The Pauli exclusion principle (PEP) can be considered from two aspects. First, it asserts that particles that have half-integer spin (fermions) are described by antisymmetric wave functions, and particles that have integer spin (bosons) are described by symmetric wave functions. It is called spin-statistics connection (SSC). The physical reasons why SSC exists are still unknown. On the other hand, PEP is not reduced to SSC and can be consider from another aspect, according to it, the permutation symmetry of the total wave function can be only of two types: symmetric or antisymmetric. They both belong to one-dimensional representations of the permutation group, while other types of permutation symmetry are forbidden. However, the solution of the Schrödinger equation may have any permutation symmetry. We analyze this second aspect of PEP and demonstrate that proofs of PEP in some wide-spread textbooks on quantum mechanics, basing on the indistinguishability principle, are incorrect. The indistinguishability principle is insensitive to the permutation symmetry of wave function. So, it cannot be used as a criterion for the PEP verification. However, as follows from our analysis of possible scenarios, the permission of states with permutation symmetry more general than symmetric and antisymmetric leads to contradictions with the concepts of particle identity and their independence. Thus, the existence in our Nature particles only in symmetric and antisymmetric permutation states is not accidental, since all symmetry options for the total wave function, except the antisymmetric and symmetric, cannot be realized. From this an important conclusion follows, we may not expect that in future some unknown elementary particles that are not fermions or bosons can be discovered.
The Pauli Exclusion Principle and the Spin-Statistics Theorem from Worldline Non-Injectivity: Exchange Phase, Rapidity, and Topological Sheet Structure For nearly a century, the Pauli exclusion principle (PEP) and the spin-statistics theorem have stood as foundational postulates of quantum mechanics and relativistic quantum field theory. The PEP dictates that no two identical fermions can occupy the same quantum state, determining the structure of atoms, the stability of matter, and the properties of neutron stars and white dwarfs. The spin-statistics theorem connects the intrinsic spin of a particle to its statistical behavior: half-integer spin particles (fermions) obey Fermi-Dirac statistics, while integer spin particles (bosons) obey Bose-Einstein statistics. Despite their universal success, these principles have never been derived from a more primitive geometric or topological principle — until now. This paper demonstrates that both the Pauli exclusion principle and the spin-statistics theorem emerge naturally and rigorously from a single geometric fact: the **non-injectivity of a timelike worldline** for Lorentz factors exceeding a critical threshold,
γ>γcrit. In this regime, a single worldline intersects a constant-time hypersurface
Σt in
N>1 distinct spatial points, generating a multi‑sheet spacetime structure. This phenomenon, known as **worldline non-injectivity**, is the foundation of the TPST–DGQ framework. **Key results and logical flow:** 1. **Multi‑sheet structure for a single particle:** For
γ>γcrit, a particle's worldline produces
N(ϵ)∼ϵ−(d−2) topological sheets, each carrying the same physical properties (mass, charge, spin) via the Ontological Identity Principle. 2. **Composite worldline for two identical particles:** By combining two identical particles into a composite worldline in configuration space, we obtain a two‑particle sheet structure. Identical particles share isomorphic sheet structures, reducing the
N×N sheet pairs to
N independent pairs. 3. **Exchange as a permutation of sheet blocks:** The exchange operator
P12 swaps the sheet blocks associated with the two particles. This permutation is a topological operation in the two‑particle configuration space. 4. **Exchange phase from winding number:** The exchange path corresponds to half of a complete winding cycle around the fold structure of the composite worldline. The accumulated topological phase is
Φexchange=πw, where
w is the **winding number** of the worldline. Hence the exchange phase factor is
η=eiπw=(−1)w. 5. **Spin from winding number:** The winding number
w is directly related to the spin
s by the requirement that a
4π rotation returns the physical state to itself (single‑valuedness). This yields
w=2s. Therefore
η=(−1)2s: half‑integer spin gives
η=−1 (fermions, antisymmetric), integer spin gives
η=+1 (bosons, symmetric). This is the spin‑statistics theorem derived from geometry. 6. **Pauli exclusion principle:** For two identical fermions (
η=−1) at spatial coincidence, the two‑particle amplitude satisfies
A=ηA, forcing
A=0. Thus no two fermions can occupy the same quantum state. The PEP is no longer a postulate; it is a theorem. 7. **Rapidity as inter‑sheet phase measure:** The rapidity
ζ=artanh(v/c) is shown to be a monotonic function of the inter‑sheet phase difference
Φn. The non‑injectivity threshold
γ>γcrit corresponds to
ζ>ζcrit. The speed of light
c emerges as the asymptotic limit where the inter‑sheet phase diverges, making
v=c unreachable for massive particles. 8. **Universal cancellation identity:** The same algebraic identity
N(ϵ)⋅ϵd−2=O(1) that regularizes holographic entropy, Coulomb self‑energy, wavefunction normalization, electromagnetic fields, and the cosmological constant also regularizes the two‑particle exchange amplitude — zero for fermions, finite for bosons. Quantum statistics thus joins the list of phenomena unified under the principle of worldline non‑injectivity. **Implications:** This work completes the derivation of the foundations of quantum mechanics within the TPST–DGQ framework, following previous derivations of the Born rule, the Schrödinger equation, Planck’s constant, and wavefunction collapse. It also establishes a geometric origin for the spin‑statistics connection, a result that in standard physics relies on the heavy machinery of relativistic quantum field theory (unitarity, causality, positivity of energy). Here, it follows from the topology of worldline folds. This manuscript is current in Official Peer Review. Not final version.Copyright©2026 Alex De Giuseppe.All rights reserved. This work is protected by copyright. Any form of plagiarism, unauthorized reproduction, or misappropriation of ideas, mathematically results, or text without proper citation constitutes a violation of academic and intellectual property standards and common laws. No commercial use, adaptation, or derivative works are permitted without explicit written permission from the author. For correspondence, citations, collaboration inquiries, or feedback please contact:degiuseppealex@gmail.com The hash files that determine ownership have been created.
This is the first scientific book devoted to the Pauli Exclusion Principle, which is a fundamental principle of quantum mechanics and is permanently applied in chemistry, physics, molecular biology and in physical astronomy. However, while the principle has been studied for more than 90 years, rigorous theoretical foundations still have not been established and many unsolved problems remain. Following an introduction and historical survey, this book discusses the still unresolved questions around this fundamental principle. For instance, why, according to the Pauli Exclusion Principle, are only symmetric and antisymmetric permutation symmetries for identical particles realized, while the Schrödinger equation is satisfied by functions with any permutation symmetry? Chapter 3 covers possible answers to this, while chapter 4 presents effective and elegant methods for finding the Pauli-allowed states in atomic, molecular and nuclear spectroscopy. Chapter 5 discusses parastatistics and fractional statistics, demonstrating that the quasiparticles in a periodical lattice, including excitons and magnons, are obeying modified parafermi statistics. With detailed appendices, The Pauli Exclusion Principle: Origin, Verifications and Applications is intended as a self-sufficient guide for graduate students and academic researchers in the fields of quantum mechanics, theoretical chemistry, physics, and applied mathematics. It will be a valuable resource for any reader interested in the foundations of quantum mechanics and its applications in areas such as atomic and molecular spectroscopy, spintronics, molecular biology, and applied fields of quantum information.
Why is it that particles with half-integer spin are Fermi particles whereas particles with integer spin are Bose particles? An explanation has been worked out by Pauli from complicated arguments from quantum field theory and relativity. He has shown that the two must necessarily go together … but we have not been able to reproduce his arguments on an elementary level. This probably means we do not have a complete understanding of the fundamental principle involved… R. P. Feynman, R.B. Leighton and M. Sands, Feynman Lectures on Physics , Volume 3, Chapter 4, Section 1, Addison-Wesley, Reading, MA (1963) Introduction Particles with half-integer angular momentum obey the Pauli exclusion principle (PEP) – a restriction that a non-degenerate single-particle quantum state can have occupation number of only 0 or 1. This restriction was announced by W. Pauli in 1924 for which, in 1945, he received the Nobel Prize in Physics. Soon after Pauli, the exclusion principle was generalized by P. Dirac and E. Fermi who – independently – integrated it into quantum mechanics. As a consequence half-integer spin particles are called Fermi–Dirac particles or fermions . PEP applies to electrons, protons, neutrons, neutrinos, quarks – and their antiparticles – as well as composite fermions such as He 3 atoms. Thermodynamic properties of metals and semiconductors are largely determined by electron (fermion) behavior.
Abstract Two concepts, of fundamental importance to quantum mechanics, will be discussed in this chapter. The first is that of symmetry. Even though the concept of symmetry is familiar in a wide range of natural sciences, the way symmetry constrains the consequences of quantum mechanics is rather subtle and, at the same time, far-reaching. The second is the symmetry property of the states under the exchange of two identical particles. Identical particles with a half-integer spin (fermions) obey the Fermi–Dirac statistics: the wave functions are totally antisymmetric under the exchange of the particles. Identical particles with an integer spin (bosons) are instead subject to the Bose–Einstein statistics. Their wave functions are totally symmetric.
For a quantum mechanical system of N particles, the Hamiltonian is a sum of the total kinetic energy and the potential energy. In classical physics, it is possible to keep track of individual particles. A system of N identical particles is said to satisfy Bose-Einstein statistics if its wave function is symmetric under the exchange of particles, and these particles are known as bosons. In the nonrelativistic quantum mechanics, this principle must be accepted as an empirical postulate. In the relativistic quantum theory, it can be proven that half-integer-spin particles cannot be bosons and integer-spin particles cannot be fermions. The Pauli exclusion principle plays a critical role in programming physical properties of electrons or more generally fermions.