The second law of thermodynamics is discussed and reformulated from a quantum information theoretic perspective for open quantum systems using relative entropy. Specifically, the relative entropy of a quantum state with respect to equilibrium states is considered and its monotonicity property with respect to an open quantum system evolution is used to obtain second lawlike inequalities. We discuss this first for generic quantum systems in contact with a thermal bath and subsequently turn to a formulation suitable for the description of local dynamics in a relativistic quantum field theory. A local version of the second law similar to the one used in relativistic fluid dynamics can be formulated with relative entropy or even relative entanglement entropy in a space-time region bounded by two light cones. We also give an outlook toward isolated quantum field theories and discuss the role of entanglement for relativistic fluid dynamics.
The second law of thermodynamics is discussed and reformulated from a quantum information theoretic perspective for open quantum systems using relative entropy. Specifically, the relative entropy of a quantum state with respect to equilibrium states is considered and its monotonicity property with respect to an open quantum system evolution is used to obtain second lawlike inequalities. We discuss this first for generic quantum systems in contact with a thermal bath and subsequently turn to a formulation suitable for the description of local dynamics in a relativistic quantum field theory. A local version of the second law similar to the one used in relativistic fluid dynamics can be formulated with relative entropy or even relative entanglement entropy in a space-time region bounded by two light cones. We also give an outlook toward isolated quantum field theories and discuss the role of entanglement for relativistic fluid dynamics.
We review the fundamental properties of the quantum relative entropy for finite-dimensional Hilbert spaces. In particular, we focus on several inequalities that are related to the second law of thermodynamics, where the positivity and the monotonicity of the quantum relative entropy play key roles; these properties are directly applicable to derivations of the second law (e.g., the Clausius inequality). Moreover, the positivity is closely related to the quantum fluctuation theorem, while the monotonicity leads to a quantum version of the Hatano-Sasa inequality for nonequilibrium steady states. Based on the monotonicity, we also discuss the data processing inequality for the quantum mutual information, which has a similar mathematical structure to that of the second law. Moreover, we derive a generalized second law with quantum feedback control. In addition, we review a proof of the monotonicity in line with Petz.
In this thesis, we present and discuss the quantum statistical foundations of relativistic hydrodynamics with special emphasis on the entropy current. We show that it is possible to provide a rigorous definition for this quantity in the framework of relativistic quantum statistical mechanics and we put forward a general method to calculate it at local thermodynamic equilibrium. The method is based on the proof of existence of the thermodynamic potential current, a usually tacitly understood hypothesis. We then apply the method for the entropy current to the study of two different systems. The first system is a relativistic quantum fluid at global thermodynamic equilibrium, phenomenologically related to the quark-gluon plasma and, from a quantum field theoretical standpoint, to the Unruh effect. The second systems is a relativistic quantum fluid with boost invariance, also related to the quark-gluon plasma and of great interest as the first solvable system out of equilibrium. The thermal expectation value of the energy-momentum tensor as well as the entropy current are calculated for both systems, and renormalization is discussed.
The second law of thermodynamics states that for a thermally isolated system entropy never decreases. Most physical processes we observe in nature involve variations of macroscopic quantities over spatial and temporal scales much larger than microscopic molecular collision scales and thus can be considered as in local equilibrium. For a many-body system in local equilibrium a stronger version of the second law applies which says that the entropy production at each spacetime point should be non-negative. In this paper we provide a proof of the second law for such systems and a first derivation of the local second law. For this purpose we develop a general non-equilibrium effective field theory of slow degrees of freedom from integrating out fast degrees of freedom in a quantum many-body system and consider its classical limit. The key elements of the proof are the presence of a Z2 symmetry, which can be considered as a proxy for local equilibrium and micro-time-reversibility, and a classical remnant of quantum unitarity. The Z2 symmetry leads to a local current from a procedure analogous to that used in the Noether theorem. Unitarity leads to a definite sign of the divergence of the current. We also discuss the origin of an arrow of time, as well as the coincidence of causal and thermodynamical arrows of time. Applied to hydrodynamics, the proof gives a first-principle derivation of the phenomenological entropy current condition and provides a constructive procedure for obtaining the entropy current.
We show that in any relativistic system, entanglement entropy obeys a speed limit set by the entanglement in thermal equilibrium. The bound is derived from inequalities on relative entropy with respect to a thermal reference state. Thus the thermal state constrains far-from-equilibrium entanglement dynamics whether or not the system actually equilibrates, in a manner reminiscent of fluctuation theorems in classical statistical mechanics. A similar shape-dependent bound constrains the full nonlinear time evolution, supporting a simple physical picture for entanglement propagation that has previously been motivated by holographic calculations in conformal field theory. We discuss general quantum field theories in any spacetime dimension, but also derive some results of independent interest for thermal relative entropy in 1+1d CFT.
The second law of thermodynamics states that the entropy of an isolated system can only increase over time. This appears to conflict with the reversible evolution of isolated quantum systems under the Schrödinger equation, which preserves the von Neumann entropy. Nonetheless, one finds that with respect to many observables, expectation values approach a fixed value—their equilibrium value. This ultimately raises the question: ? For classical systems, one introduces the assumption of a low-entropy initial state along with the concept of ignorance about the microscopic details of the physical system, leading to a statistical interpretation of the second law. By considering the observables through which we examine quantum systems, both these assumptions can be incorporated, building upon recent studies of the of observables. While the statistical behavior of observable expectation values is well established, a quantitative connection to entropy increase has been lacking so far. In deriving novel bounds for the equilibration of observables, and considering the entropy of the system relative to observables, we recover a variant of the second law: the entropy with respect to a given observable tends toward its equilibrium value in the course of the system’s unitary evolution. These results also support recent findings that question the necessity of nonintegrability for equilibration in quantum systems. We further illustrate our bounds using numerical results from the paradigmatic example of a quantum Ising model on a chain of spins. There, we observe entropy increasing up to equilibrium values, as well as fluctuations, which expose the underlying reversible evolution in accordance with the derived bounds.
We argue that the entanglement entropy for a very small subsystem obeys a property which is analogous to the first law of thermodynamics when we excite the system. In relativistic setups, its effective temperature is proportional to the inverse of the subsystem size. This provides a universal relationship between the energy and the amount of quantum information. We derive the results using holography and confirm them in two-dimensional field theories. We will also comment on an example with negative specific heat and suggest a connection between the second law of thermodynamics and the strong subadditivity of entanglement entropy.