We discuss the properties of bound states in finite-bandwidth waveguide QED beyond the rotating wave approximation or excitation-number-conserving light-matter coupling models. Therefore, we extend the standard calculations to a broader range of light-matter strengths, in particular, in the so-called ultrastrong coupling regime. We do this using the polaron technique. Our main results are as follows: We compute the spontaneous emission rate, which is renormalized as compared with the Fermi golden rule formula. We generalize the existence criteria for bound states, their properties, and their role in the qubit thermalization. We discuss effective spin-spin interactions through both vacuum fluctuations and bound states. Finally, we sketch a perfect state-transfer protocol among distant emitters mediated by bound states.
We discuss the properties of bound states in finite-bandwidth waveguide QED beyond the rotating wave approximation or excitation-number-conserving light-matter coupling models. Therefore, we extend the standard calculations to a broader range of light-matter strengths, in particular, in the so-called ultrastrong coupling regime. We do this using the polaron technique. Our main results are as follows: We compute the spontaneous emission rate, which is renormalized as compared with the Fermi golden rule formula. We generalize the existence criteria for bound states, their properties, and their role in the qubit thermalization. We discuss effective spin-spin interactions through both vacuum fluctuations and bound states. Finally, we sketch a perfect state-transfer protocol among distant emitters mediated by bound states.
Quantum optics with giant emitters has shown a new route for the observation and manipulation of non-Markovian properties in waveguide QED. In this paper we extend the theory of giant atoms, hitherto restricted to the perturbative light-matter regime, to deal with the ultrastrong-coupling regime. Using static and dynamical polaron methods, we address the low-energy subspace of a giant atom coupled to an Ohmic waveguide beyond the standard rotating-wave approximation. We analyze the equilibrium properties of the system by computing the atomic frequency renormalization as a function of the coupling characterizing the localization-delocalization quantum phase transition for a giant atom. We show that virtual photons dressing the ground state are nonexponentially localized around the contact points but decay as a power law. The dynamics of an initially excited giant atom is studied, pointing out the effects of ultrastrong coupling on the Lamb shift and the spontaneous emission decay rate. Finally, we comment on the existence of the so-called oscillating bound states beyond the rotating-wave approximation.
Starting from the paradigmatic spin-boson model (SBM), we investigate the static and dynamical properties of a system of two distant two-level emitters coupled to a one-dimensional Ohmic waveguide beyond the rotating wave approximation (RWA). Employing static and dynamical polaron ansatze we study the effects of finite separation distance on the behavior of the photon-mediated Ising-like interaction, qubit frequency renormalization, ground state magnetization, and entanglement entropy of the two qubit system. Based on previous works we derive an effective approximate Hamiltonian for the two-impurity SBM that preserves the excitation-number and thus facilitates the analytical treatment. In particular, it allows us to introduce non-Markovianity arising from delay-feedback effects in two distant emitters in the so-called ultrastrong coupling (USC) regime. We test our results with numerical simulations performed over a discretized circuit-QED model, finding perfect agreement with previous results, and showing interesting new dynamical effects arising in ultrastrong waveguide-QED with distant emitters. In particular, we revisit the Fermi two-atom problem showing that, in the USC regime, initial correlations yield two different evolutions for symmetric and antisymmetric states even before the emitters become causally connected. Finally, we demonstrate that the collective dynamics, e.g., superradiance or subradiance, are affected not only by the distance between emitters, but also on the coupling, due to significant frequency renormalization. This constitutes another dynamical consequence of the USC regime.
Starting from the paradigmatic spin-boson model (SBM), we investigate the static and dynamical properties of a system of two distant two-level emitters coupled to a one-dimensional Ohmic waveguide beyond the rotating wave approximation. Employing static and dynamical polaron Ans\"atze we study the effects of finite separation distance on the behavior of the photon-mediated Ising-like interaction, qubit frequency renormalization, ground-state magnetization, and entanglement entropy of the two-qubit system. Based on previous works we derive an effective approximate Hamiltonian for the two-impurity SBM that preserves the excitation-number and thus facilitates the analytical treatment. In particular, it allows us to introduce non-Markovianity arising from delay-feedback effects in two distant emitters in the so-called ultrastrong coupling (USC) regime. We test our results with numerical simulations performed over a discretized circuit-QED model, finding perfect agreement with previous results, and showing interesting dynamical effects arising in ultrastrong waveguide QED with distant emitters. In particular, we revisit the Fermi two-atom problem showing that, in the USC regime, initial correlations yield two different evolutions for symmetric and antisymmetric states even before the emitters become causally connected. Finally, we demonstrate that the collective dynamics, e.g., superradiance or subradiance, are affected not only by the distance between emitters, but also by the coupling, due to significant frequency renormalization. This constitutes another dynamical consequence of the USC regime.
In this work we develop a semianalytical variational Ansatz to study the properties of few-photon excitations interacting with a collection of quantum emitters in regimes that go beyond the rotating-wave approximation. This method can be used to approximate both the static and dynamical properties of a superconducting qubit in an open transmission line, including the spontaneous emission spectrum and the resonances in scattering experiments. The approximations are quantitatively accurate for rather strong couplings, as shown by a direct comparison to matrix-product-state numerical methods, and provide also a good qualitative description for stronger couplings well beyond the Markovian regime.
Waveguide quantum electrodynamics (waveguide QED) describes the interaction between an electromagnetic field confined to a one-dimensional waveguide with atom-like quantum emitters close by. The characteristics of these kinds of systems are the possibility for strong and even ultrastrong interactions between the photonic and atom-like systems, and practically infinite range interactions between the emitters. These properties are valuable for a wide range of quantum optical applications, like quantum communication, quantum networks and quantum metrology. In this thesis we focus on two challenges in quantum optics, namely the generation and scattering of multiphoton states. In the first part of this thesis we demonstrate how waveguide QED systems can be exploited for the generation of multiphoton states, in particular of single-mode Fock states and superpositions thereof as well as multi-mode photonic states with metrological applications. The basic setup for this goal is an ensemble of quantum emitters coupled to a waveguide. In the so-called atomic mirror configuration symmetric Dicke states (or a superposition thereof) decay superradiantly to the ground state and emit the desired multiphoton state, which can be efficiently collected at the ends of the waveguide. We propose various protocols for the preparation of these Dicke states in waveguide QED systems and characterize the emitted photonic state. It turns out that in the low excitation regime, that is, if the number of photons is much lower than the ensemble size, the photonic state is emitted into a single mode. This single-mode structure is fundamental to current proposals for applications in quantum metrology with optical interferometers. Outside the low excitation regime, a multi-mode photonic state is generated, for which the metrological capabilities were unknown. We were able to show that these states still lead to quantum-enhanced optical interferometry. In the second part of this thesis we demonstrate how the scattering of multiphoton states on a single quantum emitter coupled to the waveguide can be used for testing the limits of the light-matter interaction strength. In particular, we investigate systems in the so-called ultrastrong coupling regime, where the coupling strength between the photonic and atom-like system is of the order of the emitter's transition energy. In this regime, many methods and approximations used in quantum optics, especially the Rotating Wave Approximation, break down and one needs to develop new analytical and numerical methods to study these systems. One approach is the so-called polaron Transformation. We show how this transformation can be applied for predicting the scattering amplitude of few photons scattering on the emitter. The comparison of these results with numerical simulations using matrix product states shows a good agreement for moderate coupling strengths. Both parts together show that waveguide QED systems are promising candidates for the generation of multiphoton states as well as for the investigation of fundamental limits probed through the scattering of multiphoton states. The latter also finds application in the implementation of photon-photon nonlinearities induced by the interaction with the quantum emitters. Apart from these and many other theoretical predictions, waveguide QED systems are also undergoing rapid progress in experiments. Therefore, we expect these kinds of systems to bring forth several advances in the field of quantum optics.
Understanding physical properties of quantum emitters strongly interacting with quantized electromagnetic modes is one of the primary goals in the emergent field of waveguide quantum electrodynamics (QED). When the light-matter coupling strength is comparable to or even exceeds energies of elementary excitations, conventional approaches based on perturbative treatment of light-matter interactions, two-level description of matter excitations, and photon-number truncation are no longer sufficient. Here we study in and out of equilibrium properties of waveguide QED in such nonperturbative regimes on the basis of a comprehensive and rigorous theoretical approach using an asymptotic decoupling unitary transformation. We uncover several surprising features ranging from symmetry-protected many-body bound states in the continuum to strong renormalization of the effective mass and potential; the latter may explain recent experiments demonstrating cavity-induced changes in chemical reactivity as well as enhancements of ferromagnetism or superconductivity. To illustrate our general results with concrete examples, we use our formalism to study a model of coupled cavity arrays, which is relevant to experiments in superconducting qubits interacting with microwave resonators or atoms coupled to photonic crystals. We examine the relation between our results and delocalization-localization transition in the spin-boson model; notably, we point out that a reentrant transition can occur in the regimes where the coupling strength becomes the dominant energy scale. We also discuss applications of our results to other problems in different fields, including quantum optics, condensed matter physics, and quantum chemistry.