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arXiv:1909.03855 · Physical Review Research

Condensation versus ordering: From the spherical models to Bose-Einstein condensation in the canonical and grand canonical ensemble

A. Crisanti, Alessandro Sarracino, Marco Zannetti

Published Sep 20, 2019• 16 citations
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Abstract

This paper shows that Bose-Einstein condensates in canonical and grand-canonical conditions stands for different phenomena: the familiar ordering transition in the former opposed to condensation of fluctuations without any ordering in the latter. The authors connect this to recent experiments that show Bose-Einstein condensates in a gas of photons.

DOI
10.1103/physrevresearch.1.023022

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This paper shows that Bose-Einstein condensates in canonical and grand-canonical conditions stands for different phenomena: the familiar ordering transition in the former opposed to condensation of fluctuations without any ordering in the latter. The authors connect this to recent experiments that show Bose-Einstein condensates in a gas of photons.
Grand-canonical fluctuations of Bose-Einstein condensates of light are accessible to state-of-the-art experiments [J. Schmitt et al., Phys. Rev. Lett. 112, 030401 (2014).PRLTAO0031-900710.1103/PhysRevLett.112.030401]. We phenomenologically describe these fluctuations by using the grand-canonical ensemble for a weakly interacting Bose gas at thermal equilibrium. For a two-dimensional harmonic trap, we use two models for which the canonical partition functions of the weakly interacting Bose gas are given by exact recurrence relations. We find that the grand-canonical condensate fluctuations for weakly interacting Bose gases vanish at zero temperature, thus behaving qualitatively similarly to an ideal gas in the canonical ensemble (or microcanonical ensemble) rather than the grand-canonical ensemble. For low but finite temperatures, the fluctuations remain considerably higher than for the canonical ensemble, as predicted by the ideal gas in the grand-canonical ensemble, thus clearly showing that we are not in a regime in which the ensembles are equivalent.
Abstract Particle fluctuations in systems, exhibiting Bose–Einstein condensation, are reviewed in order to clarify the basic points that attract high interest and often confront misunderstanding. It is explained that the so-called ‘grand canonical catastrophe’, claiming the occurrence of catastrophic particle fluctuations in the condensed phase, treated by grand canonical ensemble, does not exist. What exists is the incorrect use of the grand canonical ensemble, where gauge symmetry is not broken, while the correct description of the condensed phase necessarily requires gauge symmetry breaking. The ideal Bose gas has no catastrophic condensate fluctuations, and moreover there are no condensate fluctuations at all, as soon as gauge symmetry is broken. However it does have anomalous fluctuations of uncondensed particles, which implies its instability. For interacting particles, there are no condensate fluctuations, as soon as gauge symmetry is broken, and anomalous fluctuations of uncondensed particles, when correctly calculated, do not appear. Particle fluctuations in the systems of trapped atoms are discussed. Canonical ensemble and grand canonical ensemble with broken gauge symmetry are equivalent with respect to the number of particle scaling.
The realisation of Bose-Einstein condensation under grand-canonical conditions has provided the experimental evidence for the simultaneous occurrence of macroscopic fluctuations and phase coherence of the condensate. The observation of these two features, against a consolidated tradition which wants the fluctuations to be pathological (grand-canonical catastrophe) and incompatible with spontaneous symmetry braking, calls for a comprehensive rethinking of the approach to the problem. In this paper we consider the uniform ideal gas in a box and we present an alternative conceptual framework. We show that the usually-employed Bogoliubov quasi-average construction fails to reproduce the broken-symmetry state. The observed features are accounted for by a different pattern of spontaneous symmetry breaking, characterised by condensation of fluctuations and long-range correlations of the order parameter.
The analytical theory of Bose–Einstein condensation of an ideal gas in mesoscopic systems has been briefly reviewed in application to traps with arbitrary shapes and dimension. This theory describes the phases of the classical gas and the formed Bose–Einstein condensate, as well as the entire vicinity of the phase transition point. The statistics and thermodynamics of Bose–Einstein condensation have been studied in detail, including their self-similar structure in the critical region, transition to the thermodynamic limit, effect of boundary conditions on the properties of a system, and nonequivalence of the description of Bose–Einstein condensation in different statistical ensembles. The complete classification of universality classes of Bose–Einstein condensation has been given.
We calculate certain features of Bose–Einstein condensation in the ideal gas by using recurrence relations for the partition function. The grand canonical ensemble gives inaccurate results for certain properties of the condensate that are accurately provided by the canonical ensemble. Calculations in the latter can be made tractable for finite systems by means of the recurrence relations. The ideal one-dimensional harmonic Bose gas provides a particularly simple and pedagogically useful model for which detailed results are easily derived. An analysis of the Bose system via permutation cycles yields insight into the physical meaning of the recurrence relations.