We study a limit cycle of a quantum Otto engine whose every cycle consists of two finite-time quantum isochoric (heating or cooling) processes and two quantum adiabatic work-extracting processes.Considering a two-level system as a working substance that weakly interacts with two reservoirs comprising an infinite number of bosons, we investigate the non-Markovian effect [short-time behavior of the reduced dynamics in the quantum isochoric processes (QIPs)] on work extraction after infinite repetition of the cycles.We focus on the parameter region where energy transferred to the reservoir can come back to the system in a short-time regime, which we call energy backflow to show partial quantum-mechanical reversibility.As a situation completely different from macroscopic thermodynamics, we find that the interaction energy is finite and negative by evaluating the average energy change of the reservoir during the QIPs by means of the full-counting statistics, corresponding to the twopoint measurements.This feature leads us to the following findings: (1) The Carnot theorem is consistent with a definition of work including the interaction energy, although the commonly used definition of work excluding the interaction leads to a serious conflict with the thermodynamic law, and (2) the energy backflow can increase the work extraction.Our findings show that we need to pay attention to the interaction energy in designing a quantum Otto engine operated in a finite time, which requires us to include the non-Markovian effect, even when the system-reservoir interaction is weak.
We study a limit cycle of a quantum Otto engine whose every cycle consists of two finite-time quantum isochoric (heating or cooling) processes and two quantum adiabatic work-extracting processes.Considering a two-level system as a working substance that weakly interacts with two reservoirs comprising an infinite number of bosons, we investigate the non-Markovian effect [short-time behavior of the reduced dynamics in the quantum isochoric processes (QIPs)] on work extraction after infinite repetition of the cycles.We focus on the parameter region where energy transferred to the reservoir can come back to the system in a short-time regime, which we call energy backflow to show partial quantum-mechanical reversibility.As a situation completely different from macroscopic thermodynamics, we find that the interaction energy is finite and negative by evaluating the average energy change of the reservoir during the QIPs by means of the full-counting statistics, corresponding to the twopoint measurements.This feature leads us to the following findings: (1) The Carnot theorem is consistent with a definition of work including the interaction energy, although the commonly used definition of work excluding the interaction leads to a serious conflict with the thermodynamic law, and (2) the energy backflow can increase the work extraction.Our findings show that we need to pay attention to the interaction energy in designing a quantum Otto engine operated in a finite time, which requires us to include the non-Markovian effect, even when the system-reservoir interaction is weak.
Enhancement of thermal efficiency of quantum heat engines has been discussed mainly in terms of quantumness of working substances. In the present study, we propose as another possibility to utilize a quantum-mechanical (reversible) feature of system-reservoir interaction, which reveals itself in the short-time regime as a non-Markovian effect on the reduced dynamics of the substance, before asymptotically approaching irreversible processes. For this purpose, we study a limit cycle of the quantum Otto engine comprising a working two-level system and two reservoirs, including the non-Markovian effect for the finite-time isochoric processes while the work-extracting processes are kept quantum adiabatic. Assuming that the system interacts weakly with the reservoirs consisting of infinite bosons, we find a parameter regime beyond the Carnot efficiency in which a positive work is extracted by including a non-Markovian effect called energy backflow. We also find that the interaction energy is finite and contributes to the positive work even for the weak interaction. The work diminishes if we include into the work the energy for detaching the working substance from reservoirs.
Quantum thermodynamics explores novel thermodynamic phenomena that emerge when interactions between macroscopic systems and microscopic quantum ones go into action. Among various issues, quantum heat engines, in particular, have attracted much attention as a critical step in theoretical formulation of quantum thermodynamics and investigation of efficient use of heat by means of quantum resources. In the present paper, we focus on heat absorption and emission processes as well as work extraction processes of a quantum Otto cycle. We describe the former as non-Markovian dynamics, and thereby find that the interaction energy between a macroscopic heat bath and a microscopic qubit is not negligible. Specifically, we reveal that the interaction energy is divided into the system and the bath in a region of the short interaction time and remains negative in the region of the long interaction time. In addition, a counterintuitive energy flow from the system and the interaction energy to the hot bath occurs in another region of the short interaction time. We quantify these effects by defining an index of non-Markovianity in terms of the interaction energy. With this behavior of the interaction energy, we show that a non-Markovian quantum Otto cycle can switch functions such as an engine as well as a heater or a heat pump by controlling the interaction time with the heat bath. In particular, the qubit itself loses its energy if we shorten the interaction time, and in this sense, the qubit is cooled through the cycle. This property has a possibility of being utilized for cooling the qubits in quantum computing. We also describe the work extraction from the microscopic system to a macroscopic system like us humans as an indirect measurement process by introducing a work storage as a new reservoir.
We study finite-time quantum Otto cycles whose working medium is a harmonic oscillator undergoing a quantum Brownian motion described by the Caldeira-Leggett model when the oscillator is in contact with heat baths in isochoric processes. The time evolution of the Otto cycle is studied by analytically solving the exact Heisenberg-Langevin equations for the system variables and the interaction energy between the system and the bath. This enables us to investigate non-Markovian strong-coupling effects on the quantum Otto cycle. We obtain cyclic steady states and study the thermodynamic properties of the Otto cycle for various values of the parameters describing the heat baths and the coupling between the system and the bath. We compare our results with those obtained in the Markovian limit, where the time evolution is described by the Lindblad equation. We find that the change in the interaction energy during the isochoric process contributes to both work and heat and plays a crucial role in determining the thermodynamic behavior of the cycle. This is in contrast to the behavior of the state observables of the working medium, which show relatively small change compared to the Markovian counterparts. We find that non-Markovian effects only become significant when we consider thermodynamic fluxes such as work and heat with the system-bath interaction fully taken into account. We also compare our results with the power-efficiency trade-off relation recently proposed for the Markovian quantum Otto engine.
We establish a quantum Otto engine cycle in which the working substance contacts with squeezed reservoirs during the two quantum isochoric processes. We consider two working substances: (1) a qubit and (2) two coupled qubits. Due to the effects of squeezing, the working substance can be heated to a higher effective temperature, which leads to many interesting features different from the ordinary ones, such as (1) for the qubit as working substance, if we choose the squeezed parameters properly, the positive work can be exported even when T(H) <T(L), where T(H) and T(L) are the temperatures of the hot and cool reservoirs, respectively; (2) the efficiency can be higher than classical Carnot efficiency. These results do not violate the second law of thermodynamics and it can be understood as quantum fuel is more efficient than the classical one.
We consider a finite-time quantum Otto heat engine that consists of two isochoric (thermal-contact) process, where the system is alternatively coupled to a hot squeezed and a cold thermal reservoir, and two unitary driven strokes, where the system is isolated from these two baths and its von Neumann entropy keeps constant. Both quantum inner friction and coherence are generated along the driven stroke and coherence cannot be fully erased after the finite-time hot isochore. Using full counting statistics, we present the probability distribution functions of heat injection and total work per cycle, which are dependent on the time duration along each process. With these, we derive the analytical expressions for the thermodynamic quantities of the two-level heat engine, such as total work, thermodynamic efficiency, entropy production, and work fluctuations, in which effects of coherence, squeezing, inner friction and finite-time heat exchange are included. We then numerically determine the thermodynamic quantities and the fluctuations using the parameters employed in the experimental implementation. Our results clarify the role of coherence and squeezing in the performance and fluctuations in the quantum Otto engines.
Abstract This paper proposes a theoretical model for a heat engine operating on the Otto cycle, employing a two-qubit Heisenberg chain as its working substance. This system is subjected to an external, time-dependent homogeneous magnetic field and a symmetric cross-spin interaction. The interaction is configured to occur along two distinct orientations, contingent upon the direction of Zeeman energy and symmetric interaction: either exclusively along the X -direction or exclusively along the Z -direction. Furthermore, the thermal reservoirs integral to the Otto engine are considered to engage with the working substance via two discrete modes: a localized interaction or a collective interaction. The two qubits exhibit weak coupling to a non-equilibrium thermal environment during the isochoric heating and cooling strokes, thereby validating the application of a Markovian model as a suitable approximation for describing the time evolution of the working substance. This study investigates the influence of various system parameters on the thermodynamic quantities and the resultant power output. A principal finding is that refrigeration functionality is the predominant operational characteristic when the system engages in collective interaction with the reservoirs. Conversely, localized interactions facilitate dual operational modes, with the sign of the Zeeman energy determining the function as either a refrigerator or a heat engine. Significantly, positive power output is achieved in the engine regime, and we find that the choice of interaction axis acts as a powerful amplification mechanism for the thermodynamic output, while the system-environment coupling scheme proves to be the most decisive factor in determining the machine’s fundamental purpose.