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arXiv:2009.08237 · Europhysics Letters (EPL)

Square-well potential in quaternionic quantum mechanics

Sergio Giardino

Published Oct 1, 2020• 13 citations
arXivHTMLPDF

Abstract

Abstract The one-dimensional infinite square well is the simplest solution of quantum mechanics, and consequently one of the most important. In this paper, we provide this solution using the real Hilbert space approach to quaternionic quantum mechanics ( ). We further provide the one-dimensional finite as well and a method to generate quaternionic solutions from non-degenerate complex solutions.

DOI
10.1209/0295-5075/132/20007

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Abstract We address an interesting problem in elementary quantum mechanics, namely how can one obtain the momentum state eigenfunctions for the infinite square well potential as a direct solution of the time-independent Schrödinger equation in momentum space. The conventional method for obtaining the momentum state eigenfunctions for the infinite square well potential is to take the Fourier transform of the coordinate space eigenfunctions. Unfortunately, the Schrödinger equation in momentum space for the infinite well potential is not well-defined. As such we must use a potential whose Fourier transform is well-defined and then take a limit in which the potential approaches that of the infinite well potential. We present three approaches to the problem: one based on dimensional analysis, one in which the infinite well potential is viewed as the limit of a finite well whose depth approaches infinity, and one in which the infinite well potential is viewed as the limit of a power law potential in the limit that the power approaches infinity.
Complex numbers were created by introducing the imaginary unit i to represent the square root of -1, allowing solutions to equations that involved square roots of negative numbers. Complex numbers were further extended to quaternionic numbers by introducing additional imaginary units, namely " j " and " k ". Quaternions are non-commutative and involve four components, with each component being a real number or a multiple of an imaginary unit. Usually complex numbers are used to represent wave functions in quantum mechanics. Solutions using quaternions to square well, spin and angular momentum, Dirac equations have been obtained by many researchers. In this article, we have made use of quaternions to study the generalization of adding angular momenta, the digital signal processing of a quaternionic function and circular potential of a particle in real Hilbert space and have obtained quaternionic solutions in terms of Bessel functions.
The Dirac delta function potential is considered within the real Hilbert space approach for complex wave functions, as well as quaternionic wave functions. As has been previously determined, the real Hilbert space approach enables the possibility of self-interacting physical systems. The self-interaction precludes confining states, and also imposes non-stationary quantum states, both of them representing novel situations that cannot be observed in terms of quantum wave functions. These results remark the differences between quaternionic quantum mechanics ($\mathbbm H$QM) and complex quantum mechanics ($\mathbbm C$QM), and also establish a method of solving the wave equation that may be applied to a variety of different cases.