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arXiv:2010.14674 · Physical review. B./Physical review. B

Optically controlled polariton condensate molecules

E. D. Cherotchenko, Helgi Sigurðsson, Alexis Askitopoulos, Anton V. Nalitov

Published Mar 29, 2021• 17 citations
arXivHTMLPDF

Abstract

A condensed-matter platform for analog simulation of complex two-dimensional molecular bonding configurations, based on optically trapped exciton-polariton condensates is proposed. The stable occupation of polariton condensates in the excited states of their optically configurable potential traps permits emulation of excited atomic orbitals. A classical mean-field model describing the dissipative coupling mechanism between $p$-orbital condensates is derived, identifying lowest-threshold condensation solutions as a function of trap parameters corresponding to bound and antibound $\ensuremath{\pi}$ and $\ensuremath{\sigma}$ bonding configurations, similar to those in quantum chemistry.

DOI
10.1103/physrevb.103.115309

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A condensed-matter platform for analog simulation of complex two-dimensional molecular bonding configurations, based on optically trapped exciton-polariton condensates is proposed. The stable occupation of polariton condensates in the excited states of their optically configurable potential traps permits emulation of excited atomic orbitals. A classical mean-field model describing the dissipative coupling mechanism between ppp-orbital condensates is derived, identifying lowest-threshold condensation solutions as a function of trap parameters corresponding to bound and antibound \ensuremathπ\ensuremath{\pi}\ensuremathπ and \ensuremathσ\ensuremath{\sigma}\ensuremathσ bonding configurations, similar to those in quantum chemistry.
Superfluids under specific conditions can exhibit spontaneous breaking of continuous translation symmetries and form exotic spatially ordered states of matter known as supersolids. Despite its early theoretical prediction, it took over half-a-centrury to experimentally demonstrate the supersolid phase in ultracold atomic Bose-Einstein condensates, forming due to long-range interatomic interactions. Here we propose as a promising new platform for supersolidity exciton-polariton superfluids, confined in annular optically induced traps. The supersolid phase emerges due to effective attractive interactions, mediated by the normal excitonic component of the system. Experimental demonstration of spontaneously formed spatially ordered phase is in agreement with detailed mean-field theoretical analysis and numerical simulation. The spontaneous character of the observed supersolid transition is further evidenced by the formation of specific zero-energy Nambu-Goldstone modes in the collective excitation spectrum.
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This thesis includes theoretical studies regarding stability and manipulation of Bose-Einstein condensates (BECs) of ultra-cold atoms in 2D trapping geometry, as well as formation of steady states of exciton-polariton Bose-Einstein condensates created in solid states. We analyze and numerically model the dynamics and localization of the condensates using mean-field model. Chapter 1 contains an introduction to the physics of ultra-cold atom BEC and excitonpolariton BEC which provides a framework for the work presented in later chapters. In Chapter 2, we consider a method for achieving dynamically controllable transport of highly mobile matter-wave solitons in an ultra-cold atom BEC with attractive interparticle interaction loaded into a driven two-dimensional optical lattice. Our numerical analysis based on the mean-field model and the theory based on the effective particle approach demonstrate that fast, time-periodic rocking of the two-dimensional optical lattice enables efficient stabilization and manipulation of spatially localized matter wave packets via induced reconfigurable mobility channels. Chapter 3 consists of an investigation of the instability - collapse of a BEC with attractive interactions. In this chapter we explore the influence of an orbital angular momentum on the collapse of vortex-free elliptic clouds of Bose-Einstein condensates trapped in a radially symmetric harmonic potential or a rotating elliptic potential. The results of our analysis show that the number of trapped ultracold atoms corresponding to the collapse threshold can be radically increased for such rotating nonlinear matter waves in a radially harmonic trap. The results corresponding to a BEC cloud confined in a rotating elliptic trap show that the elongated stationary states can be parallel or perpendicular to the long axis of the trap and display bistable nature. In Chapter 4, we examine spatial localization and dynamical stability of Bose-Einstein condensates of exciton-polaritons in microcavities under the condition of off-resonant spatially inhomogeneous optical pumping both with and without a harmonic trapping potential. We employ the open-dissipative Gross-Pitaevskii model for describing an incoherently pumped polariton condensate coupled to an exciton reservoir. We reveal that spatial localization of the steady-state condensate occurs due to effective self-trapping created by the polariton flows, regardless of the presence of the external potential. A ground state of the polariton condensate with repulsive interactions between the quasiparticles represents a dynamically stable bright dissipative soliton. We also investigate the conditions for sustaining spatially localized structures, with nonzero angular momentum, in the form of single-charge vortices. Chapter 5 consider the existence of novel spatially localized states of exciton-polariton Bose-Einstein condensates in semiconductor microcavities with fabricated periodic inplane potentials. Our theory shows that, under the conditions of continuous nonresonant pumping, localization is observed for a wide range of optical pump parameters due to effective potentials self-induced by the polariton flows in the spatially periodic system. We show that the self-localization of exciton-polaritons in the lattice may occur both in the gaps and bands of the single-particle linear spectrum, and is dominated by the effects of gain and dissipation rather than the structured potential, in sharp contrast to the conservative condensates of ultra-cold alkali atoms.
Exciton-polariton Bose-Einstein condensates (BECs) are newly emerged quantum systems that are capable of showing macroscopic quantum phenomena with intrinsic open-dissipative nature. The spatial distribution of the polariton density, without any external potential, can be controlled by the geometric shape of the pumping laser, enabling the investigation of polariton dynamics with topologically non-trivial configurations. Meanwhile, exciton-polaritons have spin degrees of freedom inherited from excitons and photons, making it a candidate for the realization of quantum logic gates. In this thesis, we will investigate theoretically the nonlinear dynamics of exciton-polariton BECs involving both polaritons' spatial degrees of freedom and spin degrees of freedom, and interactions between them. This thesis is organised as follows: In Chapter 1, we will present an overall review of exiton-polariton systems and important properties of polariton BECs and then introduce the dynamical equations with various interactions that will serve as the main theoretical tool for subsequent chapters. Several polariton pumping and trapping techniques appearing in later chapters will also be introduced. In Chapter 2, we will investigate the superfluidity properties of a single-component polariton condensate under an incoherent annular pumping configuration. By studying the stability properties of polariton persistent currents, we find that the persistent currents can exhibit dynamical instability and energetic-like instability according to different parameter region. A stability phase diagram will be given and its relation with the Landau's criterion will be discussed. In Chapter 3, we will investigate the spin dynamics of a two-component polariton condensate under a homogeneous pumping configuration. Owing to the Josephson coupling, there exist multiple steady state solutions that allow of controlled spin state switching. A desynchronized region where there exists no stable steady solution is found. In the desynchronized region, a desynchronized state beating periodically over time can exist, which will serve as a building block of spin waves presented in the next chapter. In Chapter 4, by combining results from the previous two chapters we will investigate generally the nonlinear dynamics of polariton condensates under an annular pumping configuration. The spin-orbit interaction provided by the Josephson coupling supports azimuthon states that have simultaneous modulations in both amplitude and phase. The azimuthon states, when viewed in a different polarization basis, form rotating spin waves that can be referred to as the optical ferris wheel. In Chapter 5, results from previous chapters will be extended to micocavities that support the anisotropic TE-TM splitting interaction. Rotating singularities (small-scale vortices) are found as a result. Their properties and experimental observation techniques will be discussed. Chapter 2-5 provide a theoretical framework for the nonlinear dynamics of polariton condensates. They rely mostly on optical trapping techniques and are ready to be tested in experiments. In Chapter 6, polaritons trapped by an engineered periodic mesa potential will be discussed. We will investigate the band structure of polaritons under the influence of the periodic potential together with discussions on the phase-modulated interference pattern which corresponds to the polariton Talbot patterns observed in experiments.