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arXiv:2002.06332 · Physical Review Letters

Quantum Jarzynski Equality in Open Quantum Systems from the One-Time Measurement Scheme

Akira Sone, Yi-Xiang Liu, Paola Cappellaro

Published Aug 7, 2020• 48 citations
arXivHTMLPDF

Abstract

In open quantum systems, a clear distinction between work and heat is often challenging, and extending the quantum Jarzynski equality to systems evolving under general quantum channels beyond unitality remains an open problem in quantum thermodynamics. In this Letter, we introduce well-defined notions of guessed quantum heat and guessed quantum work, by exploiting the one-time measurement scheme, which only requires an initial energy measurement on the system alone. We derive a modified quantum Jarzynski equality and the principle of maximum work with respect to the guessed quantum work, which requires the knowledge of the system only. We further show the significance of guessed quantum heat and work by linking them to the problem of quantum hypothesis testing.

DOI
10.1103/physrevlett.125.060602

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In open quantum systems, a clear distinction between work and heat is often challenging, and extending the quantum Jarzynski equality to systems evolving under general quantum channels beyond unitality remains an open problem in quantum thermodynamics. In this Letter, we introduce well-defined notions of guessed quantum heat and guessed quantum work, by exploiting the one-time measurement scheme, which only requires an initial energy measurement on the system alone. We derive a modified quantum Jarzynski equality and the principle of maximum work with respect to the guessed quantum work, which requires the knowledge of the system only. We further show the significance of guessed quantum heat and work by linking them to the problem of quantum hypothesis testing.
One of the most important problems in quantum thermodynamics is how to distinguish work and heat in autonomous quantum systems. In this paper, work and heat are defined through the following criterion, i.e., work is the energy that cannot change the entropy of the energy resource, and satisfies the Jarzynski equality, while heat does not. Two kinds of definitions satisfying the two corresponding requirements are proposed and demonstrated, and the consistency condition of the two kinds is given. Through the first definition, the problem of entropy production is investigated. A model study is also presented to verify the proposal.
Measuring the fluctuations of work in coherent quantum systems is notoriously problematic. Aiming to reveal the ultimate source of these problems, we demand of work measurement schemes the sheer minimum and see if those demands can be met at all. We require (A\mathfrak{A}A) energy conservation for arbitrary initial states of the system and (B\mathfrak{B}B) the Jarzynski equality for thermal initial states. By energy conservation we mean that the average work must be equal to the difference of initial and final average energies, and that untouched systems must exchange deterministically zero work. Requirement B\mathfrak{B}B encapsulates the second law of thermodynamics and the quantum--classical correspondence principle. We prove that work measurement schemes that do not depend on the system's initial state satisfy B\mathfrak{B}B if and only if they coincide with the famous two-point measurement scheme, thereby establishing that state-independent schemes cannot simultaneously satisfy A\mathfrak{A}A and B\mathfrak{B}B. Expanding to the realm of state-dependent schemes allows for more compatibility between A\mathfrak{A}A and B\mathfrak{B}B. However, merely requiring the state-dependence to be continuous still effectively excludes the coexistence of A\mathfrak{A}A and B\mathfrak{B}B, leaving the theoretical possibility open for only a narrow class of exotic schemes.
Work is an important quantity in thermodynamics. In a closed quanutm system, the two-point energy measurements can be applied to measure the work but cannot be utilized in an open quantum system. With the two-point energy measurements, it has been shown that the work fluctuation satisfies the Jarzynski equality. We propose a scheme to measure the work in an open quantum system through the technique of reservoir engineering. Based on this scheme, we show that the work fluctuation in open quantum system may violate the Jarzynski equality. We apply our scheme to a two-level atom coupled to an engineered reservoir and numerically justify the general results, especially demonstrating that the second law of thermodynamics can be violated.
It has been established that the inclusive work for classical, Hamiltonian dynamics is equivalent to the two-time energy measurement paradigm in isolated quantum systems. However, a plethora of other notions of quantum work has emerged, and thus the natural question arises whether any other quantum notion can provide motivation for purely classical considerations. In the present analysis, we propose the conditional stochastic work for classical, Hamiltonian dynamics, which is inspired by the one-time measurement approach. This novel notion is built upon the change of expectation value of the energy conditioned on the initial energy surface. As main results we obtain a generalized Jarzynski equality and a sharper maximum work theorem, which account for how non-adiabatic the process is. Our findings are illustrated with the parametric harmonic oscillator.
Estimation of work at the quantum scale remains a central challenge in quantum thermodynamics. Canonical approaches have a fundamental drawback: they assume classical control of the quantum system, as implicit in a time-dependent Hamiltonian. Yet the energetic cost of implementing this control is omitted and can exceed the system's energy scale by orders of magnitude, calling into question the operational significance of work values. We address this by autonomizing the controlled energy transfer, embedding the driven dynamics into an energy-conserving evolution on a larger quantum system. Work is then unambiguously identified with the energy transferred between the two systems, singling out a unique observable on the driven system: the work operator. We show that the quantum work operator evades a no-go theorem by deriving a quantum fluctuation theorem that recovers the Jarzynski equality in classical scenarios. We incorporate imperfect control and quantify corrections to work statistics. Extending the framework to open quantum systems, we obtain an operatorial first law in which work, heat, and internal-energy changes are represented by distinct operators on the reduced system. Together, these results settle the long-standing debate over whether work is a quantum observable: it is, once the controlling system is included in the description rather than treated as external.
The classical Jarzynski equality establishes an exact relation between the stochastic work performed on a system driven out of thermal equilibrium and the free energy difference in a corresponding quasistatic process. This fluctuation theorem bears experimental relevance, as it enables the determination of the free energy difference through the measurement of externally applied work in a nonequilibrium process. In the quantum case, the Jarzynski equality only holds if the measurement procedure of the stochastic work is drastically changed: it is replaced by a so-called two-point measurement scheme that requires the knowledge of the initial and final Hamiltonian and therefore lacks the predictive power for the free energy difference that the classical Jarzynski equation is known for. Here, we propose a quantum fluctuation theorem that is valid for externally measurable quantum work determined during the driving protocol. In contrast to the two-point measurement case, the theorem also applies to open quantum systems and the scenario can be realized without knowing the system Hamiltonian. Our fluctuation theorem comes in the form of an inequality and therefore only yields bounds to the true free energy difference. The inequality is saturated in the quasiclassical case of vanishing energy coherences at the beginning and at the end of the protocol. Thus, there is a clear quantum disadvantage.