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arXiv:2012.06741 · Contributions to Plasma Physics

Thermodynamic coefficients of ideal Fermi gas

Alexey Kozharin, Pavel R. Levashov

Published Oct 1, 2021• 3 citations
arXivHTMLPDF

Abstract

Abstract We present analytical formulae for the first and second derivatives of the Helmholtz free energy of non‐relativistic ideal Fermi gas. Important thermodynamic quantities such as heat capacity, sound velocity, heat capacity ratio, and others are explicitly expressed through the derivatives. We demonstrate correct ideal Boltzmann gas and low‐temperature Fermi gas asymptotes and derive corrections to thermodynamic functions for these limiting cases. Numerical computations of thermodynamic properties of ideal Fermi gas can be accurately performed using the developed freely available Python module ifg.

DOI
10.1002/ctpp.202100139

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Abstract We present analytical formulae for the first and second derivatives of the Helmholtz free energy of non‐relativistic ideal Fermi gas. Important thermodynamic quantities such as heat capacity, sound velocity, heat capacity ratio, and others are explicitly expressed through the derivatives. We demonstrate correct ideal Boltzmann gas and low‐temperature Fermi gas asymptotes and derive corrections to thermodynamic functions for these limiting cases. Numerical computations of thermodynamic properties of ideal Fermi gas can be accurately performed using the developed freely available Python module ifg.
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The properties of an ideal Fermi gas in an external potential in any dimensional space are studied, based on the semiclassical (Thomas-Fermi) approximation. The general analytical expressions of the total particle number N,N,N, density of states $D(\ensuremath{\varepsilon}),$ Fermi energy EF,{E}_{F},EF​, total energy E,E,E, and heat capacity CCC have been derived, where N,N,N, E,E,E, and CCC are expressed by the Fermi integration. Moreover, the analytical expressions of the total energy E,E,E, chemical potential \ensuremath{\mu}, and heat capacity CCC in the high- and low-temperature approximations are given. From these results, how the characteristics of the Fermi gas depend on an external potential and the dimension of space is discussed.