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arXiv:1906.02302 · European Journal of Physics

Proving the existence of bound states for attractive potentials in one-dimension and two-dimensions without calculus

J. Alexander Jacoby, Maurice Curran, David R. Wolf, James K. Freericks

Published May 16, 2019• 5 citations
arXivHTMLPDF

Abstract

Abstract Schrödinger developed an operator method for solving quantum mechanics. While this technique is overshadowed by his more familiar differential equation approach, it has found wide application as an illustration of supersymmetric quantum mechanics. One reason for reticence in its usage for conventional quantum instruction is that the approach for simple problems like the particle-in-a-box is much more complicated than the differential equation approach, making it appear to be less useful for pedagogy. We argue that the approach is still quite attractive because it employs only algebraic methods, and thereby has a much lower level of math background needed to use it. We show how Schrödinger’s operator method can be streamlined for these particle-in-a-box problems greatly reducing the complexity of the solution and making it much more accessible. As an application, we illustrate how this approach can be used to prove an important result, the existence of bound states for one- and two-dimensional attractive potentials, using only algebraic methods. The approach developed here can be employed in undergraduate classes and possibly even high school classes because it employs only algebra and requires essentially no calculus.

DOI
10.1088/1361-6404/ab21ed

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Abstract Schrödinger developed an operator method for solving quantum mechanics. While this technique is overshadowed by his more familiar differential equation approach, it has found wide application as an illustration of supersymmetric quantum mechanics. One reason for reticence in its usage for conventional quantum instruction is that the approach for simple problems like the particle-in-a-box is much more complicated than the differential equation approach, making it appear to be less useful for pedagogy. We argue that the approach is still quite attractive because it employs only algebraic methods, and thereby has a much lower level of math background needed to use it. We show how Schrödinger’s operator method can be streamlined for these particle-in-a-box problems greatly reducing the complexity of the solution and making it much more accessible. As an application, we illustrate how this approach can be used to prove an important result, the existence of bound states for one- and two-dimensional attractive potentials, using only algebraic methods. The approach developed here can be employed in undergraduate classes and possibly even high school classes because it employs only algebra and requires essentially no calculus.
An important technique for teaching introductory wave mechanics is provided by the numerical calculation of stationary state solutions of the Schrödinger equation. Realistic problems in wave mechanics that do not require sophisticated computer techniques are very valuable for the instruction of undergraduates. In the central-field model for atoms, the calculation of electron states reduces to the solution of a one-dimensional differential equation whose numerical solutions are no more difficult to obtain than those for a finite square well. A method used by our students is discussed in this paper for the calculation of the electron wavefunctions in a central-field potential. By working this problem, students obtain meaningful results that give them insight into the theory of atomic structure. Results of their experience are included, and possibilities of extending this example are discussed.
In this chapter, we introduce the particle in a box. This problem has become a standard in most quantum texts, even though it does not accurately represent too many real physical systems. Instead, it is used to illustrate quantum principles because it is viewed as one of the simplest quantum systems to discuss. Within our approach, however, this problem is a bit more challenging to solve. Nevertheless, it does provide a number of interesting insights, and it also allows us to prove an important result about the existence of bound states in one, two, and three dimensions. Our work here also allows us to answer the question why are some eigenvalues in quantum mechanics quantized, while others are not.
Quantum Science and Technology (QST) has rapidly emerged as a transformative domain, driving advances in computing, sensing, and communication. The global expansion of quantum research and education programs reflects the recognition of quantum technologies as central to twenty-first-century scientific and technological progress. Sustaining this trajectory requires cultivating a workforce with strong conceptual and technical foundations in quantum science. Yet, significant pedagogical challenges persist, particularly in designing curricula that balance theoretical rigor with accessibility for students with basic understanding of ordinary differential equations. This study seeks to address a critical gap in undergraduate quantum mechanics instruction by introducing a tractable framework for solving the Schrödinger equation with noncentral potentials. Such potentials—including ring-shaped interactions—are indispensable for modelling molecular structures, anisotropic systems, and ultracold collision phenomena. Despite their importance, their mathematical complexity has historically hindered integration into standard coursework, leaving students underprepared for contemporary quantum applications. We develop a differential-equation-based approach that explicitly solves the orbital component of the Schrödinger equation under a noncentral potential. The resulting normalized wavefunctions are expressed in terms of Jacobi polynomials. The framework is designed to be mathematically rigorous yet pedagogically accessible, enabling undergraduate students to engage with noncentral potentials without requiring advanced mathematical tools beyond the standard curriculum. The solutions obtained demonstrate clear dependence on both potential parameters and quantum numbers, while maintaining consistency with established results in the literature. This validates the framework’s accuracy and suitability for instructional use. By simplifying the mathematical treatment without sacrificing rigor, the approach provides students with meaningful exposure to complex quantum systems. This work offers a pathway for incorporating noncentral potentials into undergraduate quantum mechanics instruction. By broadening the conceptual toolkit available to students, it supports the development of a versatile quantum-ready workforce and advances the integration of contemporary quantum applications into mainstream education.
The factorization method of Schrödinger shows us how to determine the energy eigenstates without needing to determine the wavefunctions in position or momentum space. A strategy to convert the energy eigenstates to wavefunctions is well known for the one-dimensional simple harmonic oscillator by employing the Rodrigues formula for the Hermite polynomials in position or momentum space. In this work, we illustrate how to generalize this approach in a representation-independent fashion to find the wavefunctions of other problems in quantum mechanics that can be solved by the factorization method. We examine three problems in detail: (i) the one-dimensional simple harmonic oscillator; (ii) the three-dimensional isotropic harmonic oscillator; and (iii) the three-dimensional Coulomb problem. This approach can be used in either undergraduate or graduate classes in quantum mechanics.
Incorporating relativity into quantum mechanics presents challenges, one of which is the inconsistent possibility of multiple particles within a single-particle theory. This chapter describes the traditional, semi-analytic bound state in a 1-D box problem that requires a trial-and-error search algorithm. It examines techniques for finding the bound states for an arbitrary potential as a numerical eigenvalue problem and employs similar techniques for the relativistic hydrogen states of the Klein-Gordon equation. The chapter also employs a Monte Carlo algorithm to simulate the spontaneous decay of atoms or nuclei. It presents the numerical solution of the time-independent Schrodinger equation and also examines partial wave expansions, which leads to methods of computing the spherical harmonics and the associated Legendre functions, and ultimately the 3-D hydrogenic wave functions. The chapter deals with the Feynman path integral formulation of quantum mechanics, and its solution via the Metropolis algorithm.