Abstract Putting a general, physically relevant upper bound on equilibration times in closed quantum systems is a recently much pursued endeavor. In 2017 Phys. Rev. X 7 031027 García-Pintos et al suggest such a bound. We point out that the general assumptions which allow for an actual estimation of this bound are violated in cases in which Fermi’s golden rule and related open quantum system theories apply. To probe the range of applicability of Fermi’s golden rule for systems of the type addressed in the above work, we numerically solve the corresponding Schrödinger equation for some finite spin systems comprising up to 25 spins. These calculations shed light on the breakdown of standard quantum master equations in the ‘superweak’ coupling limit, which occurs for finite sized baths.
Abstract Putting a general, physically relevant upper bound on equilibration times in closed quantum systems is a recently much pursued endeavor. In 2017 Phys. Rev. X 7 031027 García-Pintos et al suggest such a bound. We point out that the general assumptions which allow for an actual estimation of this bound are violated in cases in which Fermi’s golden rule and related open quantum system theories apply. To probe the range of applicability of Fermi’s golden rule for systems of the type addressed in the above work, we numerically solve the corresponding Schrödinger equation for some finite spin systems comprising up to 25 spins. These calculations shed light on the breakdown of standard quantum master equations in the ‘superweak’ coupling limit, which occurs for finite sized baths.
Putting a generally valid upper bound on equilibration times of physically relevant observables is a much pursued endeavor. Recently, such a bound has been suggested by Garcia-Pintos et al. While the mathematical correctness of the bound as such is undisputed, its concrete calculation requires the knowledge of certain quantities, which Garcia-Pintos et al. assess by means of assumptions. We show that, e.g., in standard cases of slow, exponential equilibration, (at least) one of these assumptions is not valid. This demonstration highlights the difficulty to judge the validity of the above assumptions without further information. Such information is, in general, very hard to obtain.
Abstract The Golden Rule is a colloquial name for a standard formula in time-dependent quantum mechanics. It provides a way to calculate the rate of transition between quantum states. It is approximate and has limited applicability; however, it is the starting point for many treatments of rate processes. Later it will be used in the discussion of master equations. This section gives the usual derivation of the Golden Rule. The following section shows how it is used to relate optical absorption spectra to time correlation functions.
Finding the equilibration time scale is an important open question in studying the equilibration of quantum systems. There are many kinds of systems that are unable to achieve equilibration, such as Anderson insulator, many-body localization systems and some integrable systems. For those systems that can reach equilibration, it was proved that there exists a general equilibration time scale. But these upper bounds are unrealistically long, and the lower bounds are also unrealistically short. How to get an accurate and general equilibration time scale is still unclear. In this paper, we study local equilibration time scales in quantum lattice systems. With the relation between equilibration and entanglement entropy, we define a new criterion for equilibration. This criterion is based on Rényi entropy, which is simpler for calculation. Moreover, the production of Rényi entropy is highly dependent on the spreading of information, and hence the tools developed in quantum information theory can help a lot. For the upper bound of equilibration time, we use the normal criterion of the time average ofthe fluctuation of the observation. This equilibration criterion is assessed with concrete observable operator, hence it is more accurate than the criterion of Rényi entropy. But this criterion is more complicated for calculation. With an appropriate assumption about the initial state, we present a new upper bound of equilibration time. Since the results are not constrained by the Hamiltonian of the system, this bound can be applied to various situations. If we are concerned with the local equilibration, we can limit the observation to a small region. If the whole system is big enough, the local observation would always find that the rest part is staying at the canonical ensemble, so that the local equilibration time will not increase with the size of whole system. When the local region is small enough, the upper bound of equilibration time can be much shorter. The local Rényi entropy has close relation to the propagation of information. The limitation of the speed of information propagation in a quantum lattice system can be given by the Lieb-Robinson bound, with which we evaluate the production rate of local 2-Rényi entropy. With these, we give a new lower bound of equilibration time for systems whose interactions are respectively short-range, exponentially-decaying and long-range. In earlier works, the lower bound of equilibration time is equal to the Lieb-Robinson time of the local system. In our rigorous proof, however, the lower bound is related to the strength of hopping, which also decides the Lieb-Robinson velocity. This means the equilibration time is related to the Lieb-Robinson time indeed. But the strictly equal relation may not hold. These new bounds are important to understanding the process of quantum equilibration.
A finite quantum system evolving unitarily equilibrates in a probabilistic fashion. In the general many-body setting the time fluctuations of an observable A are typically exponentially small in the system size. We consider here quasifree Fermi systems where the Hamiltonian and observables are quadratic in the Fermi operators. We first prove a bound on the temporal fluctuations ΔA(2) and then map the equilibration dynamics to a generalized classical XY model in the infinite temperature limit. Using this insight, we conjecture that, in most cases, a central limit theorem can be formulated, leading to what we call Gaussian equilibration: observables display a Gaussian distribution with relative error ΔA/A[over ¯]=O(L(-1/2)), where L is the dimension of the single-particle space. The conjecture, corroborated by numerical evidence, is proven analytically under mild assumptions for the magnetization in the quantum XY model and for a class of observables in a tight-binding model. We also show that the variance is discontinuous at the transition between a quasifree model and a nonintegrable one.
We study an ``observable-based'' notion of equilibration and its application to realistic systems like spin qubits in quantum dots. On the basis of the so-called distinguishability, we analytically derive general equilibration bounds, which we relate to the standard deviation of the fluctuations of the corresponding observable. Subsequently, we apply these ideas to the central spin model describing the spin physics in quantum dots. We probe our bounds by analyzing the spin dynamics induced by the hyperfine interaction between the electron spin and the nuclear spins using exact diagonalization. Interestingly, even small numbers of nuclear spins as found in carbon or silicon based quantum dots are sufficient to significantly equilibrate the electron spin.
Fermi's golden rule which describes the transition rates between two electronic levels under external stimulations is used ubiquitously in different fields of physics. The original Fermi's golden rule was derived from perturbative time-dependent Schrödinger's equation without the direct contribution by decoherence effect. However, as a result of recent developments of quantum computing and ultra fast carrier dynamics, the decoherence becomes a prominent topic in fundamental research.Here, by using the non-adiabatic molecular dynamics which goes beyond the time-dependent Schrödinger's equation by introducing decoherence, we study the effect of decoherence on Fermi's golden rule for the fixed basis and the adiabatic basis, respectively. We find that when the decoherence time becomes short, there is a significant deviation from the Fermi's golden rule for both bases. By using monolayer WS2 as an example, we investigate the decoherence effect in the carrier transitions induced by the electron-phonon coupling with first-principle method.