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arXiv:2012.07611 · Physical Review A

Fast-forward scaling of atom-molecule conversion in Bose-Einstein condensates

J. J. Zhu, Xi Chen

Published Feb 4, 2021• 20 citations
arXivHTMLPDF

Abstract

Robust stimulated Raman exact passages are requisite for controlling nonlinear quantum systems, with wide applications, ranging from ultracold molecules to nonlinear optics to superchemistry. Inspired by shortcuts to adiabaticity, we propose the fast-forward scaling of stimulated Raman adiabatic processes with nonlinearity involved, describing the transfer from an atomic Bose-Einstein condensate to a molecular one by controllable external fields. The fidelity and robustness of atom-molecule conversion are shown to surpass those of conventional adiabatic passages, assisted by the fast-forward driving field. Finally, our results are extended to fractional stimulated Raman adiabatic processes for the coherent superposition of atomic and molecular states.

DOI
10.1103/physreva.103.023307

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Robust stimulated Raman exact passages are requisite for controlling nonlinear quantum systems, with wide applications, ranging from ultracold molecules to nonlinear optics to superchemistry. Inspired by shortcuts to adiabaticity, we propose the fast-forward scaling of stimulated Raman adiabatic processes with nonlinearity involved, describing the transfer from an atomic Bose-Einstein condensate to a molecular one by controllable external fields. The fidelity and robustness of atom-molecule conversion are shown to surpass those of conventional adiabatic passages, assisted by the fast-forward driving field. Finally, our results are extended to fractional stimulated Raman adiabatic processes for the coherent superposition of atomic and molecular states.
Summary form only given. Coherent conversion of an atomic to a molecular Bose-Einstein condensate (BEC) is a first step towards 'superchemistry', which is the atom optics analog of frequency conversion in nonlinear optics. A number of studies of this have shown that direct conversion via Raman photo-association appears feasible, based on stimulated free-bound and bound-bound transitions in the presence of two laser fields E/sup (1)/=E/sub 0//sup (1)/ cos(/spl omega//sup (1)/t) and E/sup (2)/=E/sub 0//sup (2)/ cos(/spl omega//sup (2)/t). Here pairs of atoms from the two-atom continuum are transferred-via an excited bound molecular state-to a bound molecular state of lower energy. Raman photo-association allows coupling to a single molecular state, which can be selected by the Raman laser frequencies /spl omega//sup (1)/ and /spl omega//sup (2)/. However, practical calculations using available lasers and transitions indicate that coherent transfer is often limited by spontaneous emission from the intermediate molecular excited electronic state. A possible route towards minimizing losses and decoherence from spontaneous emission is to use the stimulated Raman adiabatic passage (STIRAP) method (Drummond et al, Phys. Rev. Lett. vol. 81, p. 3055, 1998) in which a counter-intuitive pulse sequence is used where the first input pulse couples the molecular levels, even when there are no molecules present.
Accurate control of a quantum system is a fundamental requirement in many areas of modern science ranging from quantum information processing to high-precision measurements. A significantly important goal in quantum control is preparing a desired state as fast as possible, with sufficiently high fidelity allowed by available resources and experimental constraints. Stimulated Raman adiabatic passage (STIRAP) is a robust way to realize high-fidelity state transfer but it requires a sufficiently long operation time to satisfy the adiabatic criteria. Here we theoretically propose and then experimentally demonstrate a shortcut-to-adiabatic protocol to speed-up the STIRAP. By modifying the shapes of the Raman pulses, we experimentally realize a fast and high-fidelity stimulated Raman shortcut-to-adiabatic passage that is robust against control parameter variations. The all-optical, robust and fast protocol demonstrated here provides an efficient and practical way to control quantum systems.
A set of nonlinear evolution equations describing the dynamics of atoms, molecules, and photons in the course of stimulated atomic-molecular conversion in a Bose-Einstein condensate is derived and studied in the mean-field approximation. It is shown that conversion can be periodic or aperiodic in time, the rate of the process being determined to a considerable extent by the initial density of particles and by the initial phase difference. Depending on the initial conditions, various conversion modes can be realized. The possibility of stabilization of a special state (of rest) of the system for nonzero initial number densities of particles is predicted. It is pointed out that coherence of a Bose condensate of atoms, molecules, and photons predetermines the possibility of phase control of the conversion process.
Accurate control of a quantum system is a fundamental requirement in many areas of modern science ranging from quantum information processing to high-precision measurements. A significantly important goal in quantum control is to prepare a desired state as fast as possible with sufficiently high fidelity allowed by available resources and experimental constraints. Stimulated Raman adiabatic passage (STIRAP) is a robust way to realize high-fidelity state transfer but it requires a sufficiently long operation time to satisfy the adiabatic criteria. We here theoretically propose and then experimentally demonstrate a shortcut-to-adiabatic protocol to speed up the STIRAP. By modifying the shapes of the Raman pulses, we experimentally realize a fast and high-fidelity stimulated Raman shortcut-to-adiabatic passage that is robust against control parameter variations. The all-optical, robust, and fast protocol demonstrated here provides an efficient and practical way to control quantum systems.
We theoretically examine Raman photoassociation of a Bose-Einstein condensate, revisiting stimulated Raman adiabatic passage (STIRAP). Due to collisional mean-field shifts, efficient molecular conversion requires strong coupling and low density, either of which can bring about rogue photodissociation to noncondensate modes. We demonstrate explicitly that rogue transitions are negligible for low excited-state fractions and photodissociation that is slower than the STIRAP time scale. Moreover, we derive a reduced-parameter model of collisions, and thereby find that a gain in the molecular conversion efficiency can be obtained by adjusting the atom-atom scattering length with off-resonant magnetoassociation. This gain saturates when the atom-atom scattering length is tuned to a specific fraction of either the molecule-molecule or atom-molecule scattering length. We conclude that a fully optimized STIRAP scheme may offer the best chance for achieving coherent conversion from an atomic to a molecular condensate with photoassociation.
A set of nonlinear evolution equations describing the dynamics of atoms, molecules, and photons in the course of stimulated atomic—molecular conversion in a Bose—Einstein condensate is derived and studied in the mean-field approximation. It is shown that conversion can be periodic or aperiodic in time, the rate of the process being determined to a considerable extent by the initial density of particles and by the initial phase difference. Depending on the initial conditions, various conversion modes can be realized. The possibility of stabilization of a special state (of rest) of the system for nonzero initial number densities of particles is predicted. It is pointed out that coherence of a Bose condensate of atoms, molecules, and photons predetermines the possibility of phase control of the conversion process.