Abstract Many fruitful analogies have emerged between the theories of quantum entanglement and thermodynamics, motivating the pursuit of an axiomatic description of entanglement akin to the laws of thermodynamics. A long-standing open problem has been to establish a true second law of entanglement, and in particular a unique function that governs all transformations between entangled systems, mirroring the role of entropy in thermodynamics. Contrary to previous promising evidence, here we show that this is impossible and that no direct counterpart to the second law of thermodynamics can be established. This is accomplished by demonstrating the irreversibility of entanglement theory from first principles. Assuming only the most general microscopic physical constraints of entanglement manipulation, we show that entanglement theory is irreversible under all non-entangling transformations. We furthermore rule out reversibility without significant entanglement expenditure, showing that reversible entanglement transformations require the generation of macroscopically large amounts of entanglement according to certain measures. Our results not only reveal fundamental differences between quantum entanglement transformations and thermodynamic processes, but also showcase a unique property of entanglement that distinguishes it from other known quantum resources.
Abstract Many fruitful analogies have emerged between the theories of quantum entanglement and thermodynamics, motivating the pursuit of an axiomatic description of entanglement akin to the laws of thermodynamics. A long-standing open problem has been to establish a true second law of entanglement, and in particular a unique function that governs all transformations between entangled systems, mirroring the role of entropy in thermodynamics. Contrary to previous promising evidence, here we show that this is impossible and that no direct counterpart to the second law of thermodynamics can be established. This is accomplished by demonstrating the irreversibility of entanglement theory from first principles. Assuming only the most general microscopic physical constraints of entanglement manipulation, we show that entanglement theory is irreversible under all non-entangling transformations. We furthermore rule out reversibility without significant entanglement expenditure, showing that reversible entanglement transformations require the generation of macroscopically large amounts of entanglement according to certain measures. Our results not only reveal fundamental differences between quantum entanglement transformations and thermodynamic processes, but also showcase a unique property of entanglement that distinguishes it from other known quantum resources.
We introduce a reversible theory of exact entanglement manipulation by establishing a necessary and sufficient condition for state transfer under trace-preserving transformations that completely preserve the positivity of partial transpose (PPT). Under these free transformations, we show that logarithmic negativity emerges as the pivotal entanglement measure for determining entangled states' transformations, analogous to the role of entropy in the second law of thermodynamics. Previous results proved that entanglement is irreversible under quantum operations that completely preserve PPT and under all nonentangling transformations. In this work, we find that going beyond the complete positivity constraint imposed by standard quantum mechanics enables a reversible theory of exact entanglement manipulation, which may suggest a potential incompatibility between the reversibility of entanglement and the fundamental principles of quantum mechanics.
A central question since the beginning of quantum information science is how two distant parties can convert one entangled state into another. It has been conjectured that such conversions could be executed reversibly in an asymptotic regime, mirroring the reversible nature of Carnot cycles in classical thermodynamics. While a conclusive proof of this conjecture has been missing so far, earlier studies have excluded reversible entanglement manipulation in various settings. In this Letter, we show that arbitrary mixed state entanglement transformations can be made reversible under local operations and classical communication, when assisted by an entanglement battery-an auxiliary quantum system that stores and supplies entanglement in a way that ensures no net entanglement is lost. In particular, the rate of transformation in the asymptotic limit can be quantitatively expressed as a ratio of entanglement present within the quantum states involved. Our setting allows us to consider different entanglement quantifiers which give rise to unique principles governing state transformations, effectively constituting diverse manifestations of a "second law" of entanglement manipulation. These findings resolve a long-standing open question on the reversible manipulation of entangled states and are also applicable to multipartite entanglement and other quantum resource theories, including quantum thermodynamics.
Pure-state entanglement transformations have been thought of as irreversible, with reversible transformations generally only possible in the limit of many copies. Here, we show that reversible entanglement transformations do not require processing on the many-copy level but can instead be undertaken on individual systems, provided the amount of entanglement which is produced or consumed is allowed to fluctuate. We derive necessary and sufficient conditions for entanglement manipulations in this case. As a corollary, we derive an equation which quantifies the fluctuations of entanglement, which is formally identical to the Jarzynski fluctuation equality found in thermodynamics. One can also relate a forward entanglement transformation to its reverse process in terms of the entanglement cost of such a transformation, in a manner equivalent to the Crooks relation. We show that a strong converse theorem for entanglement transformations is formally related to the second law of thermodynamics, while the fact that the Schmidt rank of an entangled state cannot increase is related to the third law of thermodynamics. Achievability of the protocols is done by introducing an entanglement battery, a device which stores entanglement and uses an amount of entanglement that is allowed to fluctuate but with an average cost which is still optimal. This allows us to also solve the problem of partial entanglement recovery, and in fact, we show that entanglement is fully recovered. Allowing the amount of consumed entanglement to fluctuate also leads to improved and optimal entanglement dilution protocols.
The second law of thermodynamics places constraints on state transformations. It applies to systems composed of many particles, however, we are seeing that one can formulate laws of thermodynamics when only a small number of particles are interacting with a heat bath. Is there a second law of thermodynamics in this regime? Here, we find that for processes which are approximately cyclic, the second law for microscopic systems takes on a different form compared to the macroscopic scale, imposing not just one constraint on state transformations, but an entire family of constraints. We find a family of free energies which generalize the traditional one, and show that they can never increase. The ordinary second law relates to one of these, with the remainder imposing additional constraints on thermodynamic transitions. We find three regimes which determine which family of second laws govern state transitions, depending on how cyclic the process is. In one regime one can cause an apparent violation of the usual second law, through a process of embezzling work from a large system which remains arbitrarily close to its original state. These second laws are relevant for small systems, and also apply to individual macroscopic systems interacting via long-range interactions. By making precise the definition of thermal operations, the laws of thermodynamics are unified in this framework, with the first law defining the class of operations, the zeroth law emerging as an equivalence relation between thermal states, and the remaining laws being monotonicity of our generalized free energies.
Entanglement is one of the most striking features of quantum mechanics, and yet it is not specifically quantum.More specific to quantum mechanics is the connection between entanglement and thermodynamics, which leads to an identification between entropies and measures of pure state entanglement.Here we search for the roots of this connection, investigating the relation between entanglement and thermodynamics in the framework of general probabilistic theories.We first address the question whether an entangled state can be transformed into another by means of local operations and classical communication.Under two operational requirements, we prove a general version of the Lo-Popescu theorem, which lies at the foundations of the theory of pure-state entanglement.We then consider a resource theory of purity where free operations are random reversible transformations, modelling the scenario where an agent has limited control over the dynamics of a closed system.Our key result is a duality between the resource theory of entanglement and the resource theory of purity, valid for every physical theory where all processes arise from pure states and reversible interactions at the fundamental level.As an application of the main result, we establish a one-to-one correspondence between entropies and measures of pure bipartite entanglement.The correspondence is then used to define entanglement measures in the general probabilistic framework.Finally, we show a duality between the task of information erasure and the task of entanglement generation, whereby the existence of entropy sinks (systems that can absorb arbitrary amounts of information) becomes equivalent to the existence of entanglement sources (correlated systems from which arbitrary amounts of entanglement can be extracted).