We discuss an approach to determine averages of the work, dissipated heat, and variation of internal energy of an open quantum system driven by an external classical field. These quantities are measured by coupling the quantum system to a quantum detector at different times. This approach allows us to preserve the full quantum features of the evolution. From the measured phase, we are able to obtain a quasicharacteristic function and a quasiprobability density function for the corresponding observables. Despite the fact that these quasiprobability density functions are not the results of direct measurements, they reproduce the expected value of the physical quantities. Analogously to the Wigner function, the negative regions of these quasiprobability density functions are directly related to pure quantum processes which are not interpretable in classical terms. We use this feature to show that in the limit of fast dissipation, the quantum features vanish and interpret this as the emergence of the classical limit of the energy exchange process. Our analysis explains and confirms the behavior observed in recent experiments performed on IBMQ devices [P. Solinas et al., Phys. Rev. A 103, L060202 (2021)]. The possibility to discriminate between classical and quantum features makes the proposed approach an excellent tool to determine if, and in which conditions, quantum effects can be exploited to increase the efficiency in an energy exchange process at the quantum level.
We discuss an approach to determine averages of the work, dissipated heat, and variation of internal energy of an open quantum system driven by an external classical field. These quantities are measured by coupling the quantum system to a quantum detector at different times. This approach allows us to preserve the full quantum features of the evolution. From the measured phase, we are able to obtain a quasicharacteristic function and a quasiprobability density function for the corresponding observables. Despite the fact that these quasiprobability density functions are not the results of direct measurements, they reproduce the expected value of the physical quantities. Analogously to the Wigner function, the negative regions of these quasiprobability density functions are directly related to pure quantum processes which are not interpretable in classical terms. We use this feature to show that in the limit of fast dissipation, the quantum features vanish and interpret this as the emergence of the classical limit of the energy exchange process. Our analysis explains and confirms the behavior observed in recent experiments performed on IBMQ devices [P. Solinas et al., Phys. Rev. A 103, L060202 (2021)]. The possibility to discriminate between classical and quantum features makes the proposed approach an excellent tool to determine if, and in which conditions, quantum effects can be exploited to increase the efficiency in an energy exchange process at the quantum level.
Despite the increasing interest, the research field which studies the concepts of work and heat at the quantum level has suffered from two main drawbacks: first, the difficulty to properly define and measure the work, heat, and internal energy variation in a quantum system and, second, the lack of experiments. Here, we report a full characterization of the dissipated heat, work, and internal energy variation in a two-level quantum system interacting with an engineered environment. We use the IBMQ quantum computer to implement the driven system's dynamics in a dissipative environment. The experimental data allow us to construct quasiprobability distribution functions from which we recover the correct averages of work, heat, and internal energy variation in the dissipative processes. Interestingly, by increasing the environment coupling strength, we observe a reduction of the pure quantum features of the energy exchange processes that we interpret as the emergence of the classical limit. This makes the present approach a privileged tool to study, understand, and exploit quantum effects in energy exchanges.
In this article, we introduce a quasiprobability distribution of work that is based on the Wigner function. This proposal rests on the idea that the work conducted on an isolated system can be coherently measured by coupling the system to a quantum measurement apparatus. In this way, a quasiprobability distribution of work can be defined in terms of the Wigner function of the apparatus. This quasidistribution contains the information of the work statistics and also holds a clear operational definition that can be directly measured in a real experiment. Moreover, it is shown that the presence of quantum coherence in the energy eigenbasis is related with the appearance of features related to non-classicality in the Wigner function such as negativity and interference fringes. On the other hand, from this quasiprobability distribution, it is straightforward to obtain the standard two-point measurement probability distribution of work and also the difference in average energy for initial states with coherences.
We consider a collision model representation of nonequilibrium dynamics for an externally driven open quantum system. Specifically we investigate the nondemolition quasiprobability distributions (QPDFs) of work and heat in both Markovian and non-Markovian regimes. In this model, work and heat correspond to different evolution processes, and their contributions can be distinguished. For the system state with initial coherence, in both Markovian and non-Markovian regimes, negative quasiprobabilities at half of the energy gap of the system for work and the variation of internal energy appear, which is considered to be a witness of the quantumness of the system. We also find that when the external driving speed slows down, the quantumness of the system is weakened, and when the driving speed is slow enough, the negative quasiprobability will disappear and the results of the QPDF coincide with those of the two-measurement protocol. Most importantly, we find that non-Markovianity can enhance the quantumness of the system.
In this tutorial, we present the definition, interpretation, and properties of some of the main quasiprobabilities that can describe the statistics of measurement outcomes evaluated at two or more times. Such statistics incorporate the incompatibility of the measurement observables and the state of the measured quantum system. We particularly focus on Kirkwood-Dirac quasiprobabilities and related distributions. We also discuss techniques to experimentally access a quasiprobability distribution, ranging from the weak two-point measurement scheme, to a Ramsey-like interferometric scheme and procedures assisted by an external detector. Once defined the fundamental concepts following the standpoint of joint measurability in quantum mechanics, we illustrate the use of quasiprobabilities in quantum thermodynamics to describe the quantum statistics of work and heat, and to explain anomalies in the energy exchanges entailed by a given thermodynamic transformation. On the one hand, in work protocols, we show how absorbed energy can be converted to extractable work and vice versa due to Hamiltonian incompatibility at distinct times. On the other hand, in exchange processes between two quantum systems initially at different temperatures, we explain how quantum correlations in their initial state may induce cold-to-hot energy exchanges, which are unnatural between any pair of equilibrium nondriven systems. We conclude the tutorial by giving simple examples where quasiprobabilities are applied to many-body systems: scrambling of quantum information, sensitivity to local perturbations, and quantum work statistics in the quenched dynamics of models that can be mapped onto systems of free fermions, for instance, the Ising model with a transverse field. Throughout the tutorial, we meticulously present derivations of essential concepts alongside straightforward examples, aiming to enhance comprehension and facilitate learning. Published by the American Physical Society 2024
In the present Thesis we study the behavior of multi-time correlation functions and of thermodynamical quantities such as heat in open quantum systems undergoing an evolution generally affected by the presence of memory effects, i.e. non-Markovian. In the last decade, a large part of the scientific community in this field has dedicated its efforts to the understanding, precise definition and quantification of non-Markovianity in the quantum realm and now we have at our disposal several benchmark results and a plethora of different estimators that allow to determine the degree of non-Markovianity of a given dynamics. It comes therefore natural to investigate how other different dynamical quantities relate to such estimators also in order to understand the physical implications of memory effects on the statistics of observable quantities. In the first part of this work, a quantitative test of the violation of the so-called quantum regression theorem in presence of a non-Markovian dynamical regime is investigated. The quantum regression theorem represents a procedure that, whenever valid, allows to reconstruct two-time correlation functions of system's operators from the sole knowledge of the dynamics of mean values. It is worth stressing that two-time correlation functions are necessary in order to fully characterize the statistical properties of a quantum system, since they are able to catch aspects of the dynamics, such as fluorescence spectrum, in general not accessible looking at mean values. Despite their relevance however, obtaining two-time correlation functions often represents a formidable task, since the knowledge of the full "system+environment" dynamics is required, a generally too demanding request in the context of open quantum systems theory. The quantum regression theorem represents in this regard the easiest route to determine two-time correlation functions, this highlighting its importance. In this work we show that, in a pure-dephasing spin-boson model, the quantum regression theorem represents a stronger condition than non-Markovianity, in the sense that any presence of memory effects in the reduced dynamics inevitably results in violations to the former. These results have been published in [G.Guarnieri, A. Smirne, B. Vacchini, Phys. Rev. A 90, 022110 (2014)]. The second part of the Thesis is devoted to the characterization of heat ow at the microscopic level in open quantum systems, both finite and infinite dimensional. In particular we begin by studying the time behavior of its mean value in a non-Markovian dynamical regime, showing that, at variance with what happens in the Born-Markov semigroup limiting case, heat can backflow from the environment to the system. After providing a condition for the occurrence of such phenomenon and a measure for its amount for a given dynamics, the relationship with suitable non-Markovianity estimators is sought in two paradigmatic models, namely the spin-boson and the quantum brownian motion. The results, collected in [ G. Guarnieri, C. Uchiyama, B. Vacchini, Phys. Rev. A 93, 012118 (2016); G. Guarnieri, J. Nokkala, R. Schmidt, S. Maniscalco, B. Vacchini, Phys. Rev. A 94, 062101 (2016)], on the one hand allow for the identification of parameter-regions where the heat backflow is absent or maximum. On the other hand they show that the occurrence of heat backflow represents a stricter condition than non-Markovianity, in the sense that non-Markovianity allows for the observation of heat flowing back from the environment to the system and, vice versa, a Markovian dynamics prevents its occurrence. This Thesis concludes with the formulation of a new family of lower bounds to the mean dissipated heat in an environmental-assisted erasure-protocol scenario where Landauer's principle applies. As originally conceived for classical systems, this principle states that every irreversible erasure of information stored in a system inevitably carries along an amount of heat dissipated into the environment which is expended to perform the action. Within the framework recently put forward in [D. Reeb, M. M. Wolf, New J. Phys. 16, 103011 (2014)], which guarantees the validity of Landauer's principle in an open quantum systems scenario, we provide an asymptotically tight family of lower bounds to the dissipated heat which are also valid in the non-equilibrium setting. This construction is applied to an open system consisting of a three-level V-system, in which one transition is externally pumped by a laser field while the other is coupled through an XX-interaction to an environment consisting of a spin chain. Beside calculating all these quantities, an exact solution for the dynamics of such system is also provided. These results are collected in [G. Guarnieri, S. Campbell, J. Goold, S. Pigeon, M. Paternostro, B. Vacchini, in preparation].
We propose an approach to define and measure the statistics of work, internal energy and dissipated heat in a driven quantum system. In our framework the presence of a physical detector arises naturally and work and its statistics can be investigated in the most general case. In particular, we show that the quantum coherence of the initial state can lead to measurable effects on the moments of the work done on the system. At the same time, we recover the known results if the initial state is a statistical mixture of energy eigenstates. Our method can also be applied to measure the dissipated heat in an open quantum system. By sequentially coupling the system to a detector, we can track the energy dissipated in the environment while accessing only the system degrees of freedom.