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arXiv:2007.10347 · Physical Review Research

Probing eigenstate thermalization in quantum simulators via fluctuation-dissipation relations

Alexander Schuckert, Michael Knap

Published Dec 4, 2020• 22 citations
arXivHTMLPDF

Abstract

The eigenstate thermalization hypothesis (ETH) offers a universal mechanism for the approach to equilibrium of closed quantum many-body systems.So far, however, experimental studies have focused on the relaxation dynamics of observables as described by the diagonal part of ETH, whose verification requires substantial numerical input.This leaves many of the general assumptions of ETH untested.Here, we propose a theory-independent route to probe the full ETH in quantum simulators by observing the emergence of fluctuation-dissipation relations, which directly probe the off-diagonal part of ETH.We discuss and propose protocols to independently measure fluctuations and dissipations as well as higher order time-ordered correlation functions.We first show how the emergence of fluctuation-dissipation relations from a nonequilibrium initial state can be observed for the two-dimensional (2D) Bose-Hubbard model in superconducting qubits or quantum gas microscopes.Then we focus on the long-range transverse field Ising model (LTFI), which can be realized with trapped ions.The LTFI exhibits rich thermalization phenomena: For strong transverse fields, we observe prethermalization to an effective magnetization-conserving Hamiltonian in the fluctuation-dissipation relations.For weak transverse fields, confined excitations lead to nonthermal features, resulting in a violation of the fluctuation-dissipation relations up to long times.Moreover, in an integrable region of the LTFI, thermalization to a generalized Gibbs ensemble occurs and the fluctuation-dissipation relations enable an experimental diagonalization of the Hamiltonian.Our work presents a theory-independent way to characterize thermalization in quantum simulators and paves the way to quantum simulate condensed matter pump-probe experiments.

DOI
10.1103/physrevresearch.2.043315

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The eigenstate thermalization hypothesis (ETH) offers a universal mechanism for the approach to equilibrium of closed quantum many-body systems.So far, however, experimental studies have focused on the relaxation dynamics of observables as described by the diagonal part of ETH, whose verification requires substantial numerical input.This leaves many of the general assumptions of ETH untested.Here, we propose a theory-independent route to probe the full ETH in quantum simulators by observing the emergence of fluctuation-dissipation relations, which directly probe the off-diagonal part of ETH.We discuss and propose protocols to independently measure fluctuations and dissipations as well as higher order time-ordered correlation functions.We first show how the emergence of fluctuation-dissipation relations from a nonequilibrium initial state can be observed for the two-dimensional (2D) Bose-Hubbard model in superconducting qubits or quantum gas microscopes.Then we focus on the long-range transverse field Ising model (LTFI), which can be realized with trapped ions.The LTFI exhibits rich thermalization phenomena: For strong transverse fields, we observe prethermalization to an effective magnetization-conserving Hamiltonian in the fluctuation-dissipation relations.For weak transverse fields, confined excitations lead to nonthermal features, resulting in a violation of the fluctuation-dissipation relations up to long times.Moreover, in an integrable region of the LTFI, thermalization to a generalized Gibbs ensemble occurs and the fluctuation-dissipation relations enable an experimental diagonalization of the Hamiltonian.Our work presents a theory-independent way to characterize thermalization in quantum simulators and paves the way to quantum simulate condensed matter pump-probe experiments.
This review gives a pedagogical introduction to the eigenstate thermalization hypothesis (ETH), its basis, and its implications to statistical mechanics and thermodynamics. In the first part, ETH is introduced as a natural extension of ideas from quantum chaos and random matrix theory (RMT). To this end, we present a brief overview of classical and quantum chaos, as well as RMT and some of its most important predictions. The latter include the statistics of energy levels, eigenstate components, and matrix elements of observables. Building on these, we introduce the ETH and show that it allows one to describe thermalization in isolated chaotic systems without invoking the notion of an external bath. We examine numerical evidence of eigenstate thermalization from studies of many-body lattice systems. We also introduce the concept of a quench as a means of taking isolated systems out of equilibrium, and discuss results of numerical experiments on quantum quenches. The second part of the review explores the implications of quantum chaos and ETH to thermodynamics. Basic thermodynamic relations are derived, including the second law of thermodynamics, the fundamental thermodynamic relation, fluctuation theorems, the fluctuation–dissipation relation, and the Einstein and Onsager relations. In particular, it is shown that quantum chaos allows one to prove these relations for individual Hamiltonian eigenstates and thus extend them to arbitrary stationary statistical ensembles. In some cases, it is possible to extend their regimes of applicability beyond the standard thermal equilibrium domain. We then show how one can use these relations to obtain nontrivial universal energy distributions in continuously driven systems. At the end of the review, we briefly discuss the relaxation dynamics and description after relaxation of integrable quantum systems, for which ETH is violated. We present results from numerical experiments and analytical studies of quantum quenches at integrability. We introduce the concept of the generalized Gibbs ensemble and discuss its connection with ideas of prethermalization in weakly interacting systems.
Identifying the general mechanics behind the equilibration of a complex isolated quantum system towards a state described by only a few parameters has been the focus of attention in non-equilibrium thermodynamics. And several experimentally unproven conjectures are proposed for the statistical description of quantum (non-)integrable models. The plausible eigenstate thermalization hypothesis (ETH), which suggests that each energy eigenstate itself is thermal, plays a crucial role in understanding the quantum thermalization in non-integrable systems; it is commonly believed that it does not exist in integrable systems. Nevertheless, integrable systems can still relax to the generalized Gibbs ensemble. From a microscopic perspective, understanding the origin of this generalized thermalization that occurs in an isolated integrable system is a fundamental open question lacking experimental investigations. Herein, we experimentally investigated the spin subsystem relaxation in an isolated spin-orbit coupling quantum system. By applying the quantum state engineering technique, we initialized the system with various distribution widths in the mutual eigenbasis of the conserved quantities. Then, we compared the steady state of the spin subsystem reached in a long-time coherent dynamics to the prediction of a generalized version of ETH and the underlying mechanism of the generalized thermalization is experimentally verified for the first time. Our results facilitate understanding the origin of quantum statistical mechanics.
The Eigenstate Thermalization Hypothesis (ETH) is a standard tool to understand the thermalization properties of an isolated quantum system. Its generalization to higher order correlations of matrix elements of local operators, dubbed the full ETH, relates the ETH free cumulants to the corresponding thermal free cumulants in the thermodynamic limit. In this work, we numerically test the full ETH predictions using exact diagonalization of two integrable spin models: the Ising and the XXZ Heisenberg models. The differences from the behavior predicted by full ETH in chaotic systems are highlighted and contrasted along the way. We further study the out-of-time-ordered correlator (OTOC) through its approximate decomposition into contributions involving the second- and fourth-order ETH free cumulants. We find that, although the fourth-order contribution governs the late-time behavior of the OTOC in these integrable models, its dynamics differs significantly from that found in nonintegrable systems.
The eigenstate thermalization hypothesis (ETH) and the theory of linear response (LRT) are celebrated cornerstones of our understanding of the physics of many-body quantum systems out of equilibrium. While the ETH provides a generic mechanism of thermalization for states arbitrarily far from equilibrium, LRT extends the successful concepts of statistical mechanics to situations close to equilibrium. In our work, we connect these cornerstones to shed light on the route to equilibrium for a class of properly prepared states. We unveil that, if the off-diagonal part of the ETH applies, then the relaxation process can become independent of whether or not a state is close to equilibrium. Moreover, in this case, the dynamics is generated by a single correlation function, i.e., the relaxation function in the context of LRT. Our analytical arguments are illustrated by numerical results for idealized models of random-matrix type and more realistic models of interacting spins on a lattice. Remarkably, our arguments also apply to integrable quantum systems where the diagonal part of the ETH may break down.
Deriving conditions under which a macroscopic system thermalizes directly from the underlying quantum many-body dynamics of its microscopic constituents is a long-standing challenge in theoretical physics. The well-known eigenstate thermalization hypothesis (ETH) is presumed to be a key mechanism, but has defied rigorous verification for generic systems thus far. A weaker variant (weak ETH), by contrast, is provably true for a large variety of systems, including even many integrable models, but its implications with respect to the problem of thermalization are still largely unexplored. Here we analytically demonstrate that systems satisfying the weak ETH exhibit thermalization for two very natural classes of far-from-equilibrium initial conditions: the overwhelming majority of all pure states with a preset nonequilibrium expectation value of some given local observable, and the Gibbs states of a Hamiltonian which subsequently is subject to a quantum quench in the form of a sudden change of some local system properties.
The eigenstate thermalization hypothesis (ETH) is the leading interpretation in our current understanding of quantum thermalization. Recent results uncovered strong connections between quantum correlations in thermalizing systems and the structure of free probability theory, leading to the notion of full ETH. However, most studies have been performed for ergodic systems and it is still unclear whether or how full ETH manifests in ergodicity-breaking models. We fill this gap by studying standard probes of full ETH in ergodicity-breaking quantum circuits, presenting numerical and analytical results for interacting integrable systems. These probes can display distinct behavior and undergo a different scaling than the ones observed in ergodic systems. For the analytical results we consider an interacting integrable dual-unitary model and present the exact eigenstates, allowing us to analytically express common probes for full ETH. We discuss the underlying mechanisms responsible for these differences and show how the presence of solitons dictates the behavior of ETH-related quantities in the dual-unitary model. We show numerical evidence that this behavior is sufficiently generic away from dual-unitarity when restricted to the appropriate symmetry sectors.