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arXiv:2012.06505 · Physical review. B./Physical review. B

Quantum chaos and ensemble inequivalence of quantum long-range Ising chains

Angelo Russomanno, Michele Fava, Markus Heyl

Published Sep 27, 2021• 32 citations
arXivHTMLPDF

Abstract

We use large-scale exact diagonalization to study the quantum Ising chain in a transverse field with long-range power-law interactions decaying with exponent $\ensuremath{\alpha}$. We numerically study various probes for quantum chaos and eigenstate thermalization on the level of eigenvalues and eigenstates. The level-spacing statistics yields a clear sign towards a Wigner-Dyson distribution and therefore towards quantum chaos across all values of $\ensuremath{\alpha}>0$. Yet, for $\ensuremath{\alpha}<1$ we find that the microcanonical entropy is nonconvex. This is due to the fact that the spectrum is organized in energetically separated multiplets for $\ensuremath{\alpha}<1$. While quantum chaotic behavior develops within the individual multiplets, many multiplets do not overlap and do not mix with each other, as we analytically and numerically argue. Our findings suggest that a small fraction of the multiplets could persist at low energies for $\ensuremath{\alpha}\ensuremath{\ll}1$ even for large $N$, giving rise to ensemble inequivalence.

DOI
10.1103/physrevb.104.094309

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We use large-scale exact diagonalization to study the quantum Ising chain in a transverse field with long-range power-law interactions decaying with exponent \ensuremathα\ensuremath{\alpha}\ensuremathα. We numerically study various probes for quantum chaos and eigenstate thermalization on the level of eigenvalues and eigenstates. The level-spacing statistics yields a clear sign towards a Wigner-Dyson distribution and therefore towards quantum chaos across all values of \ensuremathα>0\ensuremath{\alpha}>0\ensuremathα>0. Yet, for \ensuremathα<1\ensuremath{\alpha}<1\ensuremathα<1 we find that the microcanonical entropy is nonconvex. This is due to the fact that the spectrum is organized in energetically separated multiplets for \ensuremathα<1\ensuremath{\alpha}<1\ensuremathα<1. While quantum chaotic behavior develops within the individual multiplets, many multiplets do not overlap and do not mix with each other, as we analytically and numerically argue. Our findings suggest that a small fraction of the multiplets could persist at low energies for \ensuremathα\ensuremath≪1\ensuremath{\alpha}\ensuremath{\ll}1\ensuremathα\ensuremath≪1 even for large NNN, giving rise to ensemble inequivalence.
We study eigenstate thermalization and related signatures of quantum chaos in the one-dimensional ferromagnetic transverse-field Ising model with power-law interactions. The presence of long-range interactions allows for a finite-temperature phase transition despite the one-dimensional geometry of the model. Unlike previous studies of eigenstate thermalization in non-disordered systems with finite temperature phase transitions, our model possesses sufficiently many energy eigenstates below the critical energy density to allow us to make a definitive statement about the presence of eigenstate thermalization and chaotic level statistics in the broken-symmetry phase.
We investigate thermalization in finite quantum systems with strong long-range interactions. Nearly conserved quantities inherited from the fully connected limit organize the Hilbert space into weakly coupled sectors and split the many-body spectrum into energy bands. Despite the resulting breakdown of global ergodicity, quantum chaos develops within individual energy bands, enabling the definition of microcanonical ensembles within the bands. This supports a band-resolved formulation of thermalization, which we term fragmented eigenstate thermalization hypothesis (fETH). Unlike conventional ETH, finite-size scaling in fETH obeys a symmetry-imposed selection rule that restricts which system sizes can be compared. This band-resolved description has consequences for equilibrium statistical mechanics. While microcanonical ensembles remain confined to a single band, canonical ensembles mix different bands. This mismatch explains ensemble inequivalence without invoking equilibrium phase transitions. Our results apply broadly to Hamiltonians near a fully permutation-symmetric limit.
In classical systems, chaos is clearly defined via the behavior of trajectories. In quantum systems with a classical analogue one finds that the transition from regular to chaotic dynamics is signified by a change in the spectral statistics. This has been found to remain true for quantum systems with no classical analogue, including many-body systems. Furthermore, quantum chaotic systems explore all the allowed configurations in the Hilbert space, i.e. they are ergodic, while integrable systems, and systems in the many-body localized phase, are restricted to a certain subspace of the available phase space, and hence strongly break ergodicity. In this dissertation, we study the intermediate behavior between ergodicity and localization, i.e. the weak breaking of ergodicity. The model examined is the PXP spin chain model, where spins are allowed to flip only under certain kinetic constraints. We start by reproducing some already established results. First, we explore the eigenstate thermalization hypothesis (ETH) for this model and demonstrate the existence of a small number of states, throughout the PXP spectrum, that violate the ETH. Then we study the level-spacing statistics of the model, a well-known quantum chaos diagnostic, which turns out to be close to semi-Poisson and approach Wigner--Dyson statistics for large system sizes. Moreover, we examine various aspects of the model that have not been studied before. For example, the eigenvector component statistics, another quantum chaos diagnostic, for the PXP model turn out to be non-Gaussian. Finally, we perform a quench, in order to study how the energy spreads throughout the system, and observe ballistic fronts.
We investigate signatures of quantum chaos within Ising spin chains subjected to transverse and longitudinal fields, incorporating both local (nearest-neighbor) and non-local (long-range) couplings. While local Ising models may exhibit integrable or chaotic dynamics contingent on interaction strengths and field parameters, systems with non-local interactions generally display a stronger propensity toward chaos, even when the non-local couplings are weak. By examining the distribution of energy level spacings through the level spacing ratio, we delineate the transition from integrable to chaotic regimes and characterize the emergence of quantum chaos in these systems. Our analysis demonstrates that non-local couplings facilitate faster operator spreading and more intricate dynamical behavior, enabling these systems to approach maximal chaos more readily than their local counterparts. Additionally, we analyze Krylov complexity as a dynamical probe of chaos, observing a characteristic peak followed by a plateau at late times in chaotic regimes. This behavior provides a quantitative means to distinguish between integrable and chaotic phases, with the growth rate and saturation level of the complexity serving as effective indicators. Our findings underscore the role of non-local interactions in accelerating the onset of chaos and modifying dynamical complexity in quantum spin chains.
Our current understanding of quantum chaos in many-body quantum systems hinges on the random matrix theory (RMT) behavior of eigenstates and their energy level statistics. Although RMT has been remarkably successful in describing "coarse" features of many-body quantum Hamiltonians in chaotic regimes, such as the Wigner-Dyson level spacing statistics or the volume-law behavior of eigenstate entanglement entropy, it remains a challenge to describe their "finer" features, particularly those arising from spatial locality. Here, we show that we can accurately describe the statistical behavior of eigenstate ensembles in many-body Hamiltonians by using pure random states with physical constraints that capture the essential features of the Hamiltonian, specifically spatial locality and symmetries. We demonstrate our approach on local spin Hamiltonians with a scalar U(1) charge. By constructing ensembles of constrained random states that account for two commuting scalar charges playing the role of energy and magnetization, we describe the patterns of entanglement of midspectrum eigenstates beyond their average volume-law behavior, including O(1) corrections and fluctuations, analytically and numerically. When defining the correspondence between quantum chaotic eigenstates in many-body Hamiltonians and RMT ensembles, our work highlights the important role played by spatial locality in describing universal features beyond the volume-law behavior.
A characteristic feature of “quantum chaotic” systems is that their eigenspectra and eigenstates display universal statistical properties described by random matrix theory (RMT). However, eigenstates of local systems also encode structure beyond RMT. To capture this feature, we introduce a framework that allows us to compare the properties of eigenstates in local systems with those of pure random states. In particular, our framework defines a notion of distance between quantum state ensembles that utilizes the Kullback-Leibler divergence to compare the microcanonical distribution of entanglement entropy (EE) of eigenstates with a reference RMT distribution generated by pure random states (with appropriate constraints). This notion gives rise to a quantitative metric for quantum chaos that not only accounts for averages of the distributions but also higher moments. The differences in moments are compared on a highly resolved scale set by the standard deviation of the RMT distribution, which is exponentially small in system size. As a result, the metric can distinguish between chaotic and integrable behaviors and, in addition, quantify and compare the of chaos (in terms of proximity to RMT behavior) between two systems that are assumed to be chaotic. We implement our framework in local, minimally structured, Floquet random circuits, as well as a canonical family of many-body Hamiltonians, the mixed-field Ising model (MFIM). Importantly, for Hamiltonian systems, we find that the reference random distribution must be appropriately constrained to incorporate the effect of energy conservation in order to describe the ensemble properties of midspectrum eigenstates. The metric captures deviations from RMT across all models and parameters, including those that have been previously identified as strongly chaotic, and for which other diagnostics of chaos such as level spacing statistics look strongly thermal. In Floquet circuits, the dominant source of deviations is the second moment of the distribution, and this persists for all system sizes. For the MFIM, we find significant variation of the KL divergence in parameter space. Notably, we find a small region where deviations from RMT are minimized, suggesting that “maximally chaotic” Hamiltonians may exist in fine-tuned pockets of parameter space. Published by the American Physical Society 2024