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arXiv:2104.08235 · New Journal of Physics

Characterizing the Zeeman slowing force for 40Ca19F molecules

P. Kaebert, M Stepanova, T Poll, M. Petzold, S Xu, M. Siercke, Silke Ospelkaus

Published Aug 18, 2021• 12 citations
arXivHTMLPDF

Abstract

Abstract In this paper we investigate the feasibility of Zeeman slowing calcium monofluoride molecules originating from a cryogenic buffer gas cell. We measure the A 2 Π 1 / 2 ( v = 0 , J = 1 2 ) − X 2 Σ 1 / 2 ( v = 0 , N = 1 ) hyperfine spectrum of CaF in the Paschen–Back regime and find excellent agreement with theory. We then investigate the scattering rate of the molecules in a molecular Zeeman slower by illuminating them with light from a 10 mW broad repumper and a 10 mW multi-frequency slowing laser. By comparing our results to theory we can calculate the photon scattering rate at higher powers, leading to a force profile for Zeeman slowing. We show results from a simple 1D simulation demonstrating that this force is narrow enough in velocity space to lead to significant velocity compression, and slowing of the molecules to trappable velocities.

DOI
10.1088/1367-2630/ac1ed7

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Abstract In this paper we investigate the feasibility of Zeeman slowing calcium monofluoride molecules originating from a cryogenic buffer gas cell. We measure the A 2 Π 1 / 2 ( v = 0 , J = 1 2 ) − X 2 Σ 1 / 2 ( v = 0 , N = 1 ) hyperfine spectrum of CaF in the Paschen–Back regime and find excellent agreement with theory. We then investigate the scattering rate of the molecules in a molecular Zeeman slower by illuminating them with light from a 10 mW broad repumper and a 10 mW multi-frequency slowing laser. By comparing our results to theory we can calculate the photon scattering rate at higher powers, leading to a force profile for Zeeman slowing. We show results from a simple 1D simulation demonstrating that this force is narrow enough in velocity space to lead to significant velocity compression, and slowing of the molecules to trappable velocities.
Cold molecules are an invaluable tool for modern physics. Cold atoms have already revolutionized precision metrology, allowed for spectacular findings in quantum physics and opened the door for the creation and observation of novel states of matter. Cold molecules bring with them additional degrees of freedom which give rise to unique properties that enable new kinds of experiments. For these experiments it is of vital importance to start with a sufficiently large number of cold molecules. There are multiple paths for the slowing and cooling of atoms and most of the slowing techniques utilizing lasers for direct cooling have been transferred to the molecular case with its specific requirements. The Zeeman slowing technique is advantageous for loading a trap with cold particles but had not yet been transferred from atoms to the molecular case. In this thesis I will show the first realization of the Zeeman slowing technique for diatomic molecules. This thesis will discuss several preparatory steps: Our group has had some ideas to collimate the molecular beam with a conical nozzle outlet at the buffer gas cell which I investigated on potassium atoms generated by the ablation of 39K35Cl inside the buffer gas cell. I also realized a fluorescence spectroscopy of the |XΣ1/2, N = 1, v = 0⟩ → |AΠ1/2, N = 0, v = 0⟩ transition in magnetic fields up to 300 G and confirmed simulations regarding our two laser cycling scheme in the Paschen-Back regime by measuring the scattering rate of light on one molecule. Finally, I created pre-cooled 40Ca19F with a forward velocity of around 150 m s−1 from a 40Ca19F2 target with laser ablation inside a cryogenic buffer gas cell. With the Zeeman slowing technique I slowed the molecules down to 25 m s−1, a velocity where trapping can be possible. I have also shown the characteristic compression into specific velocity classes for not yet trappable velocities. Together these two findings demonstrate that molecular Zeeman slowing is possible and a real promising tool for future experiments.
We present a novel slowing scheme for beams of laser-coolable diatomic molecules reminiscent of Zeeman slowing of atomic beams. The scheme results in efficient compression of the one-dimensional velocity distribution to velocities trappable by magnetic or magneto-optical traps. We experimentally demonstrate our method in an atomic testbed and show an enhancement of flux below v = 35 m s −1 by a factor of ≈20 compared to white light slowing. 3D Monte Carlo simulations performed to model the experiment show excellent agreement. We apply the same simulations to the prototype molecule 88 Sr 19 F and expect 15% of the initial flux to be continuously compressed in a narrow velocity window at around 10 m s −1 . This is the first experimentally shown continuous and dissipative slowing technique in molecule-like level structures, promising to provide the missing link for the preparation of large ultracold molecular ensembles.
We present a novel slowing scheme for beams of laser-coolable diatomic molecules reminiscent of Zeeman slowing of atomic beams. The scheme results in efficient compression of the one-dimensional velocity distribution to velocities trappable by magnetic or magneto-optical traps. We experimentally demonstrate our method in an atomic testbed and show an enhancement of flux below v = 35 m s-1 by a factor of ≈20 compared to white light slowing. 3D Monte Carlo simulations performed to model the experiment show excellent agreement. We apply the same simulations to the prototype molecule 88Sr19F and expect 15% of the initial flux to be continuously compressed in a narrow velocity window at around 10 m s-1. This is the first experimentally shown continuous and dissipative slowing technique in molecule-like level structures, promising to provide the missing link for the preparation of large ultracold molecular ensembles. © 2018 The Author(s). Published by IOP Publishing Ltd on behalf of Deutsche Physikalische Gesellschaft.
Laser cooling and trapping in a magneto-optical trap (MOT) have been essential to the success of cold atom physics in the last decades. Recently, the application of the same techniques to molecules has begun. The complexity of even a simple diatomic molecule makes laser cooling difficult, but promises new applications in many areas of research. In this thesis I describe the development of the first three-dimensional MOT of calcium fluoride (CaF) molecules. First, a cryogenic buffer gas source was set up, producing a pulsed beam of 9.3*10^10 molecules per steradian per pulse with forward velocities around 170 m/s. A similar source for very large molecules was set up during a 5 month internship at the University of Vienna. Next, the molecular pulse was slowed down to the capture velocity of a MOT using chirped laser slowing, resulting in about 7*10^5 CaF molecules passing through the typical MOT volume of 1 cm^3 at velocities of 15+-5 m/s. A new deceleration method, called Zeeman-Sisyphus deceleration, was also investigated. In this method molecules move through a spatially varying magnetic field and are optically pumped between low- and high-field seeking states in such as a way that they are always losing kinetic energy. The method promises to deliver more slow molecules because the molecules are guided transversely as they are decelerated. A small prototype was built and the optical pumping step was tested successfully. Finally, 7.6*10^3 CaF molecules were trapped in a MOT and cooled to a temperature of 8.5 mK. The radial trap frequency is 2 pi*130 Hz and the damping constant is beta=9.5*10^2 s^-1. The lifetime is about 100 ms and depends strongly on the scattering rate. This MOT is an an ideal starting point for a wide range of new experiments with ultracold molecules.
We study the properties of a cryogenic buffer gas source that uses a low-temperature two-stage buffer gas cell to produce very slow beams of ytterbium monofluoride molecules. The molecules are produced by laser ablation inside the cell and extracted into a beam by a flow of cold helium. We measure the flux and velocity distribution of the beam as a function of ablation energy, helium flow rate, cell temperature, and the size of the gap between the first and second stages of the cell. We also compare the velocity distributions from one-stage and two-stage cells. The one-stage cell emits a beam with a speed of about 82 m s − 1 and a translational temperature of 0.63 K. The slowest beams are obtained using the two-stage cell at the lowest achievable cell temperature of 1.8 K. This beam has a peak velocity of 56 m s − 1 and a flux of 9 × 10 9 ground-state molecules per steradian per pulse, with a substantial fraction at speeds below 40 m s − 1 . These slow molecules can be decelerated further by radiation pressure slowing and then captured in a magneto-optical trap. Published by the American Physical Society 2024