Theoretical and experimental studies have suggested the relevance of quantum coherence to the performance of photovoltaic and light-harvesting complex molecular systems. However, there are ambiguities regarding the validity of statements we can make about the coherence in such systems. Here, we analyze the general procedure for coherence detection in quantum systems and show the counterintuitive phenomenon of detecting a quantum system's initial coherence when both the input and output states of the probe interacting with the system are locally completely incoherent. Our analysis yields the necessary and sufficient conditions for valid claims regarding the coherence of directly inaccessible systems. We further provide a proof-of-principle protocol that uses entangled probes to detect quantum coherence satisfying these conditions and discuss its potency for detecting coherence.
Theoretical and experimental studies have suggested the relevance of quantum coherence to the performance of photovoltaic and light-harvesting complex molecular systems. However, there are ambiguities regarding the validity of statements we can make about the coherence in such systems. Here, we analyze the general procedure for coherence detection in quantum systems and show the counterintuitive phenomenon of detecting a quantum system's initial coherence when both the input and output states of the probe interacting with the system are locally completely incoherent. Our analysis yields the necessary and sufficient conditions for valid claims regarding the coherence of directly inaccessible systems. We further provide a proof-of-principle protocol that uses entangled probes to detect quantum coherence satisfying these conditions and discuss its potency for detecting coherence.
Quantum coherence, present whenever a quantum system exists in a superposition of multiple classically distinct states, marks one of the fundamental departures from classical physics. Quantum coherence has recently been investigated rigorously within a resource-theoretic formalism. However, the finer-grained notion of multilevel coherence, which explicitly takes into account the number of superposed classical states, has remained relatively unexplored. A comprehensive analysis of multi-level coherence, which acts as the single-party analogue to multi-partite entanglement, is essential for understanding natural quantum processes as well as for gauging the performance of quantum technologies. Here we develop the theoretical and experimental groundwork for characterizing and quantifying multilevel coherence. We prove that non-trivial levels of purity are required for multilevel coherence, as there is a ball of states around the maximally mixed state that do not exhibit multilevel coherence in any basis. We provide a simple necessary and sufficient analytical criterion to verify multilevel coherence, which leads to a complete classification for three-level systems. We present the robustness of multilevel coherence, a bona fide quantifier which we show to be numerically computable via semidefinite programming and experimentally accessible via multilevel coherence witnesses. We further verify and lower-bound the robustness of multilevel coherence by performing a semi-device-independent phase discrimination task, implemented experimentally with four-level probes in a photonic setup. Our results contribute to understanding the operational relevance of genuine multilevel coherence, also by demonstrating the key role it plays in enhanced phase discrimination---a primitive for quantum communication and metrology---and suggest new ways to reliably test the quantum behaviour of physical systems.
Quantum coherence, present whenever a quantum system exists in a superposition of multiple classically distinct states, marks one of the fundamental departures from classical physics.Quantum coherence has recently been investigated rigorously within a resource-theoretic formalism.However, the finer-grained notion of multilevel coherence, which explicitly takes into account the number of superposed classical states, has remained relatively unexplored.A comprehensive analysis of multilevel coherence, which acts as the singleparty analogue to multipartite entanglement, is essential for understanding natural quantum processes as well as for gauging the performance of quantum technologies.Here, we develop the theoretical and experimental groundwork for characterizing and quantifying multilevel coherence.We prove that nontrivial levels of purity are required for multilevel coherence, as there is a ball of states around the maximally mixed state that do not exhibit multilevel coherence in any basis.We provide a simple, necessary, and sufficient analytical criterion to verify the presence of multilevel coherence, which leads to a complete classification of multilevel coherence for three-level systems.We present the robustness of multilevel coherence, a bona fide quantifier, which we show to be numerically computable via semidefinite programming and experimentally accessible via multilevel coherence witnesses, which we introduce and characterize.We further verify and lower bound the robustness of multilevel coherence by performing a semi-device-independent phase discrimination task, which is implemented experimentally with four-level quantum probes in a photonic setup.Our results contribute to understanding the operational relevance of genuine multilevel coherence, also by demonstrating the key role it plays in enhanced phase discrimination-a primitive for quantum communication and metrology-and suggest new ways to reliably and effectively test the quantum behavior of physical systems.
The development of spectroscopic techniques able to detect and verify quantum coherence is a goal of increasing importance given the rapid progress of new quantum technologies, the advances in the field of quantum thermodynamics, and the emergence of new questions in chemistry and biology regarding the possible relevance of quantum coherence in biochemical processes. Ideally, these tools should be able to detect and verify the presence of quantum coherence in both the transient dynamics and the steady state of driven-dissipative systems, such as light-harvesting complexes driven by thermal photons in natural conditions. This requirement poses a challenge for standard laser spectroscopy methods. Here, we propose photon correlation measurements as a new tool to analyze quantum dynamics in molecular aggregates in driven-dissipative situations. We show that the photon correlation statistics of the light emitted in several models of molecular aggregates can signal the presence of coherent dynamics. Deviations from the counting statistics of independent emitters constitute a direct fingerprint of quantum coherence in the steady state. Furthermore, the analysis of frequency resolved photon correlations can signal the presence of coherent dynamics even in the absence of steady state coherence, providing direct spectroscopic access to the much sought-after site energies in molecular aggregates.
We analyze under which dynamical conditions the coherence of an open quantum system is totally unaffected by noise. For a single qubit, specific measures of coherence are found to freeze under different conditions, with no general agreement between them. Conversely, for an N-qubit system with even N, we identify universal conditions in terms of initial states and local incoherent channels such that all bona fide distance-based coherence monotones are left invariant during the entire evolution. This finding also provides an insightful physical interpretation for the freezing phenomenon of quantum correlations beyond entanglement. We further obtain analytical results for distance-based measures of coherence in two-qubit states with maximally mixed marginals.
Quantum coherence is the key resource for quantum technology, with applications in quantum optics, information processing, metrology and cryptography. Yet, there is no universally efficient method for quantifying coherence either in theoretical or in experimental practice. I introduce a framework for measuring quantum coherence in finite dimensional systems. I define a theoretical measure which satisfies the reliability criteria established in the context of quantum resource theories. Then, I present an experimental scheme implementable with current technology which evaluates the quantum coherence of an unknown state of a d-dimensional system by performing two programmable measurements on an ancillary qubit, in place of the O(d2) direct measurements required by full state reconstruction. The result yields a benchmark for monitoring quantum effects in complex systems, e.g. certifying non-classicality in quantum communication and simulation protocols and probing the quantum behaviour of biological complexes.
Abstract Quantum coherence is one of the most basic characteristics of quantum mechanics. Here we give some methods to detect and measure quantum coherence. Firstly, we propose a coherence criterion without full quantum state tomography based on partial transposition. Moreover, we present a coherent nonlinear detection strategy from witnesses, in which we find that for some coherent states, normal witness detection fails but our nonlinear detection succeeds. In addition, we prove that when the nonlinear detection on the two copies of the coherent state fails, the nonlinear detection on the three copies may be successful. Finally, due to the difficulty in calculating robustness of coherence for general states, we introduce a lower bound for coherent robustness based on the witness operator, and after comparing our lower bound with the currently known lower bound, one show that our lower bound is better. Coherence is believed to play a crucial role in quantum information tasks, making the detection and quantization of coherence particularly significant. Therefore, these results help to open up new avenues for advancement in quantum theory.