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arXiv:2109.14639 · Physical Review Applied

Dispersive Readout of Molecular Spin Qudits

Álvaro Gómez-León, Fernando M. Luis, David Zueco

Published Jun 14, 2022• 19 citations
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Abstract

We study the physics of a magnetic molecule described by a ``giant'' spin with multiple ($d>2$) spin states interacting with the quantized cavity field produced by a superconducting resonator. By means of the input-output formalism, we derive an expression for the output modes in the dispersive regime of operation. It includes the effect of magnetic anisotropy, which makes different spin transitions addressable. We find that the measurement of the cavity transmission allows us to uniquely determine the spin state of the qudits. We discuss, from an effective Hamiltonian perspective, the conditions under which the qudit readout is a nondemolition measurement and consider possible experimental protocols to perform it. Finally, we illustrate our results with simulations performed for realistic models of existing magnetic molecules.

DOI
10.1103/physrevapplied.17.064030

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We study the physics of a magnetic molecule described by a ``giant'' spin with multiple (d>2d>2d>2) spin states interacting with the quantized cavity field produced by a superconducting resonator. By means of the input-output formalism, we derive an expression for the output modes in the dispersive regime of operation. It includes the effect of magnetic anisotropy, which makes different spin transitions addressable. We find that the measurement of the cavity transmission allows us to uniquely determine the spin state of the qudits. We discuss, from an effective Hamiltonian perspective, the conditions under which the qudit readout is a nondemolition measurement and consider possible experimental protocols to perform it. Finally, we illustrate our results with simulations performed for realistic models of existing magnetic molecules.
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The implementation of a universal quantum processor still poses fundamental issues related to error mitigation and correction, which demand to investigate also platforms and computing schemes alternative to the main stream. A possibility is offered by employing multi-level logical units (qudits), naturally provided by molecular spins. Here we present the blueprint of a Molecular Spin Quantum Processor consisting of single Molecular Nanomagnets, acting as qudits, placed within superconducting resonators adapted to the size and interactions of these molecules to achieve a strong single spin to photon coupling. We show how to implement a universal set of gates in such a platform and to readout the final qudit state. Single-qudit unitaries (potentially embedding multiple qubits) are implemented by fast classical drives, while a novel scheme is introduced to obtain two-qubit gates via resonant photon exchange. The latter is compared to the dispersive approach, finding in general a significant improvement. The performance of the platform is assessed by realistic numerical simulations of gate sequences, such as Deutsch-Josza and quantum simulation algorithms. The very good results demonstrate the feasibility of the molecular route towards a universal quantum processor.
We review the progress made in integrating magnetic molecules containing transition metal ions into nanoelectronic solid-state devices and using them as molecular spin qubits. Molecular spin qubits offer numerous advantages over other material platforms, such as being inherently quantum systems with discrete energy levels, having a rich variety of possible chemical designs, and being synthesizable in large quantities with atomic precision. However, the integration of magnetic molecules into practical and scalable molecular spin qubit devices (MSQDs) that offer initialization, coherent control, and readout of quantum spin states remains one of the major bottlenecks on the way toward applications of these systems in quantum computing technologies. We discuss the evolution of the field of MSQDs and review the first successful implementation of essential qubit operations in a single-molecule transistor based on a TbPc 2 molecule. Further development has been achieved through the merging of molecular electronics with the circuit quantum electrodynamics (cQED) approach where molecular spin states can be manipulated by the microwave frequency photons confined in a superconducting waveguide resonator. We discuss examples of such hybrid devices operating via coupling of a superconducting resonator to large spin ensembles, such as bulk samples and thin films. We also review a possible architecture for single-molecule cQED devices and the potential advantages that it offers. Then, we highlight the possibility and benefits of the optical initialization and readout of molecular spin states. This approach has been realized by using an optical pumping technique for the initialization and changes in photoluminescence for the readout of large molecular spin ensembles coupled to a superconducting resonator. The field of MSQDs is highly interdisciplinary, bringing together progress in synthetic chemistry, molecular electronics, cQED, and optical measurements. While it is still in its infancy, there are promising theoretical designs and encouraging proof-of-concept experiments, and we discuss several proposed device architectures that are eagerly awaiting experimental realization. Advances in hybrid MSQDs will open horizons for quantum technologies.
The physical implementation of any quantum computer still faces important issues related to scalability and error correction. This study sets up the blueprint for a quantum processor based on molecular spins coupled to superconducting resonators, which control different qudits, read out their final states, and establish coherent communication channels between them. The feasibility of this route is demonstrated by an accurate design of the resonator to reach the strong-coupling regime between a single photon and a single molecule. Very good results for proof-of-principle quantum algorithms and quantum simulations are obtained by numerical simulations of a realistic experimental scenario.
Dispersive readout, the current standard for measuring superconducting qubits, relies on relatively easy to engineer, static transverse coupling between a qubit and a detuned cavity mode. However, this method requires circuit design trade-offs between qubit-cavity coupling, cavity-feedline coupling, detuning, and the resultant decoherence introduced by the cavity mode. Additionally, the criteria for performing quantum nondemolition measurements, including reduced cavity photon numbers, further limits speed and fidelity. In this work, we introduce a circuit with pulse-tunable qubit-cavity and cavity-feedline couplings so that the entire qubit-measurement process can be fully optimized. Here, the core measurement process resembles a quantum gate operation between the qubit and the cavity, with the cavity acting like an ancilla, storing the qubit-state information. To fully explore time-dependent effects of the full qubit-cavity dynamics, we go beyond the rotating-wave, Jaynes-Cummings, or dispersive approximations, to develop a pulsed-measurement protocol. In addition, we propose a realistic circuit architecture that can provide a very fast, high-fidelity, QND measurement with near-unit efficiency.
We propose a paradigm of multiplexed dispersive qubit measurement performed while the qubits dephase. A Laplace transformation of the time-dependent cavity response allows to separate contributions from multiple qubits coupled to the same resonator mode, thus allowing for simultaneous single-shot readout. With realistic parameters for silicon spin qubits we find a competitive readout fidelity, while the measurement time compares favorably to conventional dispersive readout. We extend the multiplexed readout method to quantum nondemolition measurements using auxiliary qubits.