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arXiv:1912.06632 · Scientific Reports

Detecting initial correlations via correlated spectroscopy in hybrid quantum systems

Parth Jatakia, Sai Vinjanampathy, Kasturi Saha

Published Oct 20, 2021• 3 citations
arXivHTMLPDF

Abstract

Generic mesoscopic quantum systems that interact with their environment tend to display appreciable correlations with environment that often play an important role in the physical properties of the system. However, the experimental methods needed to characterize such systems either ignore the role of initial correlations or scale unfavourably with system dimensions. Here, we present a technique that is agnostic to system-environment correlations and can be potentially implemented experimentally. Under a specific set of constraints, we demonstrate the ability to detect and measure specific correlations. We apply the technique to two cases related to Nitrogen Vacancy Centers (NV). Firstly, we use the technique on an NV coupled to a P1 defect centre in the environment to demonstrate the ability to detect dark spins. Secondly, we implement the technique on a hybrid quantum system of NV coupled to an optical cavity with initial correlations. We extract the interaction strength and effective number of interacting NVs from the initial correlations using our technique.

DOI
10.1038/s41598-021-99718-7

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Generic mesoscopic quantum systems that interact with their environment tend to display appreciable correlations with environment that often play an important role in the physical properties of the system. However, the experimental methods needed to characterize such systems either ignore the role of initial correlations or scale unfavourably with system dimensions. Here, we present a technique that is agnostic to system-environment correlations and can be potentially implemented experimentally. Under a specific set of constraints, we demonstrate the ability to detect and measure specific correlations. We apply the technique to two cases related to Nitrogen Vacancy Centers (NV). Firstly, we use the technique on an NV coupled to a P1 defect centre in the environment to demonstrate the ability to detect dark spins. Secondly, we implement the technique on a hybrid quantum system of NV coupled to an optical cavity with initial correlations. We extract the interaction strength and effective number of interacting NVs from the initial correlations using our technique.
We show that the dynamics of any open quantum system that is initially correlated with its environment can be described by a set of d2{d}^{2}d2 (or less) completely positive maps, where ddd is the dimension of the system. Only one such map is required for the special case of no initial correlations. The same maps describe the dynamics of any system-environment state obtained from the initial state by a local operation on the system. The reduction of the system dynamics to a set of completely positive maps allows known numerical and analytic tools for uncorrelated initial states to be applied to the general case of initially correlated states, which we exemplify by solving the qubit dephasing model for such states, and provides a natural approach to quantum Markovianity for this case. We show that this set of completely positive maps can be experimentally characterized using only local operations on the system, via a generalization of noise spectroscopy protocols. As further applications, we first consider the problem of retrodicting the dynamics of an open quantum system which is in an arbitrary state when it becomes accessible to the experimenter and explore the conditions under which retrodiction is possible. We also introduce a related one-sided or limited-access tomography protocol for determining an arbitrary bipartite state, evolving under a sufficiently rich Hamiltonian, via local operations and measurements on just one component. We simulate this protocol for a physical model of particular relevance to nitrogen-vacancy centers and in particular show how to reconstruct the density matrix of a set of three qubits, interacting via dipolar coupling and in the presence of local magnetic fields, by measuring and controlling only one of them.
Open quantum systems are a subject of immense interest as their understanding is crucial in the implementation of modern quantum technologies. In the study of their dynamics, the role of the initial system–environment correlations is commonly ignored. In this work, to gain insights into the role of these correlations, we solve an exactly solvable model of a single two-level system interacting with a spin environment, with the initial system state prepared by a suitable unitary operation. By solving the dynamics exactly for arbitrary system–environment coupling strength while taking into account the initial system–environment correlations, we show that the effect of the initial correlations is, in general, very significant and nontrivial. To further highlight the importance of the initial system–environment correlations, we also extend our study to investigate the dynamics of the entanglement between two two-level systems interacting with a common spin environment.
Nitrogen vacancy centers in diamond (NVs) are point defects well suited to quantum sensing of magnetic fields. NV spin states can be initialized and read out optically with high spatial resolution, enabling detection of pL-scale volumes of nuclear spins. Using Coherently Averaged Synchronized Readout (CASR), standard NMR spectroscopy techniques such as free decay, spin echo, and PGSE have been performed with Hz-scale spectral resolution using NV-diamond sensors. However, using NV detection for conventional high-resolution NMR at multi-tesla fields is challenging due to the need to manipulate NV electronic spins at resonance frequencies 100 GHz or higher. Low-field J-coupling spectroscopy provides an alternative path to chemical resolution in a regime more easily accessible to NVs. Here, we demonstrate homonuclear and heteronuclear J-coupling spectroscopy using an NV-NMR spectrometer based on permanent magnets operating at $\sim$890 kHz proton Larmor frequency (bias magnetic field $\sim21mT).ThisfieldstrengthenableschemicalcharacterizationbasedonJ−couplingusingsequencessuchasSynchronizedEcho(SyncE)andSpin−EchoDoubleResonance(SEDOR),whichdonotrequirethestrongchemicalshiftdispersionandpristinefieldhomogeneityofhigh−fieldNMR.ThefrequencyrangeiseasilydetectedbyNVsusingstandardXYdynamicaldecouplingsequencesandiswell−suitedforapplyingOverhauserDNP,whichcanboostprotonsignalbytwoordersofmagnitude.WeacquireinitialNV−NMRmeasurementsofT21 mT). This field strength enables chemical characterization based on J-coupling using sequences such as Synchronized Echo (SyncE) and Spin-Echo Double Resonance (SEDOR), which do not require the strong chemical shift dispersion and pristine field homogeneity of high-field NMR. The frequency range is easily detected by NVs using standard XY dynamical decoupling sequences and is well-suited for applying Overhauser DNP, which can boost proton signal by two orders of magnitude. We acquire initial NV-NMR measurements of T21mT).ThisfieldstrengthenableschemicalcharacterizationbasedonJ−couplingusingsequencessuchasSynchronizedEcho(SyncE)andSpin−EchoDoubleResonance(SEDOR),whichdonotrequirethestrongchemicalshiftdispersionandpristinefieldhomogeneityofhigh−fieldNMR.ThefrequencyrangeiseasilydetectedbyNVsusingstandardXYdynamicaldecouplingsequencesandiswell−suitedforapplyingOverhauserDNP,whichcanboostprotonsignalbytwoordersofmagnitude.WeacquireinitialNV−NMRmeasurementsofT_1,T, T,T_2,andOverhauserDNPinglycerolbeforeadvancingtoSEDORspectroscopyofmethanol−, and Overhauser DNP in glycerol before advancing to SEDOR spectroscopy of methanol-,andOverhauserDNPinglycerolbeforeadvancingtoSEDORspectroscopyofmethanol−^{13}Candamethanol−C and a methanol-Candamethanol−^{13}C/acetonitrile−2−C/acetonitrile-2-C/acetonitrile−2−^{13}$C mixture at sample volumes $\sim$50 pL, in which we demonstrate measurement of 1JCH^1J_\text{CH}1JCH​ couplings and resolution between species. We also acquire a homonuclear J-coupling spectrum of a natural-abundance propylene carbonate sample.
Correlations between a system and its environment lead to errors in an open quantum system. Detecting those correlations would be valuable for avoiding and/or correcting those errors. Here we show that we can detect correlations by measuring only the system itself if we know the cause of the interaction between the two, for example, in the case of a dipole-dipole interaction. We investigate the unitary UUU which is associated with the exchange Hamiltonian and examine the ability to detect initial correlations between a system and its environment for various types of initial states. The states we select are motivated by realistic experimental conditions, and we provide bounds for when we can state with certainty that there are initial system-environment correlations given experimental data.
Dimensionality plays a central role in determining the collective behavior of interacting quantum systems. Engineering strongly interacting ensembles of solid-state spin defects in reduced dimensions remains a significant challenge at the interface between the applied and fundamental sciences. Here, we create and characterize a positionally disordered, quasi-one-dimensional spin chain in diamond, consisting of optically dark substitutional nitrogen defects (P1 centers) and optically addressable probe nitrogen-vacancy (NV) centers. Our approach exploits the preferential incorporation of nitrogen along step bunches formed during chemical vapor deposition to achieve both lateral and vertical confinement. Combining spatially resolved materials characterization with nanoscale quantum sensing, we establish the one-dimensional character of the optically dark, unpolarized P1 spin ensemble. We then use correlation spectroscopy to probe local spin autocorrelations and investigate infinite-temperature dipolar spin transport. Our results establish a materials-based route for engineering low-dimensional quantum spin systems.
The ready optical detection and manipulation of bright nitrogen vacancy center spins in diamond plays a key role in contemporary quantum information science and quantum metrology. Other optically dark defects such as substitutional nitrogen atoms (`P1 centers') could also become potentially useful in this context if they could be as easily optically detected and manipulated. We develop a relatively straightforward continuous wave protocol that takes advantage of the dipolar coupling between nitrogen vacancy and P1 centers in type 1b diamond to detect and polarize the dark P1 spins. By combining mutual spin flip transitions with radio frequency driving, we demonstrate the simultaneous optical polarization and detection of the electron spin resonance of the P1 center. This technique should be applicable to detecting and manipulating a broad range of dark spin populations that couple to the nitrogen vacancy center via dipolar fields, allowing for quantum metrology using these spin populations.