Instead of calculating phase shifts at small scattering energies for a given two-body central potential and from these deduce by extrapolation to zero energy the associated scattering length and effective range, we write those parameters as integrals which are evaluated numerically to high accuracy for the Lennard-Jones and Aziz et al. interatomic potentials for both
3He and
4He, as well as for the Kolos-Wolniewicz potential between hydrogen isotopes.
The most important parameters in the study of low-energy scattering are the s-wave and p-wave scattering lengths and the s-wave effective range. We solve the scattering problem and find two useful formulas for the scattering length and the effective range for any angular momentum, as long as the Wigner threshold law holds. Using that formalism, we obtain a set of useful formulas for the angular-momentum scattering parameters of four different model potentials: hard-sphere, soft-sphere, spherical well, and well-barrier potentials. The behavior of the scattering parameters close to Feshbach resonances is also analyzed. Our derivations can be useful as hands-on activities for learning scattering theory.
Scattering processes are a fundamental way of experimentally probing distributions and properties of systems in several areas of physics. Considering two-body scattering at low energies, when the de Broglie wavelength is larger than the range of the potential, partial waves with high angular momentum are typically unimportant. The dominant contribution comes from
l=0 partial waves, commonly known as
s-wave scattering. This situation is very relevant in atomic physics, e.g. cold atomic gases, and nuclear physics, e.g. nuclear structure and matter. This manuscript is intended as a pedagogical introduction to the topic while covering a numerical approach to compute the desired quantities. We introduce low-energy scattering with particular attention to the concepts of scattering length and effective range. These two quantities appear in the effective-range approximation, which universally describes low-energy processes. We outline a numerical procedure for calculating the scattering length and effective range of spherically symmetric two-body potentials. As examples, we apply the method to the spherical well, modified Pöschl-Teller, Gaussian, and Lennard-Jones potentials. We hope to provide the tools so students can implement similar calculations and extend them to other potentials.
The interaction between atoms behaves as $\ensuremath{-}\ensuremath{\alpha}{/r}^{n}$ at large distances and, owing to the large reduced mass \ensuremath{\mu} of the collision pair, allows a semiclassical treatment within the potential well. As a result, the low-energy scattering is governed by two large parameters: the asymptotic parameter $\ensuremath{\gamma}=\sqrt{2\ensuremath{\mu}\ensuremath{\alpha}}/\ensuremath{\Elzxh}\ensuremath{\gg}{a}_{0}^{(n\ensuremath{-}2)/2}$ (
a0 is the Bohr radius) and the semiclassical zero-energy phase $\ensuremath{\Phi}\ensuremath{\gg}1.$ In our previous work [Phys. Rev. A 48, 546 (1993)] we obtained an analytical expression for the scattering length
a, which showed that it has 75% preference for positive values for
n=6, characteristic of collisions between ground-state neutral atoms. In this paper we calculate the effective range and show that it is a function of
a, ${r}_{e}{=F}_{n}\ensuremath{-}{G}_{n}{/a+H}_{n}{/a}^{2},$ where
Fn, Gn, and
Hn depend only on \ensuremath{\gamma}. Thus, we know the
s-phase shift at low momenta $k\ensuremath{\ll}{\ensuremath{\gamma}}^{\ensuremath{-}2/(n\ensuremath{-}2)}$ from the expansion $k\mathrm{cot}{\ensuremath{\delta}}_{0}\ensuremath{\simeq}\ensuremath{-}1/a+\frac{1}{2}{r}_{e}{k}^{2}.$ At $k\ensuremath{\gg}{\ensuremath{\gamma}}^{\ensuremath{-}2/(n\ensuremath{-}2)}$ the phase shift is obtained semiclassically as ${\ensuremath{\delta}}_{0}=\ensuremath{\Phi}+\ensuremath{\pi}/4\ensuremath{-}{I}_{n}{\ensuremath{\gamma}}^{2/n}{k}^{(n\ensuremath{-}2)/n},$ where ${I}_{n}=[n/(n\ensuremath{-}2)]\ensuremath{\Gamma}((n\ensuremath{-}1)/n)\ensuremath{\Gamma}((n+2)/2n)/\sqrt{\ensuremath{\pi}}.$ Therefore, \ensuremath{\gamma} and \ensuremath{\Phi} determine the
s-wave atomic scattering in a wide range of momenta, as well as the positions of upper bound states of the diatomic molecule.
It is shown how the concepts of scattering length and effective range, previously introduced for low-energy scattering from a potential V(r) in a plane, correspond to the well-known parameters in three dimensions. This is done by considering low-energy scattering in a general dimension n\ensuremath{\ge}2 and subsequently showing that both the n=2 and n=3 cases fit naturally in such a generalized treatment. Furthermore, our previous work is extended to long-range potentials, decreasing faster than 1/
rn+1. The method used is based on the properties of a local scattering length a(r) for the potential V(r) cut off at radius r and an equivalent hard-sphere radius a(r,k) for k\ensuremath{\ne}0. Some applications and illustrative examples are given.