Models for quantum absorption refrigerators serve as test beds for exploring concepts and developing methods in quantum thermodynamics. Here we depart from the minimal, ideal design and consider a generic multilevel model for a quantum absorption refrigerator, which potentially suffers from lossy processes. Based on a full-counting statistics approach, we derive a formal cooling condition for the refrigerator, which can be feasibly evaluated analytically and numerically. We exemplify our approach on a three-level model for a quantum absorption refrigerator that suffers from different forms of nonideality (heat leakage, competition between different cooling pathways) and examine the cooling current with different designs. This study assists in identifying the cooling window of imperfect thermal machines.
Models for quantum absorption refrigerators serve as test beds for exploring concepts and developing methods in quantum thermodynamics. Here we depart from the minimal, ideal design and consider a generic multilevel model for a quantum absorption refrigerator, which potentially suffers from lossy processes. Based on a full-counting statistics approach, we derive a formal cooling condition for the refrigerator, which can be feasibly evaluated analytically and numerically. We exemplify our approach on a three-level model for a quantum absorption refrigerator that suffers from different forms of nonideality (heat leakage, competition between different cooling pathways) and examine the cooling current with different designs. This study assists in identifying the cooling window of imperfect thermal machines.
We study the phenomenon of absorption refrigeration, where refrigeration is achieved by heating instead of work, in two different setups: a minimal set up based on coupled qubits and two nonlinearly coupled resonators. Considering ZZ interaction between the two qubits, we outline the basic ingredients required to achieve cooling. Using local as well as global master equations, we observe that inclusion of an XX type term in the qubit-qubit coupling is detrimental to cooling. We compare the cooling effect obtained in the qubit case with that of nonlinearly coupled resonators (multilevel system) where the ZZ interaction translates to a Kerr-type nonlinearity. For small to intermediate strengths of nonlinearity, we observe that multilevel quantum systems, for example qutrits, give better cooling effect compared to the qubits. Using Keldysh nonequilibrium Green's function formalism, we go beyond first order sequential tunneling processes and study the effect of higher order processes on refrigeration. We find a reduced cooling effect compared to the master equation calculations.
The rate of temperature decrease of a cooled quantum bath is studied as its temperature is reduced to absolute zero. The third law of thermodynamics is then quantified dynamically by evaluating the characteristic exponent ζ of the cooling process dT(t)/dt∼-T^{ζ} when approaching absolute zero, T→0. A continuous model of a quantum refrigerator is employed consisting of a working medium composed either by two coupled harmonic oscillators or two coupled two-level systems. The refrigerator is a nonlinear device merging three currents from three heat baths: a cold bath to be cooled, a hot bath as an entropy sink, and a driving bath which is the source of cooling power. A heat-driven refrigerator (absorption refrigerator) is compared to a power-driven refrigerator. When optimized, both cases lead to the same exponent ζ, showing a lack of dependence on the form of the working medium and the characteristics of the drivers. The characteristic exponent is therefore determined by the properties of the cold reservoir and its interaction with the system. Two generic heat bath models are considered: a bath composed of harmonic oscillators and a bath composed of ideal Bose/Fermi gas. The restrictions on the interaction Hamiltonian imposed by the third law are discussed. In the Appendices, the theory of periodically driven open systems and its implication for thermodynamics are outlined.
Absorption refrigerators transfer thermal energy from a cold reservoir to a hot reservoir using input energy from a third, so-called work reservoir. We examine the operation of quantum absorption refrigerators when coherences between eigenstates survive in the steady state limit. In our model, the working medium comprises a discrete, four-level system. Several studies on related setups have demonstrated the performance-enhancing potential of steady-state eigenbasis quantum coherences. By contrast, in our model such coherences generally quench the cooling current in the refrigerator, while minimally affecting the coefficient of performance (cooling efficiency). We rationalize the behavior of the four-level refrigerator by studying three-level model systems for energy transport and refrigeration. Our calculations further illuminate the shortcomings of secular quantum master equations and the necessity of employing dynamical equations of motion that retain couplings between population and coherences.
We show that it is possible to construct a quantum absorption refrigerator that provides refrigeration only in the transient regime, by using three interacting qubits, each of which is also interacting with a local heat bath. Though the machine does not provide any effective cooling in the steady state, significant cooling of a qubit can be achieved much before the system reaches its steady state. We also demonstrate a scenario where the temperature of the qubit that has to be cooled, decreases monotonically to its minimum steady-state temperature. This facilitates bypassing of precise time control in cooling. We study the behaviour of the ratio of the heat currents of the machine for both the scenarios. The results remain qualitatively unchanged for different models of thermal baths. We also comment on the temporal behaviour of bipartite and multipartite quantum correlations present in the system, when transient cooling without steady-state cooling takes place.
The study of nanoscopic thermal devices attracts an increasing attention, not only because of their key role in understanding the emergence of thermodynamics from quantum theory, but also for the potential use of quantum-mechanical thermal cycles, especially refrigerators, in quantum technologies. This thesis, is devoted to the performance optimization of autonomous (heat-driven) refrigerators. For a quantum refrigerator, one has a full microscopic description of the simple system serving as a working medium, and of its interaction with the external heat baths. This enables a consistent `finite-time? thermodynamic analysis, not relying on any phenomenological assumptions about the leading sources of irreversibility, and allows to establish arguably general performance bounds, essential to benchmark the operation of realistic devices. In particular, tight and model-independent upper bounds for the coefficient of performance at maximum power, are derived here for a class of strongly coupled refrigerators, and seen to hold more generally for other types of heat and power-driven cycles. Remarkably, these ultimate limitations only depend on the particulars of the system-baths interaction at the interface with the object to be cooled. Strategies might be then defined so as to saturate those limits: It is shown how the working medium of the refrigerator may be, for instance, scaled up into a parallel multi-stage configuration, resembling that of macroscopic multi-effect absorption chillers, as a means to increase its cooling power. Similarly, by applying reservoir engineering techniques on selected transitions between the energy states of the working medium, one can mimic exploitable non-equilibrium fluctuations in the baths, capable of boosting the overall power and COP beyond what would be otherwise allowed by the second law of thermodynamics. In this way, heat-driven chillers could be set to compete on a equal footing with the best power-driven refrigerators.
The thermodynamic uncertainty relation, originally derived for classical Markov-jump processes, provides a tradeoff relation between precision and dissipation, deepening our understanding of the performance of quantum thermal machines. Here, we examine the interplay of quantum system coherences and heat current fluctuations on the validity of the thermodynamics uncertainty relation in the quantum regime. To achieve the current statistics, we perform a full counting statistics simulation of the Redfield quantum master equation. We focus on steady-state quantum absorption refrigerators where nonzero coherence between eigenstates can either suppress or enhance the cooling power, compared with the incoherent limit. In either scenario, we find enhanced relative noise of the cooling power (standard deviation of the power over the mean) in the presence of system coherence, thereby corroborating the thermodynamic uncertainty relation. Our results indicate that fluctuations necessitate consideration when assessing the performance of quantum coherent thermal machines.