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arXiv:2111.03116 · Quantum

Work and Fluctuations: Coherent vs. Incoherent Ergotropy Extraction

Marcin Łobejko

Published Jul 14, 2022• 8 citations
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Abstract

We consider a quasi-probability distribution of work for an isolated quantum system coupled to the energy-storage device given by the ideal weight. Specifically, we analyze a trade-off between changes in average energy and changes in weight's variance, where work is extracted from the coherent and incoherent ergotropy of the system. Primarily, we reveal that the extraction of positive coherent ergotropy can be accompanied by the reduction of work fluctuations (quantified by a variance loss) by utilizing the non-classical states of a work reservoir. On the other hand, we derive a fluctuation-decoherence relation for a quantum weight, defining a lower bound of its energy dispersion via a dumping function of the coherent contribution to the system's ergotropy. Specifically, it reveals that unlocking ergotropy from coherences results in high fluctuations, which diverge when the total coherent energy is unlocked. The proposed autonomous protocol of work extraction shows a significant difference between extracting coherent and incoherent ergotropy: The former can decrease the variance, but its absolute value diverges if more and more energy is extracted, whereas for the latter, the gain is always non-negative, but a total (incoherent) ergotropy can be extracted with finite work fluctuations. Furthermore, we present the framework in terms of the introduced quasi-probability distribution, which has a physical interpretation of its cumulants, is free from the invasive nature of measurements, and reduces to the two-point measurement scheme (TPM) for incoherent states. Finally, we analytically solve the work-variance trade-off for a qubit, explicitly revealing all the above quantum and classical regimes.

DOI
10.22331/q-2022-07-14-762

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We consider a quasi-probability distribution of work for an isolated quantum system coupled to the energy-storage device given by the ideal weight. Specifically, we analyze a trade-off between changes in average energy and changes in weight's variance, where work is extracted from the coherent and incoherent ergotropy of the system. Primarily, we reveal that the extraction of positive coherent ergotropy can be accompanied by the reduction of work fluctuations (quantified by a variance loss) by utilizing the non-classical states of a work reservoir. On the other hand, we derive a fluctuation-decoherence relation for a quantum weight, defining a lower bound of its energy dispersion via a dumping function of the coherent contribution to the system's ergotropy. Specifically, it reveals that unlocking ergotropy from coherences results in high fluctuations, which diverge when the total coherent energy is unlocked. The proposed autonomous protocol of work extraction shows a significant difference between extracting coherent and incoherent ergotropy: The former can decrease the variance, but its absolute value diverges if more and more energy is extracted, whereas for the latter, the gain is always non-negative, but a total (incoherent) ergotropy can be extracted with finite work fluctuations. Furthermore, we present the framework in terms of the introduced quasi-probability distribution, which has a physical interpretation of its cumulants, is free from the invasive nature of measurements, and reduces to the two-point measurement scheme (TPM) for incoherent states. Finally, we analytically solve the work-variance trade-off for a qubit, explicitly revealing all the above quantum and classical regimes.
We investigate the decomposition of ergotropy into incoherent and coherent contributions for quantum systems subject to typical Markovian noise channels. The incoherent part originates from population inversion in the energy eigenbasis after dephasing, while the coherent part captures the role of quantum coherence in work extraction. For single-qubit systems, we derive explicit conditions for freezing and enhancement of coherent ergotropy and obtain an analytical upper bound, showing that it cannot exceed one half of the state's quantum coherence. We then study two classes of separable two-qubit states under local noise. For Bell-diagonal states, which are locally completely passive and possess no local coherence, we prove that the total extractable work equals the average of geometric quantum and classical correlations. In this case, coherent ergotropy cannot be enhanced, although freezing occurs under specific noise conditions. By contrast, for separable states with local coherence, coherent ergotropy can increase under all considered noise channels, including phase-flip and depolarizing noise. Extending the analysis to multipartite systems, we show that both the magnitude and range of noise-induced enhancement grow with the number of qubits, indicating collective reinforcement. Finally, we demonstrate through an explicit example that entanglement does not prevent this enhancement: coherent ergotropy may increase under noise even for entangled states. Our results reveal that noise can assist energy storage, challenging the conventional view of noise as purely detrimental and suggesting compatibility between noise-assisted enhancement and fast entanglement-based charging mechanisms in quantum batteries.
The amount of extractable work from a physical system is fundamentally connected to the information available about its state, as illustrated by Maxwell's demon and the Gibbs paradox. In standard thermodynamic protocols involving system--bath interactions, the maximum work is given by the free-energy difference between the initial state and the corresponding Gibbs state at the bath temperature. This motivates a natural question: does information also limit work extraction in closed quantum systems that do not involve a heat bath and where work is obtained through unitary operations generated by a time-dependent Hamiltonian? While ergotropy quantifies the maximum work extractable via unitary operations, it assumes complete knowledge of the quantum state, typically requiring full state tomography. In realistic scenarios, however, only partial information is accessible. In this case, the relevant figure of merit is observational ergotropy, which depends explicitly on the measurement used to probe the system. We show that observational ergotropy decreases under classical post-processing of measurement outcomes, implying that fine-grained measurements allow greater work extraction than coarse-grained ones. Moreover, maximizing observational ergotropy over all possible measurements recovers standard ergotropy, which decomposes into incoherent (classical) and coherent (quantum) contributions. Our results demonstrate that coherence in the measurement projectors constitutes the key resource, enabling work extraction beyond the incoherent limit and establishing coherence as the origin of quantum advantage in observational ergotropy extraction.
Work extraction in quantum finite systems is an important issue in quantum thermodynamics. The optimal work extracted is called ergotropy, and it is achieved by maximizing the average work extracted over all the unitary cycles. However, an agent that is non-neutral to risk is affected by fluctuations and should extract work by following the expected utility hypothesis. Thus, we investigate the optimal work extraction performed by a risk non-neutral agent by maximizing the average utility function over all the unitary cycles. We mainly focus on initial states that are incoherent with respect to the energy basis, achieving a probability distribution of work. In this case we show how the optimal work extraction will be performed with an incoherent unitary transformation, namely a permutation of the energy basis, which depends on the risk aversion of the agent. We give several examples, in particular also the work extraction from an ensemble of quantum batteries is examined. Furthermore, we also investigate how work extraction is affected by the presence of initial quantum coherence in the energy basis by considering a quasiprobability distribution of work.
Constraints on work extraction are fundamental to our operational understanding of the thermodynamics of both classical and quantum systems. In the quantum setting, finite-time control operations typically generate coherence in the instantaneous energy eigenbasis of the dynamical system. Thermodynamic cycles can, in principle, be designed to extract work from this nonequilibrium resource. Here, we isolate and study the quantum coherent component to the work yield in such protocols. Specifically, we identify a coherent contribution to the ergotropy (the maximum amount of unitarily extractable work via cyclical variation of Hamiltonian parameters). We show this by dividing the optimal transformation into an incoherent operation and a coherence extraction cycle. We obtain bounds for both the coherent and incoherent parts of the extractable work and discuss their saturation in specific settings. Our results are illustrated with several examples, including finite-dimensional systems and bosonic Gaussian states that describe recent experiments on quantum heat engines with a quantized load.
Understanding the generation and activation of ergotropy, the maximum work extractable by cyclic unitary operations, is central to quantum battery research. Positive-temperature thermal states are passive, whereas nonequilibrium environments can sustain nonpassive steady states with nonzero ergotropy. However, the full secular approximation commonly used in Lindblad descriptions can suppress steady-state coherence and obscure its contribution to ergotropy. Using a Bloch-Redfield master equation beyond the full secular approximation, we investigate the ergotropy of the nonequilibrium steady state (NESS) of two exchange-coupled qubits connected to independent thermal reservoirs. The NESS ergotropy of two qubits with the same frequency is entirely coherent and grows quadratically with temperature bias near equilibrium. In contrast, detuned qubits can exhibit incoherent ergotropy. We derive an exact analytical criterion for its activation and show that activation requires the hotter reservoir to be coupled to the qubit with the higher bare frequency. Comparing NESSs obtained with and without full secularization reveals quantitative and qualitative differences in ergotropy that reflect changes in both its coherent and incoherent contributions. The results clarify the mechanisms of NESS ergotropy activation and demonstrate the importance of retaining steady-state coherence beyond the full secular approximation when characterizing stationary work resources.
A central challenge in quantum thermodynamics is to access work fluctuations in coherent processes without distorting the energetics of the unmeasured evolution. In standard two-point schemes, the initial energy measurement dephases coherent inputs, causing the measured average work to differ from that of the unmeasured evolution. Here, we develop an operational scheme for accessing work statistics for closed quantum systems based on the abstract notion of variation in the Heisenberg picture Hamiltonian. This scheme preserves energetically relevant coherences, thereby faithfully reproducing unmeasured work, while still producing positive probabilities. We derive modified Jarzynski and Crooks relations, as well as a thermodynamic uncertainty relation, identifying coherence-induced correction terms. Furthermore, we show that this scheme can reliably quantify the performance of a coherent engine in situations where the two-point energy measurement would suppress work output. In addition, the scheme requires only a single measurement and can predict the work associated with a subsequent unitary transformation. We exploit this feature to construct a Maxwell-demon protocol that can outperform energy-based feedback engines for coherent work extraction. Our results establish this scheme as a framework for accessing coherent work fluctuations without erasing the coherence that drives quantum thermodynamic performance.