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arXiv:1807.08656 · Physical Review Letters

Extractable Work, the Role of Correlations, and Asymptotic Freedom in Quantum Batteries

Gian Marcello Andolina, Maximilian Keck, Andrea Mari, Michele Campisi, Vittorio Giovannetti, Marco Polini

Published Feb 1, 2019• 369 citations
arXivHTMLPDF

Abstract

We investigate a quantum battery made of N two-level systems, which is charged by an optical mode via an energy-conserving interaction. We quantify the fraction of energy stored in the battery that can be extracted in order to perform thermodynamic work. We first demonstrate that this quantity is highly reduced by the presence of correlations between the charger and the battery or between the subsystems composing the battery. We then show that the correlation-induced suppression of extractable energy, however, can be mitigated by preparing the charger in a coherent optical state. We conclude by proving that the charger-battery system is asymptotically free of such locking correlations in the N→∞ limit.

DOI
10.1103/physrevlett.122.047702

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We investigate a quantum battery made of N two-level systems, which is charged by an optical mode via an energy-conserving interaction. We quantify the fraction of energy stored in the battery that can be extracted in order to perform thermodynamic work. We first demonstrate that this quantity is highly reduced by the presence of correlations between the charger and the battery or between the subsystems composing the battery. We then show that the correlation-induced suppression of extractable energy, however, can be mitigated by preparing the charger in a coherent optical state. We conclude by proving that the charger-battery system is asymptotically free of such locking correlations in the N→∞ limit.
Charging a quantum battery through a pumped charger can lock a substantial part of its stored energy inside the bipartite correlations that grow between the constituent cells, and this \emph{correlation ergotropy}, being the energy that no local single-cell operation can reach and that only collective operations can recover, is the object of the present study. Following the charging trajectory of two coupled three-level cells, we find that the correlation ergotropy closely tracks the logarithmic negativity, which shows that the locked energy is carried by genuine bipartite entanglement rather than by coherent collective dynamics alone, and that an equal-strength coherent non-entangling drive produces no such locking at all. For a pure two-cell battery we establish an exact, basis-independent closed form in which the locked energy depends only on the sorted eigenvalues of the reduced cell and the cell energy levels, revealing that the locked fraction rises from zero at the separable corners of the Schmidt simplex to unity at the symmetric maximally entangled state and remains invariant under local unitaries. Decoherence and dephasing, which destroy the correlations, do \emph{not} release this energy but erase it, so extraction must be collective and must take place while the correlations persist, while cold damping leaves the effect intact and thermal occupation suppresses it. These results give a resource-theoretic reading of correlations in quantum batteries, sharpen the line between genuine entanglement and coherent collective dynamics, and point to experimentally accessible conditions for correlated-charge and collective-extraction protocols.
In this work, we investigate the autonomous charging process of a quantum battery coupled to a structured reservoir composed of two qubits, each locally coupled to its own bosonic thermal bath. Moreover, the reservoir interacts with a charger-battery architecture through three configurations: (I) direct coupling between reservoir qubits and battery; (II) collective coupling among the reservoir qubits, charger, and battery; and (III) a collective coupling between the reservoir qubits and charger together with a local charger-battery interaction. However, by using incoherent and coherent initial states, we analyze the stored energy, ergotropy, and charging power of the battery, and derive upper and lower bounds on the extractable work in terms of the free energy of coherence and the correlations exchanged between subsystems. Our results show that global and local coherences, as well as total correlations, act as quantum resources that enhance autonomous charging. Additionally, we demonstrate that the free energy stored in the quantum battery splits into contributions from coherence and correlations, providing numerical evidence that supports the derived ergotropy bounds. Importantly, this work highlights how structured reservoirs enable autonomous and resource-enhanced quantum battery operation.
A solvable charger--battery model is introduced in which quantum coherence controls both where a quantum battery's charge is stored and how robustly it survives noise. Charging converts the charger's coherence into charger--battery entanglement and splits the deposited work between a locally extractable part and a correlation-locked part accessible only through joint operations; for a qubit, the split obeys an exact complementarity, and at maximal coherence, the battery is locally passive with the entire charge locked in correlations. Robustness follows local accessibility: the stored energy and locally extractable work are population-based, immune to pure dephasing, and limited only by relaxation, with an energy half-life, whereas the correlation-locked work is fragile to both dephasing and relaxation. Dephasing, global and local depolarization, and amplitude damping are treated through a single gain--loss competition algebra, and the resulting storage lifetimes are made concrete with superconducting-transmon parameters.
Energy can be stored in quantum batteries by electromagnetic fields as chargers. In this paper, the performance of a quantum battery with single and double chargers is studied. It is shown that by using two independent charging fields, prepared in coherent states, the charging power of the quantum battery can be significantly improved, though the average number of embedded photons are kept the same in both scenarios. The results reveal that for the case of initially correlated states of the chargers, the amount of extractable energy, measured by ergotropy, is more than initially uncorrelated ones, with appropriate degrees of field intensity. Though the correlated chargers lead to greater reduction in the purity of the quantum battery, more energy and in turn more ergotropy are stored in this case. In addition, we study the battery-charger mutual information and von Neumann entropy and by using their relation we find that both quantum and classical correlations are generated between the quantum battery and chargers. We also study quantum consonance of the battery as the nonlocal coherence among its cells and find some qualitative relations between the generation of such correlations and the capability of energy storage in the quantum battery.
We investigate a two-qubit quantum battery where coherent charger-battery coupling competes with non-Markovian environmental interactions. By tuning the coupling strengths and detuning, we identify regimes in which environmental memory enhances energy storage and charging power, while strong dissipation suppresses ergotropy by driving the battery into passive states. We show that detuning plays a dual role: reducing dissipation and inducing a phase shift in the memory kernel that controls the interference between coherent energy exchange and environment-induced backflow. As a result, although the stored energy varies smoothly, the extractable work exhibits a discontinuous onset at a critical detuning, signaling a first-order phase transition in ergotropy. The corresponding phase diagram in the coupling-detuning plane reveals a sharp boundary between thermodynamically inactive and work-producing regimes. Our results demonstrate that phase-controlled coherence and non-Markovianity provide a powerful mechanism for optimizing work extraction in open quantum batteries, offering practical strategies for noise-resilient quantum energy storage.