Cooling quantum systems is arguably one of the most important thermodynamic tasks connected to modern quantum technologies and an interesting question from a foundational perspective. It is thus of no surprise that many different theoretical cooling schemes have been proposed, differing in the assumed control paradigm and complexity, and operating either in a single cycle or in steady state limits. Working out bounds on quantum cooling has since been a highly context dependent task with multiple answers, with no general result that holds independent of assumptions. In this Letter we derive a universal bound for cooling quantum systems in the limit of infinite cycles (or steady state regimes) that is valid for any control paradigm and machine size. The bound only depends on a single parameter of the refrigerator and is theoretically attainable in all control paradigms. For qubit targets we prove that this bound is achievable in a single cycle and by autonomous machines.
Cooling quantum systems is arguably one of the most important thermodynamic tasks connected to modern quantum technologies and an interesting question from a foundational perspective. It is thus of no surprise that many different theoretical cooling schemes have been proposed, differing in the assumed control paradigm and complexity, and operating either in a single cycle or in steady state limits. Working out bounds on quantum cooling has since been a highly context dependent task with multiple answers, with no general result that holds independent of assumptions. In this Letter we derive a universal bound for cooling quantum systems in the limit of infinite cycles (or steady state regimes) that is valid for any control paradigm and machine size. The bound only depends on a single parameter of the refrigerator and is theoretically attainable in all control paradigms. For qubit targets we prove that this bound is achievable in a single cycle and by autonomous machines.
In classical thermodynamics the work cost of control can typically be neglected. On the contrary, in quantum thermodynamics the cost of control constitutes a fundamental contribution to the total work cost. Here, focusing on quantum refrigeration, we investigate how the level of control determines the fundamental limits to cooling and how much work is expended in the corresponding process. We compare two extremal levels of control: first, coherent operations, where the entropy of the resource is left unchanged, and, second, incoherent operations, where only energy at maximum entropy (i.e., heat) is extracted from the resource. For minimal machines, we find that the lowest achievable temperature and associated work cost depend strongly on the type of control, in both single-cycle and asymptotic regimes. We also extend our analysis to general machines. Our work provides a unified picture of the different approaches to quantum refrigeration developed in the literature, including algorithmic cooling, autonomous quantum refrigerators, and the resource theory of quantum thermodynamics.
In classical thermodynamics the work cost of control can typically be neglected. On the contrary, in quantum thermodynamics the cost of control constitutes a fundamental contribution to the total work cost. Evaluating this contribution is an important but non-trivial problem. Here, focusing on quantum refrigeration, we show how the level of control determines the fundamental limits to cooling. We compare coherent versus incoherent operations, and derive the minimal achievable temperature and associated work cost. We discuss both the single-shot and asymptotic regimes. Our work provides a unified picture of the different approaches to quantum refrigeration developed in the literature, including algorithmic cooling, autonomous quantum refrigerators, and the resource theory of quantum thermodynamics.
The study of nanoscopic thermal devices attracts an increasing attention, not only because of their key role in understanding the emergence of thermodynamics from quantum theory, but also for the potential use of quantum-mechanical thermal cycles, especially refrigerators, in quantum technologies. This thesis, is devoted to the performance optimization of autonomous (heat-driven) refrigerators. For a quantum refrigerator, one has a full microscopic description of the simple system serving as a working medium, and of its interaction with the external heat baths. This enables a consistent `finite-time? thermodynamic analysis, not relying on any phenomenological assumptions about the leading sources of irreversibility, and allows to establish arguably general performance bounds, essential to benchmark the operation of realistic devices. In particular, tight and model-independent upper bounds for the coefficient of performance at maximum power, are derived here for a class of strongly coupled refrigerators, and seen to hold more generally for other types of heat and power-driven cycles. Remarkably, these ultimate limitations only depend on the particulars of the system-baths interaction at the interface with the object to be cooled. Strategies might be then defined so as to saturate those limits: It is shown how the working medium of the refrigerator may be, for instance, scaled up into a parallel multi-stage configuration, resembling that of macroscopic multi-effect absorption chillers, as a means to increase its cooling power. Similarly, by applying reservoir engineering techniques on selected transitions between the energy states of the working medium, one can mimic exploitable non-equilibrium fluctuations in the baths, capable of boosting the overall power and COP beyond what would be otherwise allowed by the second law of thermodynamics. In this way, heat-driven chillers could be set to compete on a equal footing with the best power-driven refrigerators.
In the task of unitarily cooling a quantum system with access to a larger quantum system, known as the machine or reservoir, ? Focusing on the task of cooling a single qubit given access to n separable, thermal qubits with arbitrary energy structure, we answer these questions by giving two new perspectives on this task. First, we show that a set of inequalities related to the energetic structure of the n -qubit machine determines the protocol which cools the qubit to the coldest reachable state, which parts of the machine contribute to this protocol and give rise to a Carnot-like bound. Second, we show that cooling protocols can be represented as perfect matchings on bipartite graphs enabling the optimization of cost functions, e.g., gate complexity or dissipation. Our results generalize the algorithmic cooling problem, establish new fundamental bounds on quantum cooling and offer a framework for designing novel autonomous thermal machines and cooling algorithms.
Thermodynamics is a branch of science blessed by an unparalleled combination of generality of scope and formal simplicity. Based on few natural assumptions together with the four laws, it sets the boundaries between possible and impossible in macroscopic aggregates of matter. This triggered groundbreaking achievements in physics, chemistry and engineering over the last two centuries. Close analogues of those fundamental laws are now being established at the level of individual quantum systems, thus placing limits on the operation of quantum-mechanical devices. Here we study quantum absorption refrigerators, which are driven by heat rather than external work. We establish thermodynamic performance bounds for these machines and investigate their quantum origin. We also show how those bounds may be pushed beyond what is classically achievable, by suitably tailoring the environmental fluctuations via quantum reservoir engineering techniques. Such superefficient quantum-enhanced cooling realises a promising step towards the technological exploitation of autonomous quantum refrigerators.
We show that it is possible to construct a quantum absorption refrigerator that provides refrigeration only in the transient regime, by using three interacting qubits, each of which is also interacting with a local heat bath. Though the machine does not provide any effective cooling in the steady state, significant cooling of a qubit can be achieved much before the system reaches its steady state. We also demonstrate a scenario where the temperature of the qubit that has to be cooled, decreases monotonically to its minimum steady-state temperature. This facilitates bypassing of precise time control in cooling. We study the behaviour of the ratio of the heat currents of the machine for both the scenarios. The results remain qualitatively unchanged for different models of thermal baths. We also comment on the temporal behaviour of bipartite and multipartite quantum correlations present in the system, when transient cooling without steady-state cooling takes place.