We consider a collision between a moving particle and a fixed system, each having internal degrees of freedom. We identify the regime where the motion of the particle acts as a work source for the joint internal system, leading to energy changes which preserve the entropy. This regime arises when the particle has high kinetic energy and its quantum state of motion is broad in momentum and narrow in space, whether pure or mixed. In this case, the scattering map ruling the dynamics of the internal degrees of freedom becomes unitary and equivalent to that of a time-dependent interaction between the internal degrees of freedom of the colliding systems. It follows that the kinetic energy lost by the particle during the autonomous quantum collision coincides with the work performed by the time-dependent interaction. Recently, collisions with particles were shown to act as heat sources under suitable conditions; here we show that they can also act as work sources. This opens interesting perspectives for quantum thermodynamics formulations within scattering theory.
We consider a collision between a moving particle and a fixed system, each having internal degrees of freedom. We identify the regime where the motion of the particle acts as a work source for the joint internal system, leading to energy changes which preserve the entropy. This regime arises when the particle has high kinetic energy and its quantum state of motion is broad in momentum and narrow in space, whether pure or mixed. In this case, the scattering map ruling the dynamics of the internal degrees of freedom becomes unitary and equivalent to that of a time-dependent interaction between the internal degrees of freedom of the colliding systems. It follows that the kinetic energy lost by the particle during the autonomous quantum collision coincides with the work performed by the time-dependent interaction. Recently, collisions with particles were shown to act as heat sources under suitable conditions; here we show that they can also act as work sources. This opens interesting perspectives for quantum thermodynamics formulations within scattering theory.
Abstract We compare definitions of the internal energy of an open quantum system and strategies to split the internal energy into work and heat contributions as given by four different approaches from the autonomous system framework. Our discussion focuses on methods that allow for arbitrary environments (not just heat baths) and driving by a quantum mechanical system. As a simple application we consider an atom as the system of interest and an oscillator field mode as the environment. Three different types of coupling are analyzed. We discuss ambiguities in the definitions and highlight differences that appear if one aims at constructing environments that act as pure heat or work reservoirs. Further, we identify different sources of work (e.g. coherence, correlations, or frequency offset), depending on the underlying framework. Finally, we give arguments to favour the approach based on minimal dissipation.
Abstract Collisional reservoirs are becoming a major tool for modelling open quantum systems. In their simplest implementation, an external agent switches on, for a given time, the interaction between the system and a specimen from the reservoir. Generically, in this operation the external agent performs work onto the system, preventing thermalization when the reservoir is at equilibrium. One can recover thermalization by considering an autonomous global setup where the reservoir particles colliding with the system possess a kinetic degree of freedom. The drawback is that the corresponding scattering problem is rather involved. Here, we present a formal solution of the problem in one dimension and for flat interaction potentials. The solution is based on the transfer matrix formalism and allows one to explore the symmetries of the resulting scattering map. One of these symmetries is micro-reversibility, which is a condition for thermalization. We then introduce two approximations of the scattering map that preserve these symmetries and, consequently, thermalize the system. These relatively simple approximate solutions constitute models of quantum thermostats and are useful tools to study quantum systems in contact with thermal baths. We illustrate their accuracy in a specific example, showing that both are good approximations of the exact scattering problem even in situations far from equilibrium. Moreover, one of the models consists of the removal of certain coherences plus a very specific randomization of the interaction time. These two features allow one to identify as heat the energy transfer due to switching on and off the interaction. Our results prompt the fundamental question of how to distinguish between heat and work from the statistical properties of the exchange of energy between a system and its surroundings.
Extending the quantum formulation of [Phys. Rev. X 3, 041003 (2013)] to a more general setting for studying the thermodynamics of information processing including initial correlations, we generalize the second law of thermodynamics to account for information processing in such autonomous systems. We consider a composite quantum system consisting of a principal system, heat bath, memory, and work source, and adopt an autonomous Hamiltonian framework. We derive constraints on the total Hamiltonian that ensure the work source to act as a catalyst preserving its original randomness, namely that the total unitary evolution must have a unitary partial transpose. We show that this requirement is equivalent to the commutativity of operators acting on the joint system of the principal system, bath, and memory, which underlies the Hamiltonian structure. Next, we generalize the quantum speed limit for the joint dynamics of system and memory to the quantum thermodynamic speed limit, from which we obtain a dynamical version of Landauer's bound. More importantly, we also interpret this quantum thermodynamic speed limit in the context of quantum hypothesis testing.
Quantum thermodynamics with open systems is often based on the quantum optical weak-coupling master equation or on operational repeated interaction models, whereas early works on thermalisation and on decoherence theory were mostly concerned with the kinetics of gas collisions. Here we formulate a master equation for the dynamics of a quantum system under inelastic scattering with a dilute thermal gas in three dimensions, comprised of ancilla particles that also possess internal degrees of freedom. We show thermodynamic consistency when the gas is at thermal equilibrium, irrespective of whether or not the ancillas are in resonance with the system. In contrast, when the internal and the motional state of the gas are thermalised to different temperatures, the gas acts not as two distinct heat baths, but as a structured non-equilibrium reservoir that can generate useful energy through uncontrolled collisions.
We study the influence of entanglement on the relation between the statistical entropy of an open quantum system and the heat exchanged with a low temperature environment. A model of quantum Brownian motion of the Caldeira–Leggett type—for which a violation of the Clausius inequality has been stated by Th M Nieuwenhuizen and A E Allahverdyan (2002 Phys. Rev. E 66 036102)—is re-examined and the results of the cited work are put into perspective. In order to address the problem from an information theoretical viewpoint a model of two coupled Brownian oscillators is formulated that can also be viewed as a continuum version of a two-qubit system. The influence of an additional internal coupling parameter on heat and entropy changes is described and the findings are compared to the case of a single Brownian particle.
Quantum measurements are known to affect the state of the measured system. Such a measurement backaction is due to the interaction of the quantum system with the measuring device. When the measured observable and the system's Hamiltonian do not commute, the backaction can lead to a mean energy change of the system. This energy change has been dubbed "quantum heat" and, in association with feedback processes and/or the interaction with thermal bath(s), proves to be a genuinely quantum resource to fuel new kinds quantum engines. We propose such a measurement powered engine exploiting the non-commutativity of local and non-local operations on a bipartite quantum system.We then investigate the origin of the quantum heat. Even if one cannot model the full dynamics of a measurement due to the collapse of the wavefunction, the energetic aspects can still be investigated by modeling the so-called pre-measurement. During this step, the system interacts and gets correlated with a quantum system which can be viewed as a small part of the measuring apparatus and called the quantum meter. Ideally, at the end of this process, the system's reduced state will be fully decohered in the measurement basis, thus corresponding to the averaged collapsed output states given by the measurement postulate. We find that the quantum heat received by the measured system corresponds to the energy necessary to turn off the coupling between the meter and the system. Using generalized definitions of heat and work, we moreover characterize the work and heat nature of these energy exchanges.Tracing the source of this energy one step further, we propose an autonomous description of a measurement. This is done by considering a flying qubit measured by the quantum field of the cavity it crosses. The interaction being position dependent, the kinetic degree of freedom is providing the required energy to switch on and off the interaction between the qubit and the meter field. A full quantum treatment allows us to evaluate the impact of the finite spatial and momentum extension of the qubit wavepacket. Since the kinetic degree of freedom can be affected by the interaction, it does not simply generate a time dependent Hamiltonian for the other degrees of freedom. We find the correction to this ideal dynamic and analyse its consequences on the nature of the energy fluxes. %spread/extension/broadnessTaking the opposite point of view, we compare the measurement cost of a qubit by a field propagating in a waveguide, depending on the initial state of the field. In the context of a circuit quantum electrodynamics setup, we find that thermal and coherent fields induce the same backaction on the qubit given the same energy constraints.The results presented and discussed in this thesis contribute to unravel the mysterious effects and mechanisms due to quantum measurements. Notably, they give an outlook to further analyse quantum measurement-based engines and to understand the energetic resource that measurements cost and constitute at the same time.