arXiv:2005.13659 · Physical Review A
Rydberg spectrum of a single trapped Ca+ ion: A Floquet analysis
Mariusz Pawlak, H. R. Sadeghpour
Abstract
We compute the Rydberg spectrum of a single ${\mathrm{Ca}}^{+}$ ion in a Paul trap by incorporating various internal and external coupling terms of the ion to the trap in the Hamiltonian. The coupling terms include spin-orbit coupling in ${\mathrm{Ca}}^{+}$, charge (electron and ionic core) coupling to the radio frequency and static fields, ion-electron coupling in the Paul trap, and ion center-of-mass coupling. The electronic Rydberg states are precisely described by a one-electron model potential for ${e}^{\ensuremath{-}}+{\mathrm{Ca}}^{2+}$, and accurate eigenenergies, quantum defect parameters, and static and tensor polarizabilities for a number of excited Rydberg states are obtained. The time-periodic rf Hamiltonian is expanded in the Floquet basis, and the trapping-field-broadened Rydberg lines are compared with recent observations of ${\mathrm{Ca}}^{+}(23P)$ and ${\mathrm{Ca}}^{+}(52F)$ Rydberg lines.