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arXiv:2002.07387 · Physical review. B./Physical review. B

Field-induced dimer orders in quantum spin chains

Shunsuke C. Furuya

Published Apr 22, 2020• 5 citations
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Abstract

Field-induced excitation gaps in quantum spin chains are an interesting phenomenon related to confinements of topological excitations. In this paper I present a type of this phenomenon. I show that an effective magnetic field with a fourfold screw symmetry induces the excitation gap accompanied by dimer orders. The dimer order parameter and the excitation gap exhibit characteristic power-law dependence on the fourfold screw-symmetric field. Moreover, the field-induced dimer order and the field-induced N\'eel order coexist when the external uniform magnetic field, the fourfold screw-symmetric field, and the twofold staggered field are applied. This situation is in close connection with a compound $[\mathrm{Cu}(\mathrm{pym}){({\mathrm{H}}_{2}\mathrm{O})}_{4}]{\mathrm{SiF}}_{6}\ifmmode\cdot\else\textperiodcentered\fi{}{\mathrm{H}}_{2}\mathrm{O}$ [J. Liu et al., Phys. Rev. Lett. 122, 057207 (2019)]. In this paper I discuss a mechanism of field-induced dimer orders by using a density-matrix renormalization group method, a perturbation theory, and quantum field theories.

DOI
10.1103/physrevb.101.134425

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Field-induced excitation gaps in quantum spin chains are an interesting phenomenon related to confinements of topological excitations. In this paper I present a type of this phenomenon. I show that an effective magnetic field with a fourfold screw symmetry induces the excitation gap accompanied by dimer orders. The dimer order parameter and the excitation gap exhibit characteristic power-law dependence on the fourfold screw-symmetric field. Moreover, the field-induced dimer order and the field-induced N'eel order coexist when the external uniform magnetic field, the fourfold screw-symmetric field, and the twofold staggered field are applied. This situation is in close connection with a compound [Cu(pym)(H2O)4]SiF6\ifmmode⋅\else\textperiodcentered\fiH2O[\mathrm{Cu}(\mathrm{pym}){({\mathrm{H}}_{2}\mathrm{O})}_{4}]{\mathrm{SiF}}_{6}\ifmmode\cdot\else\textperiodcentered\fi{}{\mathrm{H}}_{2}\mathrm{O}[Cu(pym)(H2​O)4​]SiF6​\ifmmode⋅\else\textperiodcentered\fiH2​O [J. Liu et al., Phys. Rev. Lett. 122, 057207 (2019)]. In this paper I discuss a mechanism of field-induced dimer orders by using a density-matrix renormalization group method, a perturbation theory, and quantum field theories.
A recent study [J. Lou, et al., Phys. Rev. Lett. 94, 217207 (2005)] reveals that topological edge effects induce bound midgap states in antiferromagnetic Heisenberg chains with a staggered magnetic field. We report density matrix renormalization group calculations that examine the effects of high magnetic field on the gap and midgap states and the range of validity of the field theory prediction on their scaling behavior. We also investigate the effects of the site parity (i.e., even or odd number of sites in the chain), the dilution of the spin chain by dopant atoms, and the uniform magnetic field on the emergence and evolution of the midgap states. The results provide useful insights into the behavior of the edge excitations in spin chain materials, which should facilitate the comparison between theory and experiment and stimulate further investigations.
We study the spin-12\frac{1}{2}21​ antiferromagnetic Heisenberg chain in both uniform and (perpendicular) staggered magnetic fields using the density-matrix renormalization-group method. This model has been shown earlier to describe the physics of the copper benzoate materials in magnetic field. In the present work, we extend the study to more general case for a systematic investigation of the field-induced gap and related properties of the spin-12\frac{1}{2}21​ antiferromagnetic Heisenberg chain. In particular, we explore the high magnetic field regime where interesting behaviors in the field-induced gap, magnetization, and spin correlation functions are found. Careful examination of the low energy properties and magnetization reveals interesting competing effects of the staggered and uniform fields. The incommensurate behavior in the spin correlation functions is demonstrated and discussed in detail. The present work reproduces earlier results in good agreement with experimental data on copper benzoate and predicts new interesting field-induced features at very high magnetic field.
A frustrated spin-1/21/21/2 XXZ chain model comprising a ferromagnetic nearest-neighbor coupling with the bond alternation, ${J}_{1}(1\ifmmode\pm\else\textpm\fi{}\ensuremath{\delta})<0$, and an antiferromagnetic second-neighbor exchange coupling J2>0{J}_{2}>0J2​>0 is studied at zero and weak magnetic fields by means of density-matrix renormalization-group calculations of order parameters, correlation functions, and the entanglement entropy, as well as an Abelian bosonization analysis. At zero magnetic field, the bond alternation $\ensuremath{\delta}>0$ suppresses the gapless phase characterized by a vector-chiral (VC) long-range order (LRO) and a quasi-LRO of an incommensurate spin spiral, whereas this phase occupies a large region in the space of J1/J2{J}_{1}/{J}_{2}J1​/J2​ and the easy-plane exchange anisotropy for $\ensuremath{\delta}=0$ [S. Furukawa et al., Phys. Rev. Lett. 105, 257205 (2010)]. Then, four gapped phases are found to appear as the exchange anisotropy varies from the SU(2)-symmetric case to the U(1)-symmetric case: the Haldane dimer (D+{}_{+}+​) phase with the same sign of the x,yx,yx,y- and zzz-component dimer order parameters, two VC dimer (VCD+{}_{+}+​/VCD${}_{\ensuremath{-}}$) phases with the sign of the zzz-component dimer order parameter being unaltered/reversed, and the even-parity dimer (D${}_{\ensuremath{-}}$) phase. At small magnetic fields, a field-induced ring-exchange interaction, which is proportional to a staggered scalar chirality and a magnetic flux penetrating the associated triangle, drives a transition from the D${}_{\ensuremath{-}}$ phase into a VC-Neel-dimer (VCND) phase, but not from the D+{}_{+}+​ phase. This VCND phase is stable up to the large magnetic field at which the Zeeman term closes the spin gap. A possible relevance to Rb2{}_{2}2​Cu2{}_{2}2​Mo3{}_{3}3​O12{}_{12}12​ is discussed.
Recent experiments on the S=12S=\frac{1}{2}S=21​ antiferromagnetic chain compound, Cu benzoate, discovered an unexpected gap scaling as approximately the 23\frac{2}{3}32​ power of an applied magnetic field. A theory of this gap, based on an effective staggered field, orthogonal to the applied uniform field, resulting from a staggered gyromagnetic tensor and a Dzyaloshinskii-Moriya interaction, leading to a sine-Gordon quantum field theory, has been developed. Here we discuss many aspects of this subject in considerable detail, including a review of the S=12S=\frac{1}{2}S=21​ chain in a uniform field, a spin-wave theory analysis of the uniform plus staggered field problem, exact amplitudes for the scaling of gap, staggered susceptibility and staggered magnetization with field or temperature, intensities of soliton and breather peaks in the structure function, and field and temperature dependence of the total susceptibility.
Motivated by intense research on two-dimensional spin-12\frac{1}{2}21​ Kitaev materials, Kitaev spin chains and ladders, though geometrically limited, have been studied for their numerical simplicity and insights into extended Kitaev models. The phase diagrams under the magnetic field were also explored for these quasi-one-dimensional models. For an isotropic Kitaev chain, it was found that a magnetic field polarizes the ground state except along the symmetric field angle, where the chain is found to remain gapless up to a critical field strength where it enters an intriguing soliton phase before reaching the polarized state at higher field strengths. Here we study an anisotropic Kitaev chain under a magnetic field using the density matrix renormalization group technique, where the ground state has a macroscopic degeneracy with a finite gap in the absence of the magnetic field. When the field is mainly aligned parallel to the strong bond, four-site and large unit-cell ordered phases arise. In a certain angle of the field, another ordered phase characterized by a uniform chirality with six-site periodicity emerges. We employ a perturbation theory to understand such field-induced ordered phases. The effective model uncovers the presence of transverse Ising and Dzyaloshinskii-Moriya interactions between unit cells, as well as further-neighbor Ising interaction induced by the magnetic field, which collectively explain the mechanisms behind these ordered states. Open questions and challenges are also discussed.
Correlation functions of dimer operators, the product operators of spins on two adjacent sites, are studied in the spin-12\frac{1}{2}21​ XXZ chain in the critical regime. The amplitudes of the leading oscillating terms in the dimer correlation functions are determined with high accuracy as functions of the exchange anisotropy parameter and the external magnetic field through the combined use of bosonization and density-matrix renormalization-group methods. In particular, for the antiferromagnetic Heisenberg model with SU(2) symmetry, logarithmic corrections to the dimer correlations due to the marginally irrelevant operator are studied, and the asymptotic form of the dimer correlation function is obtained. The asymptotic form of the spin-Peierls excitation gap including logarithmic corrections is also derived.