Abstract Ginzburg-Landau theory of continuous phase transitions implicitly assumes that microscopic changes are negligible in determining the thermodynamic properties of the system. In this work we provide an example that clearly contrasts with this assumption. In particular, we consider the 2-cluster-Ising model, a one-dimensional spin-1/2 system that is known to exhibit a quantum phase transition between a magnetic and a nematic phase. By imposing boundary conditions that induce topological frustration we show that local order is completely destroyed on both sides of the transition and that the two thermodynamic phases can only be characterized by string order parameters. Having proved that topological frustration is capable of altering the nature of a system's phase transition, this result is a clear challenge to current theories of phase transitions in complex quantum systems.
Abstract Ginzburg-Landau theory of continuous phase transitions implicitly assumes that microscopic changes are negligible in determining the thermodynamic properties of the system. In this work we provide an example that clearly contrasts with this assumption. In particular, we consider the 2-cluster-Ising model, a one-dimensional spin-1/2 system that is known to exhibit a quantum phase transition between a magnetic and a nematic phase. By imposing boundary conditions that induce topological frustration we show that local order is completely destroyed on both sides of the transition and that the two thermodynamic phases can only be characterized by string order parameters. Having proved that topological frustration is capable of altering the nature of a system's phase transition, this result is a clear challenge to current theories of phase transitions in complex quantum systems.
Frustration in many-body spin systems is a situation where the spins cannot orient themselves to fully minimize the interactions with their neighbors. It is caused, in general, by competing interactions or by the lattice structure, as in the antiferromagnets on non-bipartite lattices. Over the years frustrated systems have been studied substantially, since frustration can destabilize the antiferromagnetic order, lead to different phases of matter and induce various exotic properties. Frustration can be caused also by a choice of boundary conditions, i.e. the lattice topology. For instance, a ring with an odd number of sites is non-bipartite, which makes antiferromagnets in this setting frustrated. The subject of this thesis are zero-temperature one-dimensional quantum systems exactly in this setting. The major content is discussing how such a simple setting can influence the antiferromagnetic order, by studying spin-1/2 chains with discrete symmetries, whose breaking is related to the onset of the order. After reviewing the known results on topological frustration, dealing with non-thermodynamic quantities, we develop an approach for studying symmetry breaking, that is both suitable for exact analytical computations and meaningful for discussing the order also in a finite system. It consists of the realization that many spin-1/2 chains without external magnetic fields, such as the quantum XY chain, possess anticommuting global symmetries when the number of lattice sites is an odd number, implying the ground-state degeneracy already in a finite system. In this framework, we discover that topological frustration, despite being induced only by the choice of boundary conditions and even/odd system size choice, can affect the magnetization in the thermodynamic limit and system's quantum phase transitions. We find that topological frustration can destroy local order, create a site-dependent magnetization that varies in space with an incommensurate pattern, induce a first-order quantum phase transition that is not present without frustration and modify the nature of a second-order transition, by destroying local order at both sides of the transition and preserving only non-local string order parameters. All these results indicate the incompleteness of the approach to quantum many-body systems, based on the Ginzburg-Landau theory, that tries to capture the properties of the system by taking the system size to infinity before computing the observables and neglects the influence of the chain length as a relevant scale. We find that topological frustration can affect also non-equilibrium properties, by considering a local quantum quench setup. Namely, we study the Loschmidt echo and find it displays qualitatively and quantitatively different behavior for antiferromagnetic rings with an even and odd number of sites. Most of all, the differences become clearer for large system sizes, thus allowing to distinguish in a simple out-of-equilibrium experiment a system made by a certain, large, number of spins from the one with a single additional spin. The thesis also contains a mathematical part. In studying order parameters of models mappable to free fermions, Toeplitz determinants with symbols that possess a part proportional to the delta function arise. We derive asymptotic formulas for this type of determinants.
Abstract In quantum many-body systems with local interactions, the effects of boundary conditions are considered to be negligible, at least for sufficiently large systems. Here we show an example of the opposite. We consider a spin chain with two competing interactions, set on a ring with an odd number of sites. When only the dominant interaction is antiferromagnetic, and thus induces topological frustration, the standard antiferromagnetic order (expressed by the magnetization) is destroyed. When also the second interaction turns from ferro to antiferro, an antiferromagnetic order characterized by a site-dependent magnetization which varies in space with an incommensurate pattern, emerges. This modulation results from a ground state degeneracy, which allows to break the translational invariance. The transition between the two cases is signaled by a discontinuity in the first derivative of the ground state energy and represents a quantum phase transition induced by a special choice of boundary conditions.
Abstract Landau theory’s implicit assumption that microscopic details cannot affect the global phases has been challenged only recently in systems such as antiferromagnetic quantum spin chains with periodic boundary conditions. The new paradigm of topological frustration has been accordingly put forward. In this context, the quantum phases exhibit a dependence on the boundary conditions. In this work, we show that topological frustration modifies the zero temperature phase diagram of the XY chain in a transverse magnetic field by inducing new boundary quantum phase transitions. Here, by boundary quantum phase transitions we mean non-analyticities that are non-extensive in the number of particles. Such transitions are both of first and second order. Moreover, we come across the first case of second order boundary quantum phase transition characterized by a quartic dispersion relation. Our analytical results are supported by both analytical calculations and numerical investigations, and lay the foundation for understanding the phase diagram of frustrated model.
Recently it was highlighted that one-dimensional antiferromagnetic spin models with frustrated boundary conditions, i.e. periodic boundary conditions in a ring with an odd number of elements, may show very peculiar behavior. Indeed the presence of frustrated boundary conditions can destroy the local magnetic orders presented by the models when different boundary conditions are taken into account and induce novel phase transitions. Motivated by these results, we analyze the effects of the introduction of frustrated boundary conditions on several models supporting (symmetry protected) topological orders, and compare our results with the ones obtained with different boundary conditions. None of the topological order phases analyzed are altered by this change. This observation leads naturally to the conjecture that topological phases of one-dimensional systems are in general not affected by topological frustration.
We have introduced a novel Majorana representation of S=1/2 spins using the Jordan-Wigner transformation and have shown that a generalized spin model of Kitaev defined on a brick-wall lattice is equivalent to a model of noninteracting Majorana fermions with Z2 gauge fields without redundant degrees of freedom. The quantum phase transitions of the system at zero temperature are found to be of topological type and can be characterized by nonlocal string order parameters (SOP). In appropriate dual representations, these SOP become local order parameters and the basic concept of Landau theory of continuous phase transition can be applied.
A quantum Ising model in a transverse field is of the simplest quantum many-body systems used for studying universal properties of quantum phase transitions. Interestingly, it is well known that such phase transitions can be mapped to topological phase transitions in toric code models. Therefore, one can expect that well-known properties of the transverse Ising model are used for characterizing topological phase transitions in toric code models. In this paper, we consider the magnetization of the Ising model and show, while it is a local order parameter, it is mapped to a nonlocal order parameter on the topological side. Consequently, we introduce a string order parameter for topological phase transitions in toric code models defined on different lattices with different dimensions in the presence of a uniform magnetic field. Since such a string order parameter is dual of the Ising order parameter with well-known properties, it leads to a topological (nonlocal) characterization of phase transition in the toric code model in uniform field. Our results show that although topological phase transitions do not follow a symmetry-breaking mechanism, it might still be possible to use concepts of symmetry-breaking phase transitions for topological ones by finding suitable mappings.