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arXiv:2003.05288

The Brownian Motion in an Ideal Quantum Qas

Chi-Chun Zhou, Zhang, Ping, Wu-Sheng Dai

Published Mar 9, 2020• 0 citations
arXivHTMLPDF

Abstract

A Brownian particle in an ideal quantum gas is considered. The mean square displacement (MSD) is derived. The Bose-Einstein or Fermi-Dirac distribution, other than the Maxwell-Boltzmann distribution, provides a different stochastic force compared with the classical Brownian motion. The MSD, which depends on the thermal wavelength and the density of medium particles, reflects the quantum effect on the Brownian particle explicitly. The result shows that the MSD in an ideal Bose gas is shorter than that in a Fermi gas. The behavior of the quantum Brownian particle recovers the classical Brownian particle as the temperature raises. At low temperatures, the quantum effect becomes obvious. For example, there is a random motion of the Brownian particle due to the fermionic exchange interaction even the temperature is near the absolute zero.

DOI
10.48550/arxiv.2003.05288

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Abstract Chapter 11 presents a statistical mechanical treatment of the quantum ideal gases, i.e., the ideal Boltzmann, fermion, and boson gases. The discussion begins with the microscopic description and the solution of the eigenvalue problem for a quantum ideal gas. It is argued that calculating the partition function is most readily accomplished in the grand canonical ensemble using a second-quantized formulation. When the particles are distinguishable, the equation of state is identical to that of a classical ideal gas. For fermions and bosons, however, the problem of computing thermodynamic properties is significantly more complex and can only be solved exactly in certain limits. Away from these limits approximations are needed and are discussed in detail. The relevant distributions - the Fermi-Dirac and Bose-Einstein distributions are derived. The local density approximation of density functional theory is derived for the ideal electron gas. For the ideal boson gas, the phenomenon of Bose-Einstein condensation is discussed
We propose a scheme for quantum brownian motion of a particle in a fermionic bath. Based on the spin coherent-state representation of the noise operators and a canonical thermal distribution of the associated c numbers, we derive a quantum analog of generalized Langevin equation for quantum-mechanical mean position of the particle subjected to an external force field. The approach allows us to map the quantum problem on a classical setting. The quantum dispersion around the mean can be estimated order by order by a set of quantum correction equations up to a desired degree of accuracy for a given nonlinear potential. We derive a quantum diffusion equation for free particle and show that quantization, in general, enhances the mean-square displacement. Increase in temperature leads to suppression of mean-square displacement. The method is based on canonical quantization procedure and may be used for understanding diffusive transport and thermally activated processes in a fermionic bath.
Chandrasekhar's phenomenological theory of brownian motion is transcribed to the quantum regime. The statistics used is that of Boltzmann but the free particle was treated, in addition, with Fermi-Dirac statistics followed by some discussion relating to the measurements of low temperatures. Difficulties arising from the dissipative processes involved are by-passed with the aid of a new methodology enabling one to obtain a propagator in configuration space, which embraces single-particle dissipative forces. This sort of propagator is in turn used for the construction of a type of a nonequilibrium density matrix for the quantum brownian particle. Exact nonequilibrium density matrices for the free and the harmonically bound brownian particles under the influence of external time dependent forces are obtained. Finally, a quantum Fokker-Planck type equation for the general brownian particle is derived. The analysis proceeds via functional integration.
In the frames of classical mechanics the generalized Langevin equation is derived for an arbitrary mechanical subsystem coupled to the harmonic bath of a solid. A time-acting temperature operator is introduced for the quantum Klein-Kramers and Smoluchowski equations, accounting for the effect of the quantum thermal bath oscillators. The model of Brownian emitters is theoretically studied and the relevant evolutionary equations for the probability density are derived. The Schrodinger equation is explained via collisions of the target point particles with the quantum force carriers, transmitting the fundamental interactions between the point particles. Thus, electrons and other point particles are no waves and the wavy chapter of quantum mechanics originated for the force carriers. A stochastic Lorentz-Langevin equation is proposed to describe the underlaying Brownian-like motion of the point particles in quantum mechanics. Considering the Brownian dynamics in the frames of the Bohmian mechanics, the density functional Bohm-Langevin equation is proposed, and the relevant Smoluchowski-Bohm equation is derived. A nonlinear master equation is proposed by proper quantization of the classical Klein-Kramers equation. Its equilibrium solution in the exact canonical Gibbs density operator, while the well-known Caldeira-Leggett equation is simply a linearization at high temperature. In the case of a free quantum Brownian particles, a new law for the spreading of the wave packet it discovered, which represents the quantum generalization of the classical Einstein law of Brownian motion. A new projector operator is proposed for the collapse of the wave function of a quantum particle moving in a classical environment. Its application results in dissipative Schrodinger equations, as well as in a new form of dissipative Liouville equation in classical mechanics.
The Brownian motion of a light quantum particle in a heavy classical gas is theoretically described and a new expression for the friction coefficient is obtained for arbitrary temperature. At zero temperature it equals the de Broglie momentum of the mean free path divided by the mean free path. Alternatively, the corresponding mobility of the quantum particle in the classical gas is equal to the square of the mean free path divided by the Planck constant. The Brownian motion of a quantum particle in a quantum environment is also discussed.
We give a new description of quantum Brownian motion in terms of stochastic pure states. The corresponding path integral propagator allows us to establish a direct connection to the classical Langevin equation, in the Schrodinger picture. We show that in the quantum domain, one is naturally led to consider two stochastic processes driving the Brownian dynamics, one of them representing thermal fluctuations, as in the classical case. The second process reflects growing entanglement between the Brownian particle and its environment, and is therefore a truly quantum noise process. Technically, our result rests on the representation of the full propagator of the Brownian particle and its environment in a coherent state basis. For open system dynamics that may be described by a master equation, such stochastic schemes have already been proven to be efficient Monte Carlo methods. Here, we give a new stochastic scheme that covers low temperatures and strong friction, the latter limit being the case Einstein originally investigated.