Bridging thermodynamics and metrology in nonequilibrium quantum thermometry
Vasco Cavina, Luca Mancino, Antonella De Pasquale, Ilaria Gianani, Marco Sbroscia, Robert I. Booth, Emanuele Roccia, Roberto Raimondi, Vittorio Giovannetti, Marco Barbieri
Single-qubit thermometry presents the simplest tool to measure the temperature of thermal baths with reduced invasivity. At thermal equilibrium, the temperature uncertainty is linked to the heat capacity of the qubit, however, the best precision is achieved outside the equilibrium condition. Here, we discuss a way to generalize this relation in a nonequilibrium regime, taking into account purely quantum effects such as coherence. We support our findings with an experimental photonic simulation.
Single-qubit thermometry presents the simplest tool to measure the temperature of thermal baths with reduced invasivity. At thermal equilibrium, the temperature uncertainty is linked to the heat capacity of the qubit, however, the best precision is achieved outside the equilibrium condition. Here, we discuss a way to generalize this relation in a nonequilibrium regime, taking into account purely quantum effects such as coherence. We support our findings with an experimental photonic simulation.
The metrological limits of thermometry operated in nonequilibrium dynamical regimes are analyzed. We consider a finite-dimensional quantum system, employed as a quantum thermometer, in contact with a thermal bath inducing Markovian thermalization dynamics. The quantum thermometer is initialized in a generic quantum state, possibly including quantum coherence with respect to the Hamiltonian basis. We prove that the precision of the thermometer, quantified by the Quantum Fisher Information, is enhanced by the quantum coherence in its initial state. We analytically show this in the specific case of qubit thermometers for which the maximization of the Quantum Fisher Information occurs at a finite time during the transient thermalization dynamics. Such a finite-time precision enhancement can be better than the precision that is achieved asymptotically.
We discuss the application of techniques of quantum estimation theory and quantum metrology to thermometry. The ultimate limit to the precision at which the temperature of a system at thermal equilibrium can be determined is related to the heat capacity when global measurements are performed on the system. We prove that if technical or practical limitations restrict our capabilities to local probing, the highest achievable accuracy to temperature estimation reduces to a sort of mesoscopic version of the heat capacity. Adopting a more practical perspective, we also discuss the relevance of qubit systems as optimal quantum thermometers, in order to retrieve the temperature, or to discriminate between two temperatures, characterizing a thermal reservoir. We show that quantum coherence and entanglement in a probe system can facilitate faster, or more accurate measurements of temperature. While not surprising given this has been demonstrated in phase estimation, temperature is not a conventional quantum observable, therefore these results extend the theory of parameter estimation to measurement of non-Hamiltonian quantities. Finally we point out the advantages brought by a less standard estimation technique based on sequential measurements, when applied to quantum thermometry.
Accurate temperature estimation in the quantum and cryogenic regimes remains a fundamental challenge. Here, we investigate nonequilibrium quantum thermometry using a single-qubit probe coupled to a bosonic bath through noncommuting interaction operators, which unify pure dephasing and dissipative dynamics within a spin-boson model. We show that the interference between these two coupling channels induces strong non-Markovian feedback between populations and coherences, leading to coherence trapping and enhanced thermal sensitivity. Remarkably, by tuning the coupling structure, the probe's temperature sensitivity exhibits a quadratic low-temperature scaling, even under weak coupling. Moreover, while coherence-based measurements are formally suboptimal, they become the most informative in the early nonequilibrium regime, where memory effects dominate. Our findings identify noncommutative system-bath couplings as a practical and tunable resource for achieving high-precision quantum thermometry in realistic open-system architectures.
Measuring the temperature of a quantum system is an essential task in almost all aspects of quantum technologies. Theoretically, an optimal strategy for thermometry often requires measuring energy, which demands full accessibility over the entire system as well as a complex entangled measurement basis. In this paper, we take a different approach and show that single-qubit sequential measurements in the computational basis not only allow for precise thermometry of a many-body system, but may also achieve precision beyond the thermometry capacity of the probe at equilibrium, given by the Cram\'er-Rao bound. Thus, using consecutive single-qubit measurements of the probe out of equilibrium is, in most cases, very beneficial, as it achieves lower-temperature uncertainties and avoids demanding energy measurements when compared with probes at thermal equilibrium. To obtain such precision, the time between the two subsequent measurements should be smaller than the thermalization time so that the probe never thermalizes. Therefore, the nonequilibrium dynamics of the system continuously imprint information about temperature in the state of the probe. To demonstrate the generality of our findings, we consider thermometry in both spin chains and the Jaynes-Cummings model.
Quantum thermometry aims to measure temperature in nanoscale quantum systems, paralleling classical thermometry. However, temperature is not a quantum observable, and most theoretical studies have therefore concentrated on analyzing fundamental precision limits set by the quantum Fisher information through the quantum Cramer-Rao bound. In contrast, whether a direct temperature readout can be achieved in quantum thermometry remains largely unexplored, particularly under the nonequilibrium conditions prevalent in real-world applications. To address this, we develop a direct temperature readout scheme based on a thermodynamic inference strategy. The scheme integrates two conceptual developments: (i) By applying the maximum entropy principle with the thermometer's mean energy as a constraint, we assign a reference temperature to the nonequilibrium thermometer. We demonstrate that this reference temperature outperforms a commonly used effective temperature defined through equilibrium analogy. (ii) We obtain positive semi-definite error functions that lower-bound the deviation of the reference temperature from the true temperature-in analogy to the quantum Cramer-Rao bound for the mean squared error-and vanish upon thermalization with the sample. Combining the reference temperature with these error functions, we introduce a notion of corrected dynamical temperature which furnishes a postprocessed temperature readout under nonequilibrium conditions. This corrected dynamical temperature can be evaluated adaptively without prior knowledge of the actual temperature. We validate the corrected dynamical temperature in a qubit-based thermometer under a range of nonequilibrium initial states, confirming its capability to estimate the true temperature. Importantly, we find that increasing quantum coherence can enhance the precision of this readout.
A classical thermometer typically works by exchanging energy with the system being measured until it comes to equilibrium, at which point the readout is related to the final energy state of the thermometer. A recent paper noted that with a quantum thermometer consisting of a single spin/qubit, temperature discrimination is better achieved at finite times rather than once equilibration is essentially complete. Furthermore, preparing a qubit thermometer in a state with quantum coherence instead of an incoherent one improves its sensitivity to temperature differences. Implementing a recent proposal for efficiently emulating an arbitrary quantum channel, we use the quantum polarisation state of individual photons as models of "single-qubit thermometers" which evolve for a certain time in contact with a thermal bath. We investigate the optimal thermometer states for temperature discrimination, and the optimal interaction times, confirming that there is a broad regime where quantum coherence provides a significant improvement. We also discuss the more practical question of thermometers composed of a finite number of spins/qubits (greater than one), and characterize the performance of an adaptive protocol for making optimal use of all the qubits.