The fluctuation-dissipation theorem (FDT) is a hallmark of thermal equilibrium systems in the Gibbs state. We address the question whether the FDT is obeyed by isolated quantum systems in an energy eigenstate. In the framework of the eigenstate thermalization hypothesis, we derive the formal expression for two-time correlation functions in the energy eigenstates or in the diagonal ensemble. They satisfy the Kubo-Martin-Schwinger condition, which is the sufficient and necessary condition for the FDT, in the infinite system size limit. We also obtain the finite size correction to the FDT for finite-sized systems. With extensive numerical works for the XXZ spin chain model, we confirm our theory for the FDT and the finite size correction. Our results can serve as a guide line for an experimental study of the FDT on a finite-sized system.
The fluctuation-dissipation theorem (FDT) is a hallmark of thermal equilibrium systems in the Gibbs state. We address the question whether the FDT is obeyed by isolated quantum systems in an energy eigenstate. In the framework of the eigenstate thermalization hypothesis, we derive the formal expression for two-time correlation functions in the energy eigenstates or in the diagonal ensemble. They satisfy the Kubo-Martin-Schwinger condition, which is the sufficient and necessary condition for the FDT, in the infinite system size limit. We also obtain the finite size correction to the FDT for finite-sized systems. With extensive numerical works for the XXZ spin chain model, we confirm our theory for the FDT and the finite size correction. Our results can serve as a guide line for an experimental study of the FDT on a finite-sized system.
The fluctuation–dissipation theorem (FDT) is a fundamental result in statistical mechanics. It stipulates that, if perturbed out of equilibrium, a system responds at a rate proportional to a thermal-equilibrium property. Applications range from particle diffusion to electrical-circuit noise. To prove the FDT, one must prove that common thermal states obey a symmetry property, the Kubo–Martin–Schwinger (KMS) relation. Energy eigenstates of certain quantum many-body systems were recently proven to obey a KMS relation. The proof relies on the eigenstate thermalization hypothesis (ETH), which explains how such systems thermalize internally. This KMS relation contains a finite-size correction that scales as the inverse system size. Non-Abelian symmetries conflict with the ETH, so a non-Abelian ETH was proposed recently. Using it, we derive a KMS relation for SU(2)-symmetric quantum many-body systems’ energy eigenstates. The finite-size correction scales as usual under certain circumstances but can be polynomially larger in others, we argue. We support the ordinary-scaling result numerically, simulating a Heisenberg chain of 16–24 qubits. The numerics, limited by computational capacity, indirectly support the larger correction. This work helps extend into nonequilibrium physics the effort, recently of interest across quantum physics, to identify how non-Abelian symmetries may alter conventional thermodynamics.
Thermalization of a system when interacting with a thermal bath is an interesting problem. If a system eventually reaches a thermal state in the long time limit, it's expected that its density matrix would resemble the mean-force Gibbs state. Moreover, the correlation function must satisfy the Kubo-Martin-Schwinger (KMS) condition, or equivalently, the fluctuation-dissipation relation (FDR). In this paper, we derive a formal expression for the non-Markovian two-point function within the context of the weak coupling limit. Using this expression, we explicitly compute the two-point function for specific models, demonstrating their adherence to the KMS. In addition, we formulate a nonperturbative approach in the form of a self-consistent approximation that includes a partial resummation of perturbation theory. This approach can capture strong coupling phenomena while still relying on simple equations. Notably, we verify that the two-point function obtained through this method also satisfies the KMS condition.
The fluctuation-dissipation theorem (FDT) is a cornerstone of statistical mechanics, linking the linear response of a system to external perturbations with the equilibrium fluctuations of its constituent degrees of freedom. Traditionally formulated for Hermitian quantum systems in thermal equilibrium, its applicability to non-Hermitian quantum systems, which are increasingly relevant in areas such as open quantum systems, PT-symmetric quantum mechanics, and topological phases, remains a complex and largely unresolved challenge. This paper presents a theoretical framework for a universal fluctuation-dissipation theorem applicable to a broad class of non-Hermitian quantum systems. We demonstrate how the presence of non-Hermiticity, characterized by complex energy eigenvalues and non-orthogonal eigenstates, fundamentally modifies the relationship between correlation functions and response functions. Our derivation utilizes a generalized time-evolution operator and incorporates concepts from non-Hermitian spectral theory, revealing a modified FDT that accounts for energy gain or loss inherent in these systems. The resulting theorem provides insights into the interplay between quantum noise and dissipation in environments far from conventional thermal equilibrium, offering a crucial tool for understanding and engineering non-Hermitian quantum devices. We discuss the implications for non-equilibrium steady states and the breakdown of standard notions of temperature and entropy, proposing a path towards experimental verification in platforms like photonic lattices and cold atoms with controlled losses.
The fluctuation-dissipation theorem (FDT) is a central result in statistical physics, both for classical and quantum systems. It establishes a relationship between the linear response of a system under a time-dependent perturbation and time correlations of certain observables in equilibrium. Here we derive a generalization of the theorem which can be applied to any Markov quantum system and makes use of the symmetric logarithmic derivative (SLD). There are several important benefits from our approach. First, such a formulation clarifies the relation between classical and quantum versions of the equilibrium FDT. Second, and more important, it facilitates the extension of the FDT to arbitrary quantum Markovian evolution, as given by quantum maps. Third, it clarifies the connection between the FDT and quantum metrology in systems with a non-equilibrium steady state.
We present a fluctuation-dissipation theorem (FDT) for nonequilibrium quantum systems with detailed-balance breaking, which deviates from the conventional form of the FDT for equilibrium systems preserving detailed balance. Using the phase space formulation of quantum mechanics and the potential-flux landscape framework, we find that the response function of nonequilibrium quantum systems to external perturbations contains a nontrivial contribution from the quantum curl flux quantifying detailed-balance breaking in the steady state, in addition to the correlation function of observables in the steady state representing the contribution of spontaneous fluctuations which is also present in the equilibrium FDT. We illustrate our general formalism with a harmonic oscillator coupled to two heat baths, and show that the nonequilibrium FDT reduces to the conventional expression at the equilibrium condition when the flux contribution vanishes.
The fluctuation-dissipation theorem (FDT) is a central result in statistical physics, both for classical and quantum systems. It establishes a relationship between the linear response of a system under a time-dependent perturbation and time correlations of certain observables in equilibrium. Here we derive a generalization of the theorem which can be applied to any Markov quantum system and makes use of the symmetric logarithmic derivative (SLD). There are several important benefits from our approach. First, such a formulation clarifies the relation between classical and quantum versions of the equilibrium FDT. Second, and more important, it facilitates the extension of the FDT to arbitrary quantum Markovian evolutions, as given by quantum maps. Third, it brings out the full connection between the FDT and the Quantum Fisher information, the figure of merit in quantum metrology.