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arXiv:2011.08020 · Annales Henri Poincaré

Resource Theory of Heat and Work with Non-commuting Charges

Zahra Baghali Khanian, Manabendra Nath Bera, Arnau Riera, Maciej Lewenstein, Andreas Winter

Published Nov 30, 2022• 7 citations
arXivHTMLPDF

Abstract

Abstract We consider a theory of quantum thermodynamics with multiple conserved quantities (or charges). To this end, we generalize the seminal results of Sparaciari et al. (Phys. Rev. A 96:052112, 2017) to the case of multiple, in general non-commuting charges, for which we formulate a resource theory of thermodynamics of asymptotically many non-interacting systems. To every state we associate the vector of its expected charge values and its entropy, forming the phase diagram of the system. Our fundamental result is the Asymptotic Equivalence Theorem, which allows us to identify the equivalence classes of states under asymptotic approximately charge-conserving unitaries with the points of the phase diagram. Using the phase diagram of a system and its bath, we analyze the first and the second laws of thermodynamics. In particular, we show that to attain the second law, an asymptotically large bath is necessary. In the case that the bath is composed of several identical copies of the same elementary bath, we quantify exactly how large the bath has to be to permit a specified work transformation of a given system, in terms of the number of copies of the “elementary bath” systems per work system (bath rate). If the bath is relatively small, we show that the analysis requires an extended phase diagram exhibiting negative entropies. This corresponds to the purely quantum effect that at the end of the process, system and bath are entangled, thus permitting classically impossible transformations (unless the bath is enlarged). For a large bath, or many copies of the same elementary bath, system and bath may be left uncorrelated and we show that the optimal bath rate, as a function of how tightly the second law is attained, can be expressed in terms of the heat capacity of the bath. Our approach solves a problem from earlier investigations about how to store the different charges under optimal work extraction protocols in physically separate batteries.

DOI
10.1007/s00023-022-01254-1

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Abstract We consider a theory of quantum thermodynamics with multiple conserved quantities (or charges). To this end, we generalize the seminal results of Sparaciari et al. (Phys. Rev. A 96:052112, 2017) to the case of multiple, in general non-commuting charges, for which we formulate a resource theory of thermodynamics of asymptotically many non-interacting systems. To every state we associate the vector of its expected charge values and its entropy, forming the phase diagram of the system. Our fundamental result is the Asymptotic Equivalence Theorem, which allows us to identify the equivalence classes of states under asymptotic approximately charge-conserving unitaries with the points of the phase diagram. Using the phase diagram of a system and its bath, we analyze the first and the second laws of thermodynamics. In particular, we show that to attain the second law, an asymptotically large bath is necessary. In the case that the bath is composed of several identical copies of the same elementary bath, we quantify exactly how large the bath has to be to permit a specified work transformation of a given system, in terms of the number of copies of the “elementary bath” systems per work system (bath rate). If the bath is relatively small, we show that the analysis requires an extended phase diagram exhibiting negative entropies. This corresponds to the purely quantum effect that at the end of the process, system and bath are entangled, thus permitting classically impossible transformations (unless the bath is enlarged). For a large bath, or many copies of the same elementary bath, system and bath may be left uncorrelated and we show that the optimal bath rate, as a function of how tightly the second law is attained, can be expressed in terms of the heat capacity of the bath. Our approach solves a problem from earlier investigations about how to store the different charges under optimal work extraction protocols in physically separate batteries.
We consider a theory of quantum thermodynamics with multiple conserved quantities (or charges). To this end, we generalize the seminal results of Sparaciari et al. [PRA 96:052112, 2017] to the case of multiple, in general non-commuting charges, for which we formulate a resource theory of thermodynamics of asymptotically many non-interacting systems. To every state we associate the vector of its expected charge values and its entropy, forming the phase diagram of the system. Our fundamental result is the Asymptotic Equivalence Theorem (AET), which allows us to identify the equivalence classes of states under asymptotic approximately charge-conserving unitaries with the points of the phase diagram. Using the phase diagram of a system and its bath, we analyze the first and the second laws of thermodynamics. In particular, we show that to attain the second law, an asymptotically large bath is necessary. In the case that the bath is composed of several identical copies of the same elementary bath, we quantify exactly how large the bath has to be to permit a specified work transformation of a given system, in terms of the number of copies of the elementary bath systems per work system (bath rate). If the bath is relatively small, we show that the analysis requires an extended phase diagram exhibiting negative entropies. This corresponds to the purely quantum effect that at the end of the process, system and bath are entangled, thus permitting classically impossible transformations. For a large bath, system and bath may be left uncorrelated and we show that the optimal bath rate, as a function of how tightly the second law is attained, can be expressed in terms of the heat capacity of the bath. Our approach, solves a problem from earlier investigations about how to store the different charges under optimal work extraction protocols in physically separate batteries.
We study thermodynamic state transformations in the resource theory of work and heat when the initial quantum state is unknown. Moving beyond state-dependent protocols, we develop a universal framework in which a single transformation applies to all admissible input states. For mutually commuting conserved charges, we construct charge-conserving protocols whose transformation error, quantified by trace distance, decays super-polynomially with the number of system copies. As an application, we demonstrate universal work extraction: asymptotically optimal work can be extracted without microscopic knowledge of the initial state, with a super-polynomially small error. Our results show that thermodynamic state transformations remain achievable under limited prior information and establish a universal framework for resource-theoretic thermodynamics beyond the state-aware setting.
This thesis addresses problems in the field of quantum information theory. The first part of the thesis is opened with concrete definitions of general quantum source models and their compression, and each subsequent chapter addresses the compression of a specific source model as a special case of the initially defined general models. First, we find the optimal compression rate of a general mixed state source which includes as special cases all the previously studied models such as Schumacher's pure and ensemble sources and other mixed state ensemble models. For an interpolation between the visible and blind Schumacher's ensemble model, we find the optimal compression rate region for the entanglement and quantum rates. Later, we study the classical-quantum variation of the celebrated Slepian-Wolf problem and the ensemble model of quantum state redistribution for which we find the optimal compression rate considering per-copy fidelity and single-letter achievable and converse bounds matching up to continuity of functions which appear in the corresponding bounds. The second part of the thesis revolves around information theoretical perspective of quantum thermodynamics. We start with a resource theory point of view of a quantum system with multiple non-commuting charges. Subsequently, we apply this resource theory framework to study a traditional thermodynamics setup with multiple non-commuting conserved quantities consisting of a main system, a thermal bath and batteries to store various conserved quantities of the system. We state the laws of the thermodynamics for this system, and show that a purely quantum effect happens in some transformations of the system, that is, some transformations are feasible only if there are quantum correlations between the final state of the system and the thermal bath.
We extend entropy production to a deeply quantum regime involving noncommuting conserved quantities. Consider a unitary transporting conserved quantities (“charges”) between two systems initialized in thermal states. Three common formulas model the entropy produced. They respectively cast entropy as an extensive thermodynamic variable, as an information-theoretic uncertainty measure, and as a quantifier of irreversibility. Often, the charges are assumed to commute with each other (e.g., energy and particle number). Yet quantum charges can fail to commute. Noncommutation invites generalizations, which we posit and justify, of the three formulas. The noncommutation of charges, we find, breaks the equivalence of the formulas. Furthermore, different formulas quantify different physical effects of the noncommutation of charges on entropy production. For instance, entropy production can signal contextuality—true nonclassicality—by becoming nonreal. This work opens up stochastic thermodynamics to noncommuting—and so particularly quantum—charges. Published by the American Physical Society 2024
Extending the quantum formulation of [Phys. Rev. X 3, 041003 (2013)] to a more general setting for studying the thermodynamics of information processing including initial correlations, we generalize the second law of thermodynamics to account for information processing in such autonomous systems. We consider a composite quantum system consisting of a principal system, heat bath, memory, and work source, and adopt an autonomous Hamiltonian framework. We derive constraints on the total Hamiltonian that ensure the work source to act as a catalyst preserving its original randomness, namely that the total unitary evolution must have a unitary partial transpose. We show that this requirement is equivalent to the commutativity of operators acting on the joint system of the principal system, bath, and memory, which underlies the Hamiltonian structure. Next, we generalize the quantum speed limit for the joint dynamics of system and memory to the quantum thermodynamic speed limit, from which we obtain a dynamical version of Landauer's bound. More importantly, we also interpret this quantum thermodynamic speed limit in the context of quantum hypothesis testing.
We introduce the resource-theoretic free energy of a quantum channel as the maximal work extractable from the channel as its output equilibrates to a thermal state and its reference system remains locally intact. It is proportional to the relative entropy between the given channel and the absolutely thermal channel. It attains a clear operational meaning as twice the asymptotic rates of athermality distillation and formation under Gibbs-preserving superchannels, which map one absolutely thermal channel to another for a given bath, thereby revealing the asymptotic reversibility of the resource theory of athermality for quantum channels. Consequently, we establish that the optimal extractable work in converting one channel to another through the asymptotic athermality distillation and formation tasks equals the difference in their free energies. We call this optimal work the thermodynamic work capacity of channel conversion. Quantum information processing and computing fundamentally concern the manipulation and transformation of quantum channels, which encompass quantum states, their transformations, and measurements. A quantitative characterization of the optimal thermodynamic work gain or expenditure in quantum information processing constitutes a key step toward formulating thermodynamics of quantum processes.