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arXiv:2005.13659 · Physical Review A

Rydberg spectrum of a single trapped Ca+ ion: A Floquet analysis

Mariusz Pawlak, H. R. Sadeghpour

Published May 18, 2020• 11 citations
arXivHTMLPDF

Abstract

We compute the Rydberg spectrum of a single ${\mathrm{Ca}}^{+}$ ion in a Paul trap by incorporating various internal and external coupling terms of the ion to the trap in the Hamiltonian. The coupling terms include spin-orbit coupling in ${\mathrm{Ca}}^{+}$, charge (electron and ionic core) coupling to the radio frequency and static fields, ion-electron coupling in the Paul trap, and ion center-of-mass coupling. The electronic Rydberg states are precisely described by a one-electron model potential for ${e}^{\ensuremath{-}}+{\mathrm{Ca}}^{2+}$, and accurate eigenenergies, quantum defect parameters, and static and tensor polarizabilities for a number of excited Rydberg states are obtained. The time-periodic rf Hamiltonian is expanded in the Floquet basis, and the trapping-field-broadened Rydberg lines are compared with recent observations of ${\mathrm{Ca}}^{+}(23P)$ and ${\mathrm{Ca}}^{+}(52F)$ Rydberg lines.

DOI
10.1103/physreva.101.052510

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We compute the Rydberg spectrum of a single Ca+{\mathrm{Ca}}^{+}Ca+ ion in a Paul trap by incorporating various internal and external coupling terms of the ion to the trap in the Hamiltonian. The coupling terms include spin-orbit coupling in Ca+{\mathrm{Ca}}^{+}Ca+, charge (electron and ionic core) coupling to the radio frequency and static fields, ion-electron coupling in the Paul trap, and ion center-of-mass coupling. The electronic Rydberg states are precisely described by a one-electron model potential for e\ensuremath−+Ca2+{e}^{\ensuremath{-}}+{\mathrm{Ca}}^{2+}e\ensuremath−+Ca2+, and accurate eigenenergies, quantum defect parameters, and static and tensor polarizabilities for a number of excited Rydberg states are obtained. The time-periodic rf Hamiltonian is expanded in the Floquet basis, and the trapping-field-broadened Rydberg lines are compared with recent observations of Ca+(23P){\mathrm{Ca}}^{+}(23P)Ca+(23P) and Ca+(52F){\mathrm{Ca}}^{+}(52F)Ca+(52F) Rydberg lines.
We present a method for measuring the polarizability of Rydberg ions confined in the harmonic potential of a Paul trap. For a highly excited electronic state, the coupling between the electronic wave function and the trapping field modifies the excitation probability depending on the motional state of the ion. This interaction strongly depends on the polarizability of the excited state and manifests itself in the state-dependent secular frequencies of the ion. We initialize a single trapped 40^{40}40Ca+^++ ion from the motional ground state into coherent states with ∣α∣|α|∣α∣ up to 12 using electric voltages on the trap segments. The internal state, firstly initialised in the long-lived 3D5/2_{5/2}5/2​ state, is excited to a Rydberg S1/2_{1/2}1/2​-state via the 5P3/2_{3/2}3/2​ state in a two-photon process. We probe the depletion of the 3D5/2_{5/2}5/2​ state owing to the Rydberg excitation followed by a decay into the internal ground 4S1/2_{1/2}1/2​ state. By analysing the obtained spectra we extract the polarizability of Rydberg states which agree with numerical calculations. The method is easy-to-implement and applicable to different Rydberg states regardless of their principal or angular quantum numbers. An accurate value of the state polarizability is needed for quantum gate operations with Rydberg ion crystals.
Abstract We present a method for measuring the polarizability of Rydberg ions confined in the harmonic potential of a Paul trap. For a highly excited electronic state, the coupling between the electronic wave function and the trapping field modifies the excitation spectra depending on the motional state of the ion. This interaction strongly depends on the polarizability of the excited state and manifests itself in the state-dependent secular frequencies of the ion. We initialize a single trapped 40 Ca + ion from the motional ground state into coherent states with | α | up to 12 using electric voltages on the trap segments. The internal state, firstly initialised in the long-lived 3D 5 / 2 state, is excited to a Rydberg S 1 / 2 -state via the 5P 3 / 2 state in a two-photon process. We probe the depletion of the 3D 5 / 2 state owing to the Rydberg excitation followed by a decay into the internal ground 4S 1 / 2 state. By analysing the obtained spectra we extract the polarizability of Rydberg states which agree with numerical calculations. The method is applicable to different Rydberg states regardless of their principal or angular quantum numbers. An accurate value of the state polarizability is needed for quantum gate operations with Rydberg ion crystals.
Trapped Rydberg ions are a promising new system for quantum information processing. They have the potential to join the precise quantum operations of trapped ions and the strong, long-range interactions between Rydberg atoms. Technically, the ion trap will need to stay active while exciting the ions into the Rydberg state, else the strong Coulomb repulsion will quickly push the ions apart. Thus, a thorough understanding of the trap effects on Rydberg ions is essential for future applications. Here we report the observation of two fundamental trap effects. First, we investigate the interaction of the Rydberg electron with the quadrupolar electric trapping field. This effect leads to Floquet sidebands in the spectroscopy of Rydberg D-states whereas Rydberg S-states are unaffected due to their symmetry. Second, we report on the modified trapping potential in the Rydberg state compared to the ground state which results from the strong polarizability of the Rydberg ion. We observe the resultant energy shifts as a line broadening which can be suppressed by cooling the ion to the motional ground state in the directions orthogonal to the excitation laser.
Trapped Rydberg ions are a promising new system for quantum information processing. They have the potential to join the precise quantum operations of trapped ions and the strong, long-range interactions between Rydberg atoms. Combining the two systems is not at all straightforward. Rydberg atoms are severely affected by electric fields which may cause Stark shifts and field ionization, while electric fields are used to trap ions. Thus, a thorough understanding of the physical properties of Rydberg ions due to the trapping electric fields is essential for future applications. Here we report the observation of two fundamental trap effects. First, we investigate the interaction of the Rydberg electron with the trapping electric quadrupole fields which leads to Floquet sidebands in the excitation spectra. Second, we report on the modified trapping potential in the Rydberg state compared to the ground state which results from the strong polarizability of the Rydberg ion. By controlling both effects we observe resonance lines close to their natural linewidth demonstrating an unprecedented level of control of this novel quantum platform.
We demonstrate excitation of a single trapped cold (40)Ca(+) ion to Rydberg levels by laser radiation in the vacuum ultraviolet at a wavelength of 122 nm. Observed resonances are identified as 3d(2)D(3/2) to 51F, 52F and 3d(2)D(5/2) to 64F. We model the line shape and our results imply a large state-dependent coupling to the trapping potential. Rydberg ions are of great interest for future applications in quantum computing and simulation, in which large dipolar interactions are combined with the superb experimental control offered by Paul traps.
We study the dynamics of Rydberg ions trapped in a linear Paul trap, and discuss the properties of ionic Rydberg states in the presence of the static and time-dependent electric fields constituting the trap. The interactions in a system of many ions are investigated and coupled equations of the internal electronic states and the external oscillator modes of a linear ion chain are derived. We show that strong dipole–dipole interactions among the ions can be achieved by microwave dressing fields. Using low-angular momentum states with large quantum defect, the internal dynamics can be mapped onto an effective spin model of a pair of dressed Rydberg states that describes the dynamics of Rydberg excitations in the ion crystal. We demonstrate that excitation transfer through the ion chain can be achieved on a nanosecond timescale and discuss the implementation of a fast two-qubit gate in the ion chain.