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arXiv:2111.09110 · Journal of Physics D Applied Physics

Quadrupolar interaction induced frequency shift of 131 Xe nuclear spins on the surface of silicon

Yao Chen, Mingzhi Yu, Yintao Ma, Yanbin Wang, Ju Guo, Qijing Lin, Ning Zhang, Zhuangde Jiang, Libo Zhao

Published Jun 9, 2022• 7 citations
arXivHTMLPDF

Abstract

Abstract The combination of micro-machined technology with atomic spin gyroscope (ASG) devices can be used to fabricate a chip-scale atomic spin gyroscope (CASG). The core of the gyroscope is a micromachined vapour cell, which contains alkali metal and isotope-enriched noble gases, such as 129 Xe and 131 Xe . The quadrupolar frequency shift of 131 Xe is a key parameter that can affect the drift of the ASG and is related to the material of the cell in which they are contained. In micromachining technology, the utilised material is silicon. In this study, we investigated the electric quadrupolar frequency shift of 131 Xe atoms with the silicon wall of a micro-machined vapour cell. A cylindrical micromachined vapour cell was utilised in the experiment, and a large part of the inner cell surface comprised silicon material. We studied the temperature dependence of the 129 Xe spin relaxation and 131 Xe frequency shifts to evaluate the interaction of the nuclear spin with the container wall and alkali metal atoms. The results show that the average twisted angle of the 131 Xe nuclear spins as they collided with the silicon wall was measured as 29 × 10 − 6 rad. The desorption energy required for the 131 Xe nuclear spin to escape from the silicon surface was E s i = 0.009 eV . This study could help improve the bias stability of the CASG, which is a key parameter for the gyroscope, and may help to develop a method to study the surface properties of various materials.

DOI
10.1088/1361-6463/ac7757

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Abstract The combination of micro-machined technology with atomic spin gyroscope (ASG) devices can be used to fabricate a chip-scale atomic spin gyroscope (CASG). The core of the gyroscope is a micromachined vapour cell, which contains alkali metal and isotope-enriched noble gases, such as 129 Xe and 131 Xe . The quadrupolar frequency shift of 131 Xe is a key parameter that can affect the drift of the ASG and is related to the material of the cell in which they are contained. In micromachining technology, the utilised material is silicon. In this study, we investigated the electric quadrupolar frequency shift of 131 Xe atoms with the silicon wall of a micro-machined vapour cell. A cylindrical micromachined vapour cell was utilised in the experiment, and a large part of the inner cell surface comprised silicon material. We studied the temperature dependence of the 129 Xe spin relaxation and 131 Xe frequency shifts to evaluate the interaction of the nuclear spin with the container wall and alkali metal atoms. The results show that the average twisted angle of the 131 Xe nuclear spins as they collided with the silicon wall was measured as 29 × 10 − 6 rad. The desorption energy required for the 131 Xe nuclear spin to escape from the silicon surface was E s i = 0.009 eV . This study could help improve the bias stability of the CASG, which is a key parameter for the gyroscope, and may help to develop a method to study the surface properties of various materials.
High Resolution Image Download MS PowerPoint Slide Research on the electric quadrupole frequency shift mechanism and nuclear spin relaxation of 129 Xe– 131 Xe in alkali metal atomic vapor cells fabricated using microelectromechanical systems (MEMS) technology remains in its early stages. Therefore, an in-depth investigation in this field is crucial for enhancing the performance of miniaturized atomic gyroscopes and other quantum devices. This study provides a comprehensive analysis of the electric quadrupole frequency shift and relaxation of 129 Xe– 131 Xe nuclear spins in a stemless cubic MEMS vapor cell. To elucidate the microscopic characteristics of wall interactions, nuclear spin quadrupole interactions with mixed silicon and glass surfaces in MEMS vapor cells were examined. The influence of the angle between the vapor cell’s geometric axis and the applied magnetic field on the electric quadrupole frequency shift was investigated, leading to the determination of the vapor cell’s asymmetry parameter η and the average twist angle ⟨ θ ⟩ of nuclear spin-wall collisions. Furthermore, the temperature dependence of the electric quadrupole frequency shift in 131 Xe atoms was characterized, enabling the extraction of the desorption activation energy ( E A ) of 131 Xe on the MEMS vapor cell surface. By analyzing the free induction decay (FID) signals of 129 Xe and 131 Xe at varying temperatures, the relationship between their relaxation rates and temperature was established. These findings offer valuable insights for optimizing nuclear spin relaxation times in microatomic gyroscopes.
The combination of MEMS technology with atomic spin devices could fabricate chip scale atomic sensors. In most of the atomic devices based on alkali metals, the key component is an alkali vapor cell. Here we describe an alkali vapor cell fabrication technic for atomic spin gyroscope study. In the alkali vapor cell, alkali metal is filled in an oxygen and water free glovebox and noble gas isotopes such as129Xe and131Xe are also filled. Compared to an atomic magnetometer, in an atomic spin gyroscope, the isotope enriched noble gases are typically very expensive. We need to do recycling of these expensive gases after filling in the anode bonding chamber or else the gases will be wasted. Due to the large volume of the anode bonding chamber utilized in the fabrication process, a recycling platform is built based on liquid nitrogen. The relaxation time is a very important parameter of an alkali vapor cell. We developed a platform with magnetic field shielding system, non-magnetic field heating and single beam atomic spin detection subsystem. The spin relaxation time of the noble gases is tested in this study.
We report on the fabrication and characterization of MEMS atomic vapor cells suitable for applications in miniaturized quantum sensors such as atomic gyroscopes. Our MEMS cells are filled with natural abundance Rb alkali atoms and enriched noble Xe atoms and are operated in the regime of spin exchange optical pumping. The transverse relaxation time T2* of the nuclear spin in 129Xe atoms directly defines the angular random walk parameter of an atomic gyroscope. Using a field switch technique, we measure the dephasing time T2* of the 129Xe isotope as a function of temperature. Our results showing a decrease of T2* from about 1 to 0.4 seconds with an increasing temperature in the range from 80 to 150 °C are in good agreement with a simple theoretical model taking into account the most important decoherence mechanisms. We show that the observed decoherence behavior can be mostly explained trough collisions of the Xe atoms with the walls. Further characterization steps in order to gain more insight in the decoherence physics involved in our MEMS cells are discussed.
Abstract Wafer-fabricated vapor cells are essential components in the development of scalable, field-deployable atomic sensing systems, including atomic spin gyroscopes (ASGs). This paper presents a systematic study of magnetic resonance spectra obtained in a two-chamber, millimeter-sized, wafer-fabricated cell containing Cs, 129 Xe, 131 Xe, and N 2 buffer gas. For a range of vapor temperatures and pump powers, we identify characteristic structural and dynamical effects, including electric quadrupole splitting of the 131 Xe frequency and spectral branching of the 129 Xe frequency and linewidth as the signature of a parity-time symmetry-broken phase. Remarkably, we demonstrate that a primary class of systematic nonuniform field effects can be reduced to a simple one-dimensional linear gradient. We leverage these effects to offer regimes of optimized and robust sensor operation, setting a benchmark for the performance of wafer-fabricated vapor cells in both ASGs and more broad quantum technologies.
The spin polarization of 87Rb and 129Xe atomic ensemble has great impact on the signal intensity of a nuclear magnetic resonance gyroscope. The coupled spin polarization modelling process for 87Rb and 129Xe atoms ensemble is presented in detail. Three dimensional spatial distribution of the spin polarization field is obtained by numerical solution and is in good agreement with the experiment results. Influencing factors including temperature, power and detuned frequency of the pumping laser, average collision times of anti-relaxation coatings and partial pressure of gas composition are investigated. The work presents an indirect method to estimate the average collision times given the Xe polarization with different temperatures. It is found the average collision times of the 129Xe atoms with the inner surface of a bare glass cell of 3×3×3mm3 can reach up to about 2.7×105 times. It is also found that the pumping frequency corresponding to the maximum polarization of the Xe atoms polarized by spin exchange of Rb atoms is not consistent with the D1 line of the 87Rb atom when the temperature of the cell is above a certain temperature, but is detuned at a certain frequency. Quantitative analysis of the effect of anti-relaxation coatings on the spin polarization suggests that the appropriate average number of collisions of the Rb atoms with the inner surface of the cell is about 1500 times.
In the process of miniaturizing atomic spin gyroscopes, the relaxation due to the wall collisions of the alkali vapor cell leads to a shorter transverse relaxation time, which increases the key index of the atomic spin gyroscope, the angle random walk, and reduces the gyroscope’s accuracy. This paper theoretically analyzes the thermal stability of the interaction between the new anti-relaxation coating and molecules of the vapor cell, as well as the surface energy of the anti-relaxation coating molecular groups. Based on the results, a new anti-relaxation coating material and its preparation process were proposed. A novel anti-relaxation coating was experimentally prepared. Compositional analysis confirmed its successful covalent bonding with hydroxyl groups on the cell inner-surface, demonstrating superior thermal stability. Through comparative experiments including surface morphology analysis, contact angle measurement, and transverse relaxation time measurement, the new anti-relaxation coating proposed in this paper exhibits lower surface energy. It also has more excellent anti-relaxation performance compared to the traditional OTS anti-relaxation coating.