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arXiv:1903.06128 · Physical Review A

Microscopic modeling of general time-dependent quantum Markov processes

Giulio Amato, Heinz‐Peter Breuer, Bassano Vacchini

Published Mar 28, 2019• 9 citations
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Abstract

Master equations are typically adopted to describe the dynamics of open quantum systems. Such equations are either in integro-differential or in time-local form, with the latter class more frequently adopted due to the simpler numerical methods developed to obtain the corresponding solution. Here we show that any time-local master equation with positive rates in the generator, i.e., any completely positive divisible quantum process, admits a microscopic model whose reduced dynamics is well described by the given equation.

DOI
10.1103/physreva.99.030102

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Master equations are typically adopted to describe the dynamics of open quantum systems. Such equations are either in integro-differential or in time-local form, with the latter class more frequently adopted due to the simpler numerical methods developed to obtain the corresponding solution. Here we show that any time-local master equation with positive rates in the generator, i.e., any completely positive divisible quantum process, admits a microscopic model whose reduced dynamics is well described by the given equation.
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Positivity preservation is naturally guaranteed in exact non-Markovian master equations for open quantum system dynamics. However, in many approximated non-Markovian master equations, the positivity of the reduced density matrix is not guaranteed. In this paper we provide a general class of time-local, perturbative, and positivity-preserving non-Markovian master equations generated from stochastic Schr\"odinger equations, particularly quantum-state-diffusion equations. Our method has an expanded range of applicability for accommodating a variety of non-Markovian environments. We show the positivity-preserving master equation for a three-level system coupled to a dissipative bosonic environment as a particular example to exemplify our general approach. We illustrate the numerical simulations with an analysis explaining why the previous approximated non-Markovian master equations cannot guarantee positivity. Our work provides a consistent master equation for studying the non-Markovian dynamics in ultrafast quantum processes and strong-coupling systems.
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Semi-Markov processes represent a well-known and widely used class of random processes in classical probability theory. Here, we develop an extension of this type of non-Markovian dynamics to the quantum regime. This extension is demonstrated to yield quantum master equations with memory kernels which allow the formulation of explicit conditions for the complete positivity of the corresponding quantum dynamical maps, thus leading to important insights into the structural characterization of the non-Markovian quantum dynamics of open systems. Explicit examples are analyzed in detail.
Convolutionless and convolution master equations are the two mostly used physical descriptions of open quantum systems dynamics. We subject these equations to time deformations: local dilations and contractions of time scale. We prove that the convolutionless equation remains legitimate under any time deformation (results in a completely positive dynamical map) if and only if the original dynamics is completely positive divisible. Similarly, for a specific class of convolution master equations we show that uniform time dilations preserve positivity of the deformed map if the original map is positive divisible. These results allow witnessing different types of non-Markovian behavior: the absence of complete positivity for a deformed convolutionless master equation clearly indicates that the original dynamics is at least weakly non-Markovian; the absence of positivity for a class of time-dilated convolution master equations is a witness of essentially non-Markovian original dynamics.