Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

arXiv:1805.07420 · The Journal of Chemical Physics

Photon entanglement entropy as a probe of many-body correlations and fluctuations

Hao Li, Andrei Piryatinski, Ajay Ram Srimath Kandada, Carlos Silva, Eric R. Bittner

Published May 10, 2019• 17 citations
arXivHTMLPDF

Abstract

Recent theories and experiments have explored the use of entangled photons as a spectroscopic probe of physical systems. We describe here a theoretical description for entropy production in the scattering of an entangled biphoton Fock state within an optical cavity. We develop this using perturbation theory by expanding the biphoton scattering matrix in terms of single-photon terms in which we introduce the photon-photon interaction via a complex coupling constant, ξ. We show that the von Neumann entropy provides a concise measure of this interaction. We then develop a microscopic model and show that in the limit of fast fluctuations, the entanglement entropy vanishes, whereas in the limit of slow fluctuations, the entanglement entropy depends on the magnitude of the fluctuations and reaches a maximum. Our result suggests that experiments measuring biphoton entanglement give microscopic information pertaining to exciton-exciton correlations.

DOI
10.1063/1.5083613

Related papers

Probing exciton/exciton interactions with entangled photons: Theory

Eric R. Bittner, Hao Li, Andrei Piryatinski +2 more

Quantum entangled photons provide a sensitive probe of many-body interactions and offer a unique experimental portal for quantifying many-body correlations in a material system. In this paper, we present a theoretical demonstration of how photon-photon entanglement can be generated via interactions between coupled qubits. Here, we develop a model for the scattering of an entangled pair of photons from a molecular dimer. We develop a diagrammatic theory for the scattering matrix and show that one can correlate the von Neumann entropy of the outgoing bi-photon wave function with exciton exchange and repulsion interactions. We conclude by discussing possible experimental scenarios for realizing these ideas.

arXiv:1911.04614•The Journal of Chemical Physics•Feb 19, 2020•16 citations

Scattering theory of frequency-entangled biphoton states facilitated by cavity polaritons

Andrei Piryatinski, Nishaant Jacobus, Sameer Dambal +3 more

The use of quantum light to probe exciton properties in semiconductor and molecular nanostructures typically occurs in the low-intensity regime. A substantial enhancement of exciton-photon coupling can be achieved with photonic cavities, where excitons hybridize with cavity modes to form polariton states. To provide a theoretical framework for interpreting emerging experimental efforts in this direction, we develop a scattering theory describing the interaction of frequency-entangled photon pairs with cavity polariton and bipolariton states under various coupling regimes. Employing the Tavis-Cummings model in combination with our scattering approach, we present a quantitative analysis of how the interaction of the entangled photon pair with the polariton/bipolariton modifies its joint spectral amplitude (JSA). Specifically, we examine the effects of the cavity-mode steady-state population, exciton-cavity coupling strength, and different forms of the input photon JSA. Our results show that the entanglement entropy of the scattered photons is highly sensitive to the interplay between the input JSA and the spectral line shapes of the polariton resonances, emphasizing the cavity filtering effects. We suggest that biphoton scattering quantum light spectroscopy best serves as a sensitive probe of polariton and bipolariton states in the photon-vacuum cavity state. Our approach is not only robust to various regimes of cavity-exciton coupling, but also amenable to extensions beyond the Tavis-Cummings model, enabling the representation of a broad class of molecular systems and solid state quantum materials.

arXiv:2510.16358•Physical Review A•Feb 23, 2026•1 citation

Detecting entanglement with transport measurement in weakly interacting and fluctuating systems

Zhenhua Zhu, Gu Zhang, Dong E. Liu

Measuring entanglement entropy in interacting, multipartite systems remains a significant experimental challenge. We address this challenge by developing a protocol to measure von Neumann entropy (VNE) and mutual information in quantum transport systems with both many-body interactions and multiple subsystems. Our analysis indicates that the vital connection between VNE and two-point correlation functions persists under these realistic conditions. The measurement is shown to be feasible for systems with boundary interactions and, critically, for bulk-interacting systems subject to a quantum quench of their internal couplings. Our work provides a pathway to experimentally quantify entanglement in complex interacting systems and establishes mutual information as an experimentally accessible indicator for system-environment entanglement.

arXiv:2508.02378•Physical review. B./Physical review. B•Jan 12, 2026•0 citations

Quantum probe advantage in learning many-body systems

Wenzheng Dong, Andrew G. Green, Vlatko Vedral +1 more

Which properties of a quantum many-body system are operationally accessible is a central question underlying spectroscopy, thermodynamics, and quantum information science. Conventional response theory answers this question within a system-only paradigm: one perturbs and measures the matter itself, obtaining susceptibility built from causally ordered nested commutators. Here we show that coherently controlled quantum probes, when measured at the end, define a strictly larger operational learning framework beyond that accessible from response theory. We establish this through a quantum-circuit description that unifies spectroscopy, probe microscopy, and probe-based quantum technologies within a common operational framework, from which we develop quantum protocols for learning many-body properties from probe readout only. This advantage arises because the reduced dynamics of quantum probes generically encode anti-commutator and mixed-order correlators of the target; therefore, measurements on the probe provide access to fluctuations, non-equilibrium structure, and entanglement entropy that are in general not accessible through response functions or a single probe alone. Moreover, we demonstrate that entangled probes can access many-body properties such as von Neumann entropy. We prove that the required probe resources scale with the complexity of the target correlations rather than with the size of the many-body system. Quantum probes are therefore not merely more sensitive sensors but provide a new way to learn many-body properties distinct from those of tomography or quantum simulation.

quant-pharXiv:2607.11829•Jul 14, 2026•0 citations

A von Neumann Entropy Measure of Entanglement Transfer in a Double Jaynes-Cummings Model

Samina Masood, Allen H. Miller

We study the entanglement in a system consisting of two non-interacting atoms located in separate cavities, both in their ground states. A single incoming photon has a non-zero probability of entering either of the two cavities. The Jaynes-Cummings interaction in the rotating wave approximation describes the coupling of each atom with the radiation field. We compute and analyze the atom-atom entanglement, the entanglement between the two photon modes, and also the entanglement between each atom and each photon mode. The measure of entanglement is the von Neumann entropy. For the case in which the two atom-photon systems have identical properties, but allowing for non-resonant conditions, the sum of the atom-atom and photon-modes-entanglement is time independent. The effect of detuning is to decrease the strength of the largest entanglement achieved and to shorten the time for it to occur. The results support the fact that the state of the photons after emergence from cavities is entangled, notwithstanding its single-particle nature. In addition, for the case of resonance and identical cavity parameters, we demonstrate that von Neumann entropy is always greater than or equal to the measure of entanglement known as negativity.

arXiv:1412.5410•Dec 17, 2014•0 citations

Fluctuations of quantum entanglement

Edward B. Fel’dman, M. A. Yurishchev

It is emphasized that quantum entanglement determined in terms of the von Neumann entropy operator is a stochastic quantity and, therefore, can fluctuate. The rms fluctuations of the entanglement entropy of two-qubit systems in both pure and mixed states have been obtained. It has been found that entanglement fluctuations in the maximally entangled states are absent. Regions where the entanglement fluctuations are larger than the entanglement itself (strong fluctuation regions) have been revealed. It has been found that the magnitude of the relative entanglement fluctuations is divergent at the points of the transition of systems from an entangled state to a separable state. It has been shown that entanglement fluctuations vanish in the separable states.

arXiv:0908.3771•Journal of Experimental and Theoretical Physics Letters•Sep 1, 2009•11 citations
Recent theories and experiments have explored the use of entangled photons as a spectroscopic probe of physical systems. We describe here a theoretical description for entropy production in the scattering of an entangled biphoton Fock state within an optical cavity. We develop this using perturbation theory by expanding the biphoton scattering matrix in terms of single-photon terms in which we introduce the photon-photon interaction via a complex coupling constant, ξ. We show that the von Neumann entropy provides a concise measure of this interaction. We then develop a microscopic model and show that in the limit of fast fluctuations, the entanglement entropy vanishes, whereas in the limit of slow fluctuations, the entanglement entropy depends on the magnitude of the fluctuations and reaches a maximum. Our result suggests that experiments measuring biphoton entanglement give microscopic information pertaining to exciton-exciton correlations.
Quantum entangled photons provide a sensitive probe of many-body interactions and offer a unique experimental portal for quantifying many-body correlations in a material system. In this paper, we present a theoretical demonstration of how photon-photon entanglement can be generated via interactions between coupled qubits. Here, we develop a model for the scattering of an entangled pair of photons from a molecular dimer. We develop a diagrammatic theory for the scattering matrix and show that one can correlate the von Neumann entropy of the outgoing bi-photon wave function with exciton exchange and repulsion interactions. We conclude by discussing possible experimental scenarios for realizing these ideas.
The use of quantum light to probe exciton properties in semiconductor and molecular nanostructures typically occurs in the low-intensity regime. A substantial enhancement of exciton-photon coupling can be achieved with photonic cavities, where excitons hybridize with cavity modes to form polariton states. To provide a theoretical framework for interpreting emerging experimental efforts in this direction, we develop a scattering theory describing the interaction of frequency-entangled photon pairs with cavity polariton and bipolariton states under various coupling regimes. Employing the Tavis-Cummings model in combination with our scattering approach, we present a quantitative analysis of how the interaction of the entangled photon pair with the polariton/bipolariton modifies its joint spectral amplitude (JSA). Specifically, we examine the effects of the cavity-mode steady-state population, exciton-cavity coupling strength, and different forms of the input photon JSA. Our results show that the entanglement entropy of the scattered photons is highly sensitive to the interplay between the input JSA and the spectral line shapes of the polariton resonances, emphasizing the cavity filtering effects. We suggest that biphoton scattering quantum light spectroscopy best serves as a sensitive probe of polariton and bipolariton states in the photon-vacuum cavity state. Our approach is not only robust to various regimes of cavity-exciton coupling, but also amenable to extensions beyond the Tavis-Cummings model, enabling the representation of a broad class of molecular systems and solid state quantum materials.
Measuring entanglement entropy in interacting, multipartite systems remains a significant experimental challenge. We address this challenge by developing a protocol to measure von Neumann entropy (VNE) and mutual information in quantum transport systems with both many-body interactions and multiple subsystems. Our analysis indicates that the vital connection between VNE and two-point correlation functions persists under these realistic conditions. The measurement is shown to be feasible for systems with boundary interactions and, critically, for bulk-interacting systems subject to a quantum quench of their internal couplings. Our work provides a pathway to experimentally quantify entanglement in complex interacting systems and establishes mutual information as an experimentally accessible indicator for system-environment entanglement.
Which properties of a quantum many-body system are operationally accessible is a central question underlying spectroscopy, thermodynamics, and quantum information science. Conventional response theory answers this question within a system-only paradigm: one perturbs and measures the matter itself, obtaining susceptibility built from causally ordered nested commutators. Here we show that coherently controlled quantum probes, when measured at the end, define a strictly larger operational learning framework beyond that accessible from response theory. We establish this through a quantum-circuit description that unifies spectroscopy, probe microscopy, and probe-based quantum technologies within a common operational framework, from which we develop quantum protocols for learning many-body properties from probe readout only. This advantage arises because the reduced dynamics of quantum probes generically encode anti-commutator and mixed-order correlators of the target; therefore, measurements on the probe provide access to fluctuations, non-equilibrium structure, and entanglement entropy that are in general not accessible through response functions or a single probe alone. Moreover, we demonstrate that entangled probes can access many-body properties such as von Neumann entropy. We prove that the required probe resources scale with the complexity of the target correlations rather than with the size of the many-body system. Quantum probes are therefore not merely more sensitive sensors but provide a new way to learn many-body properties distinct from those of tomography or quantum simulation.
We study the entanglement in a system consisting of two non-interacting atoms located in separate cavities, both in their ground states. A single incoming photon has a non-zero probability of entering either of the two cavities. The Jaynes-Cummings interaction in the rotating wave approximation describes the coupling of each atom with the radiation field. We compute and analyze the atom-atom entanglement, the entanglement between the two photon modes, and also the entanglement between each atom and each photon mode. The measure of entanglement is the von Neumann entropy. For the case in which the two atom-photon systems have identical properties, but allowing for non-resonant conditions, the sum of the atom-atom and photon-modes-entanglement is time independent. The effect of detuning is to decrease the strength of the largest entanglement achieved and to shorten the time for it to occur. The results support the fact that the state of the photons after emergence from cavities is entangled, notwithstanding its single-particle nature. In addition, for the case of resonance and identical cavity parameters, we demonstrate that von Neumann entropy is always greater than or equal to the measure of entanglement known as negativity.
It is emphasized that quantum entanglement determined in terms of the von Neumann entropy operator is a stochastic quantity and, therefore, can fluctuate. The rms fluctuations of the entanglement entropy of two-qubit systems in both pure and mixed states have been obtained. It has been found that entanglement fluctuations in the maximally entangled states are absent. Regions where the entanglement fluctuations are larger than the entanglement itself (strong fluctuation regions) have been revealed. It has been found that the magnitude of the relative entanglement fluctuations is divergent at the points of the transition of systems from an entangled state to a separable state. It has been shown that entanglement fluctuations vanish in the separable states.