapping beam was avoided and again light-assisted losses were reduced during the loading phase of atoms from the compressed magneto-optical trap into the optical dipole trap. The loading rate was measured to be approximately 2.8x108 atoms/s. The light-assisted losses during loading of the optical dipole trap were determined to be β ≈ 4.8x10-10 cm3/s. In the final step of the experiment, the temperature of the atomic ensemble confined in the optical dipole trap was further reduced by evaporative cooling. After an evaporation time of about 30 s, temperatures of 140 nK were reached at typical atom numbers of 12000. The corresponding Fermi temperature is TF = 110 nK yielding a ratio T/TF ≈ 1.3 which indicates that the fermionic potassium atoms are cooled close to the onset of quantum degeneracy. In the future, an additional trapping and evaporative cooling step within a magnetic quadrupole trap should allow for an improved loading efficiency into the far detuned optical dipole trap and finally allow for a subsequent evaporative cooling to a quantum degenerate Fermi gas.
Isotopes of barium are selectively excited to a metastable state using a single ring dye laser. The excited atoms are then deflected out of an atomic beam by an inhomogeneous magnetic field. The deflection of the beam is studied using a hot wire detector and a quadrupole mass spectrometer. Measurements are presented showing that nearly all atoms of a particle isotope can be excited from the 6s{sup 2} ground still to the 6s5d state and subsequently spatially separated. This method of isotope separation requires metastable states having lifetimes greater than about 100 {mu}sec. These states can be readily excited from the ground state in atoms such as the Group II elements.