The authors study the contributions from populations and coherences to the entropy production in a XY model under a quantum quench protocol. The paper shows that each contribution can signal the quantum phase transition of the model even at high temperatures and that the populations contribution is responsible for the critical behavior of the entropy production.
The authors study the contributions from populations and coherences to the entropy production in a XY model under a quantum quench protocol. The paper shows that each contribution can signal the quantum phase transition of the model even at high temperatures and that the populations contribution is responsible for the critical behavior of the entropy production.
The irreversible work during a driving protocol constitutes one of the most widely studied measures in nonequilibrium thermodynamics, as it constitutes a proxy for entropy production. In quantum systems, it has been shown that the irreversible work has an additional, genuinely quantum mechanical contribution, due to coherence produced by the driving protocol. The goal of this paper is to explore this contribution in systems that undergo a quantum phase transition. Substantial effort has been dedicated in recent years to understanding the role of quantum criticality in work protocols. However, practically nothing is known about how coherence contributes to it. To shed light on this issue, we study the entropy production in infinitesimal quenches of the one-dimensional XY model. We find that coherence plays a significant role in the entropy production and can even account for most of it in certain situations. Moreover, at low temperatures, the coherence presents a finite cusp at the critical point, whereas the entropy production diverges logarithmically. For high temperatures, however, the coherence presents a kink at the critical point indicating the quantum phase transition that occurs only at T=0. Alternatively, if the quench is performed in the anisotropy parameter, then we find that there are situations where all of the entropy produced is due to quantum coherences.
The entropy produced when a system undergoes an infinitesimal quench is directly linked to the work parameter susceptibility, making it sensitive to the existence of a quantum critical point. Its singular behavior at T=0, however, disappears as the temperature is raised, hindering its use as a tool for spotting quantum phase transitions. Notwithstanding, the entropy production can be split into classical and quantum components, related with changes in populations and coherences. In this paper we show that these individual contributions can continue to exhibit signatures of the quantum phase transition, even at arbitrarily high temperatures. This is a consequence of their intrinsic connection to the derivatives of the energy eigenvalues and the energy eigenbasis. We illustrate our results in the Landau-Zener model and the prototypical quantum critical system, the XY model.
Abstract The entropy produced when a quantum system is driven away from equilibrium can be decomposed in two parts, one related with populations and the other with quantum coherences. The latter is usually based on the so-called relative entropy of coherence, a widely used quantifier in quantum resource theories. In this paper we argue that, despite satisfying fluctuation theorems and having a clear resource-theoretic interpretation, this splitting has shortcomings. First, it predicts that at low temperatures the entropy production will always be dominated by the classical term, irrespective of the quantum nature of the process. Second, for infinitesimal quenches, the radius of convergence diverges exponentially as the temperature decreases, rendering the functions non-analytic. Motivated by this, we provide here a complementary approach, where the entropy production is split in a way such that the contributions from populations and coherences are written in terms of a thermal state of a specially dephased Hamiltonian. The physical interpretation of our proposal is discussed in detail. We also contrast the two approaches by studying work protocols in a transverse field Ising chain, and a macrospin of varying dimension.
Symmetries play a central role in both equilibrium and nonequilibrium phase transitions, yet their quantitative characterization in dynamical quantum phase transitions (DQPTs) remains an open challenge. In this work, we establish a direct connection between symmetry properties of a many-body model and measures of quantum asymmetry, showing that asymmetry monotones provide a robust and physically transparent indicator of dynamical quantum criticality. Focusing on the quenched Lipkin-Meshkov-Glick model, we demonstrate that asymmetry measures associated with collective spin generators faithfully capture the onset of DQPTs, reflecting the dynamical restoration or breaking of underlying symmetries. Remarkably, the time-averaged asymmetry exhibits clear signatures of the dynamical critical point, in close correspondence with both the dynamical order parameter and the behavior of entropy production. We further uncover a quantitative link between asymmetry generation and thermodynamic irreversibility, showing that peaks in asymmetry coincide with maximal entropy production across the transition. Our results position asymmetry as a unifying concept bridging symmetry, information-theoretic quantifiers, and nonequilibrium thermodynamics in dynamical quantum phase transitions, providing a powerful framework for understanding critical dynamics beyond traditional order parameters.
Abstract Thermodynamic irreversibility is well characterized by the entropy production arising from non-equilibrium quantum processes. We show that the entropy production of a quantum system undergoing open-system dynamics can be formally split into a term that only depends on population unbalances, and one that is underpinned by quantum coherences. This allows us to identify a genuine quantum contribution to the entropy production in non-equilibrium quantum processes. We discuss how these features emerge both in Lindblad-Davies differential maps and finite maps subject to the constraints of thermal operations. We also show how this separation naturally leads to two independent entropic conservation laws for the global system-environment dynamics, one referring to the redistribution of populations between system and environment and the other describing how the coherence initially present in the system is distributed into local coherences in the environment and non-local coherences in the system-environment state. Finally, we discuss how the processing of quantum coherences and the incompatibility of non-commuting measurements leads to fundamental limitations in the description of quantum trajectories and fluctuation theorems.
Entropy production is a fundamental concept that plays a crucial role in the second law of thermodynamics and the measure of irreversibility. It imposes rigorous constraints on the kinds of transformations allowed in thermodynamic processes. Using an optical setup, here we experimentally demonstrate the division of entropy production of an open quantum system into a population-related component and a coherence-related component, supporting previous theoretical predictions. The coherence-related component represents a genuine quantum contribution with no classical counterpart. By adjusting bath temperatures and initial coherences of the system, we first derive the total entropy production due to both populations and coherences, then remove all the coherences of the system to solely obtain the population-related contribution. The difference between these two results permits to isolate the coherence-related term. Based on this division, our experiment ultimately provides proof of principle that irreversibility at the quantum level can be reduced through properly harnessing the two contributions to entropy production.