Abstract Heat generated as a result of the breakdown of an adiabatic process is one of the central concepts of thermodynamics. In isolated systems, the heat can be defined as an energy increase due to transitions between distinct energy levels. Across a second-order quantum phase transition (QPT), the heat is predicted theoretically to exhibit a power-law scaling, but it is a significant challenge for an experimental observation. In addition, it remains elusive whether a power-law scaling of heat can exist for a first-order QPT. Here we experimentally observe a power-law scaling of heat in a spinor condensate when a system is linearly driven from a polar phase to an antiferromagnetic (AFM) phase across a first-order QPT. We experimentally evaluate the heat generated during two non-equilibrium processes by probing the atom number on a hyperfine energy level. The experimentally measured scaling exponents agree well with our numerical simulation results. Our work therefore opens a new avenue to experimentally and theoretically exploring the properties of heat in non-equilibrium dynamics.
Abstract Heat generated as a result of the breakdown of an adiabatic process is one of the central concepts of thermodynamics. In isolated systems, the heat can be defined as an energy increase due to transitions between distinct energy levels. Across a second-order quantum phase transition (QPT), the heat is predicted theoretically to exhibit a power-law scaling, but it is a significant challenge for an experimental observation. In addition, it remains elusive whether a power-law scaling of heat can exist for a first-order QPT. Here we experimentally observe a power-law scaling of heat in a spinor condensate when a system is linearly driven from a polar phase to an antiferromagnetic (AFM) phase across a first-order QPT. We experimentally evaluate the heat generated during two non-equilibrium processes by probing the atom number on a hyperfine energy level. The experimentally measured scaling exponents agree well with our numerical simulation results. Our work therefore opens a new avenue to experimentally and theoretically exploring the properties of heat in non-equilibrium dynamics.
The Kibble-Zurek mechanism provides a unified theory to describe the universal scaling laws in the dynamics when a system is driven through a second-order quantum phase transition. However, for first-order quantum phase transitions, the Kibble-Zurek mechanism is usually not applicable. Here, we experimentally demonstrate and theoretically analyze a power-law scaling in the dynamics of a spin-1 condensate across a first-order quantum phase transition when a system is slowly driven from a polar phase to an antiferromagnetic phase. We show that this power-law scaling can be described by a generalized Kibble-Zurek mechanism. Furthermore, by experimentally measuring the spin population, we show the power-law scaling of the temporal onset of spin excitations with respect to the quench rate, which agrees well with our numerical simulation results. Our results open the door for further exploring the generalized Kibble-Zurek mechanism to understand the dynamics across first-order quantum phase transitions.
We study the equilibrium and dynamical properties of a ferromagnetic spinor atomic Bose-Einstein condensate. In the vicinity of the critical point for a continuous quantum phase transition, universal behaviors are observed both in the equilibrium state and in the dynamics when the quadratic Zeeman shift is swept linearly. Three distinct dynamical regions are identified for different sweeping time scales ($\ensuremath{\tau}$) when compared to the time scale ${\ensuremath{\tau}}_{\mathrm{KZ}}\ensuremath{\sim}{N}^{(1+\ensuremath{\nu}z)/\ensuremath{\nu}d}$ decided by external driving in a system with finite size N ($\ensuremath{\nu},z$ are critical exponents and d the dimensionality). They are manifested by the excitation probability P and the excess heat density Q. The adiabatic region of $\mathcal{P}\ensuremath{\sim}\mathcal{Q}\ensuremath{\sim}{\ensuremath{\tau}}^{\ensuremath{-}2}$ follows from the adiabatic perturbation theory when $\ensuremath{\tau}>{\ensuremath{\tau}}_{\mathrm{KZ}}$, while the nonadiabatic universal region of $\mathcal{P}\ensuremath{\sim}\mathcal{Q}\ensuremath{\sim}{\ensuremath{\tau}}^{\ensuremath{-}1}$ in the thermodynamic limit is described by the Kibble-Zurek mechanism when ${\ensuremath{\tau}}_{\mathrm{KZ}}>\ensuremath{\tau}>$ the time scale given by initial gap. The Kibble-Zurek scaling hypothesis is augmented with finite-size scaling in the latter region and several experimentally falsifiable features for the finite system we consider are predicted. The region of the fastest sweeping is found to be nonuniversal and far from equilibrium, with P and Q essentially being constants independent of $\ensuremath{\tau}$.
Abstract Symmetry-breaking quantum phase transitions lead to the production of topological defects or domain walls in a wide range of physical systems. In second-order transitions, these exhibit universal scaling laws described by the Kibble–Zurek mechanism, but for first-order transitions a similarly universal approach is still lacking. Here, we propose a spinor Bose–Einstein condensate as a testbed system where critical scaling behaviour in a first-order quantum phase transition can be understood from generic properties. We demonstrate the applicability of the Kibble–Zurek mechanism for this transition to determine the critical exponents for: (1) the onset of the decay of the metastable state on short times scales, and (2) the number of resulting phase-separated ferromagnetic domains at longer times, as a one-dimensional spin-1 condensate is ramped across a first-order quantum phase transition. The predictions are in excellent agreement with mean-field numerical simulations and provide a paradigm for studying the decay of metastable states in experimentally accessible systems.
This thesis discusses non-equilibrium phenomena in antiferromagnetic spinor quantum gases. We investigate, both experimentally and theoretically, the quench dynamics of antiferromagnetic spinor Bose-Einstein condensates in the vicinity of a zero temperature quantum phase transition. A microwave dressing field was used as a novel tool to access the polar to antiferrmagnetic quantum phase transition at the quadratic Zeeman shift, q=0. By performing instantaneous quenches across the phase transition,a dynamical instability was induced in the atomic cloud. This lead to pair formation and rapid amplification of spin +/-1 atoms through spin-mixing collisions. The spatial ordering kinetics in the vicinity of the phase transition was quantified by performing the local spin measurement. The coarsening dynamics was observed for the instability for q < 0, as it nucleated small domains that grew to the axial size of the cloud. Rich nonequilibrium behavior was observed in the form of growth and decay of both nematic and magnetic spin waves, following the quench. The spatiotemporal evolution was characterized through two particle correlations between atoms in each pair of spin states, which revealed dramatic differences between the dynamics of the spin correlations and those of the spin populations. \nFinally, we demonstrate the remarkable influence of linear Zeeman term on non-equilibrium dynamics of spinor Bose-Einstein condensates. We show that contrary to prior understanding magnetic field gradient actually suppresses the tendency of spin 0 state to separate into spin +/-1 state. This reconciles the Bogoliubov discrepancies and leads to a dramatic sharpening of the transition point, resulting in a resolution at the 1 Hz level. Our results point to the use of dynamics, rather than equilibrium quantities for high precision measurements of phase transitions in quantum gases.
Abstract Driving a quantum many-body system across the quantum phase transition (QPT) in the finite time has been concerned in different branches of physics to explore various fundamental questions. Here, we analyze how the underlying QPT affects the work distribution P (W ), when the control parameter of a ferromagnetic spinor Bose-Einstein condensates is tuned through the critical point in the finite time. We show that the work distribution undergoes a dramatic change with increasing the driving time τ. To capture the characteristics of the work distribution, we analyze the entropy of P (W ) and find three different regions in the evolution of entropy as a function of τ. Specifically, the entropy is insensitive to the driving time in the region of very short τ, while it exhibits a universal power-law decay in the region with intermediate value of τ. In particular, the power-law scaling of the entropy is according with the well-known Kibble-Zurek mechanism. For the region with large τ, the validity of the adiabatic perturbation theory leads to the entropy decay as τ-2 ln τ. Our results verify the usefulness of the entropy of the work distribution for understanding the critical dynamics and provide an alternative way to experimentally study nonequilibrium properties in quantum many-body systems.
Entanglement lies at the core of emergent quantum technologies such as quantum-enhanced metrology, quantum communication and cryptography, and quantum simulation and computing. Spinor Bose-Einstein condensates (BECs) offer a promising platform for the generation and application of entangled states. For example, a spin-1 BEC has served for the proof-of-principle demonstration of a quantum-enhanced atomic clock. Ferromagnetic spin-1 BECs with zero magnetization exhibit three ground-state quantum phases with different entanglement properties. The control parameter can be tuned by a magnetic field or by microwave dressing. As already experimentally demonstrated, an entangled ground state can be reached from a well accessible, non-entangled one by driving the control parameter across quantum phase transitions (QPTs). We investigate which of the entangled ground states afford quantum-enhanced interferometry. The interferometric usefulness is quantified by the quantum Fisher information (QFI), which we analyze throughout all ground-state phases. A large QFI at about half the Heisenberg limit, and thus far above the standard quantum limit, is attained by the well-known Twin-Fock state and by the central broken-axisymmetry (CBA) state. We detail how the CBA state can be used as a probe for quantum-enhanced interferometry. Furthermore, we observe that the large QFI of the CBA state can be traced back to enclosed macroscopic superposition states (MSSs). Measuring the atom number in one out of three modes generates, with high probability and heralded by the measurement outcome, a MSS similar to a NOON state. Our proposal promises NOON-like MSSs of unprecedentedly many atoms. Both proposed applications of the adiabatically prepared CBA state depend only on existent technology. Our numerical results show that they tolerate a reasonably swift quasiadiabatic passage in the presence of atom loss as well as uncertainties of atom counting. Excited-state quantum phase transitions (ESQPTs) extend the concept of QPTs beyond the ground state. While they have been extensively investigated theoretically, there are only few experimental results. From the perspective of quantum-state engineering, it is furthermore surprising how rarely order parameters of ESQPTs are discussed in the literature. Mean-field models for spinor BECs imply ESQPTs, to which some experimental observations on the mean-field dynamics can be attributed. However, so far, neither theoretical nor experimental studies have specifically addressed ESQPTs in spinor BECs. We extend the ground-state phase diagram of ferromagnetic spin-1 BECs with zero magnetization across the spectrum. There are three excited-state phases, corresponding to one ground-state phase each. The ESQPTs are signaled by a diverging density of states. The mean-field phase-space trajectories can be characterized by a winding number that is in one-to-one correspondence to the excited-state phases. We derive a closely related order parameter encoded in the dynamics of coherent states and discuss how this order parameter can be interferometrically measured in current experiments. Remarkably, the mean-field model governing the ESQPTs in spin-1 BECs with zero magnetization is encountered also, e. g., in molecular and nuclear physics. Because of the superior experimental control, spinor BECs can be considered as simulators of the ESQPTs in those systems. Our results contribute to quantum-state engineering and quantum-enhanced interferometry in spinor BECs and to the characterization of excited-state quantum phases. The latter may, in turn, lead on to applications in quantum-state engineering.