We introduce the idea of weakly coherent collisional models, where the elements of an environment interacting with a system of interest are prepared in states that are approximately thermal but have an amount of coherence proportional to a short system-environment interaction time in a scenario akin to well-known collisional models. We show that, in the continuous-time limit, the model allows for a clear formulation of the first and second laws of thermodynamics, which are modified to include a nontrivial contribution related to quantum coherence. Remarkably, we derive a bound showing that the degree of such coherence in the state of the elements of the environment represents a resource, which can be consumed to convert heat into an ordered (unitarylike) energy term in the system, even though no work is performed in the global dynamics. Our results therefore represent an instance where thermodynamics can be extended beyond thermal systems, opening the way for combining classical and quantum resources.
We introduce the idea of weakly coherent collisional models, where the elements of an environment interacting with a system of interest are prepared in states that are approximately thermal but have an amount of coherence proportional to a short system-environment interaction time in a scenario akin to well-known collisional models. We show that, in the continuous-time limit, the model allows for a clear formulation of the first and second laws of thermodynamics, which are modified to include a nontrivial contribution related to quantum coherence. Remarkably, we derive a bound showing that the degree of such coherence in the state of the elements of the environment represents a resource, which can be consumed to convert heat into an ordered (unitarylike) energy term in the system, even though no work is performed in the global dynamics. Our results therefore represent an instance where thermodynamics can be extended beyond thermal systems, opening the way for combining classical and quantum resources.
Abstract Quantum collision models normally consist of a system interacting with a set of ancillary units representing the environment. While these ancillary systems are usually assumed to be either two level systems or harmonic oscillators, in this work we move further and represent each ancillary system as a structured system, i.e. a system made out of two or more subsystems. We show how this scenario modifies the kind of master equation that one can obtain for the evolution of the open systems. Moreover, we are able to consider a situation where the ancilla state is thermal yet has some coherence. This allows the generation of coherence in the steady state of the open system and, thanks to the simplicity of the collision model, this allows us to better understand the thermodynamic cost of creating coherence in a system. Specifically, we show that letting the system interact with the coherent degrees of freedom requires a work cost, leading to the natural fulfillment of the first and second law of thermodynamics without the necessity of ad hoc formulations.
A central open question in quantum thermodynamics is the identification of thermodynamic entropy away from equilibrium. Although thermodynamic entropy coincides with the von Neumann entropy for a Gibbs state at equilibrium, the thermodynamic role of quantum coherence generated during nonequilibrium evolution remains unclear. Here, we show that von Neumann entropy does not, in general, represent the thermodynamic entropy governing heat exchange in coherent nonequilibrium quantum systems. By integrating the resource theory of quantum coherence with thermodynamic principles, we develop a general framework for nonequilibrium quantum thermodynamics. We identify thermodynamic entropy with the energy entropy derived from energy-measurement statistics and introduce a dynamical temperature extending the equilibrium concept to nonequilibrium states. Consequently, we obtain an exact entropy-balance relation separating the entropy flux associated with heat exchange from the coherence-loss contribution to entropy production, establishing an operational connection between quantum coherence, heat flow, and total entropy change. Unlike approaches relying on equilibrium reference states or stationary Gibbs ensembles, our framework uses instantaneous dynamical quantities and remains valid throughout transient nonequilibrium evolution. It provides consistent dynamical definitions of temperature, work, heat, and free energy. Applying the formalism to an exactly solvable open quantum system, we show that the first and second laws hold throughout transient evolution and that equilibrium thermodynamics emerges dynamically in the weak-coupling long-time limit. Our results establish a unified framework for coherent nonequilibrium quantum thermodynamics and suggest opportunities for controlling heat dissipation through coherence engineering in quantum thermal technologies.
In quantum thermodynamics, the decomposition of energy exchanges into heat and work remains an open problem beyond weak-coupling and slow-driving regimes. Recent formulations have shown that quantum coherence introduces additional energy contributions whose thermodynamic interpretation is still under debate, raising fundamental questions about the structure of the quantum first law. In this work, we investigate this problem through a time-dependent perturbative framework applied to the first law of quantum thermodynamics. By expanding the thermodynamic quantities up to second order, we derive explicit perturbative corrections for work, heat, and coherence contributions. Our results show that the coherence term can be consistently decomposed into coherent heat and coherent work, demonstrating that quantum coherence does not require the introduction of an independent energetic contribution beyond heat and work. The formalism resolves inconsistencies associated with previous formulations of the quantum first law, including the interpretation of coherence contributions and their connection with entropy fluxes. At second order, the perturbative corrections become directly connected to transition rates governed by Fermi's golden rule, establishing a bridge between microscopic quantum transitions and macroscopic thermodynamic quantities. These results provide a physically transparent framework to investigate coherence-driven thermodynamic processes and offer new perspectives for the analysis of driven quantum systems and nonequilibrium quantum technologies.
Planck found, when attempting to describe the way in which hot bodies glow, that energy at microscopic scales often comes in discrete chunks. Thus began the long and intimate relationship between the field of thermodynamics, which explores our ability to manipulate heat and other energy transfers between macroscopic systems, and quantum mechanics, which explains the dynamics of individual microscopic systems. Even as both our technology and our theoretical investigations have extended to ever-smaller devices, our understanding of quantum effects on thermodynamics has remained almost exclusively limited to the quantized nature of energy. There is much more, however, to quantum theory than energy quantization. In this thesis we focus on the property of quantum coherence, the ability of quantum systems to emulate Schrodinger’s cat and somehow be neither dead nor alive, but something completely different altogether. We provide a simple and elegant formulation for the processing of coherence in thermodynamics, relying on the fact that thermodynamical processes possess an underlying time-translation symmetry. This fact allows us to quantify the ways in which coherence can play an active role, facilitating otherwise impossible thermodynamic transformations. We argue that coherence should be thought of as a distinctly quantum-mechanical thermodynamic resource. By considering an isolated quantum system connected, for some period of time, to a thermal bath, we give fundamental limitations on how coherence can be irreversibly manipulated. These limitations are related to those dictated on energy transfer by the second law of thermodynamics. Others topics that are investigated here is what is the role of correlations at the smallest scales and the conversion of quantum coherence into work. It has long been appreciated that thermodynamics is subtly interlinked with the notion of information. This work provides evidence that, to apply the laws of thermodynamics to the smallest systems around us, we must develop deeper insights into the nature of quantum information.
Quantum thermodynamics is a blossoming research program that uses tools and ideas from quantum information theory to extend the laws of thermodynamics to the domain of systems to which the laws of quantum mechanics apply and the thermodynamic limit does not necessarily apply. The contributions of this program are both foundational, in providing an approach to constructively derive the laws of phenomenological thermodynamics from the postulates of unitary quantum mechanics in a rigorous and bottom-up fashion, but also prac- tical, in providing the theory for an increasing number of experiments that attempt to build thermodynamic machines at scales that were previously inaccessible. One key mathematical tool used in quantum thermodynamics is the framework of resource theories, specifically the resource theory of thermal operations, in which the thermodynamic interaction of a system with a heat bath and various additional components such as work batteries, clocks or catalysts are modeled. In this cumulative thesis, various extensions and modifications of this framework are studied in order to derive novel results and insights about the possible thermodynamic evolution of quantum systems. In particular, following a system- atic exposition of the resource theory of thermal operations from first principles, I develop answers to the following questions: i) What is the smallest heat bath required to provide the necessary randomness for a system to undergo a given stochastic or thermodynamical evolution? ii) Does this size differ depending on whether the interaction between bath and system is quantum or classical? iii) How can quantum systems thermodynamically evolve in the presence of catalytic bystander systems and how can this be put to use? iv) What are the thermodynamic state transitions that an agent can operationally affect when she only has access to partial information about the underlying states of system and bath? v) How can we understand the emergence of the canonical ensemble in statistical thermodynamics from quantum mechanics? These questions cover a wide ground, but it will become clear that they can in fact all be discussed using the same formal tools. As such, the answers to the above questions provided in this thesis are both interesting in their own right — showing for example that there exists a gap in how efficiently randomness can be exploited quantumly as compared to classically or that catalytic bystander systems can be used to extract finite amounts of work per particle from macroscopic systems with non-vanishing probability — as well as illustrate the power of quantum thermodynamics as a set of tools to connect quantum mechanics and the theory of thermodynamics more generally.
Abstract Quantum collision models allow for the dynamics of open quantum systems to be described by breaking the environment into small segments, typically consisting of non-interacting harmonic oscillators or two-level systems. This work introduces structure within these environmental units via spring-like interactions between N coupled oscillators in a ring structure, initially prepared in a thermal state. Two models of interest are examined. The first highlights a case in which a continuous time evolution can be obtained, wherein the system interacts with the environment via a beam-splitter-like, energy-preserving, interaction. The resulting dynamics are analogous to those due to interactions with unstructured units prepared as squeezed thermal states. The second model highlights a case in which the continuous time limit for the evolution cannot be taken generally, requiring instead discrete-time propagation. Special cases in which the continuous time limit can be taken are also investigated, alongside the addition of a secondary environment to induce a steady state. The first and second laws of thermodynamics are verified for both examples.