Abstract Classical arguments for thermalization of isolated systems do not apply in a straightforward way to the quantum case. Recently, there has been interest in diagnostics of quantum chaos in many-body systems. In the classical case, chaos is a popular explanation for the legitimacy of the methods of statistical physics. In this work, we relate a previously proposed criteria of quantum chaos in the unitary time evolution operator to the entanglement entropy growth for a far-from-equilibrium initial pure state. By mapping the unitary time evolution operator to a doubled state, chaos can be characterized by suppression of mutual information between subsystems of the past and that of the future. We show that when this mutual information is small, a typical unentangled initial state will evolve to a highly entangled final state. Our result provides a more concrete connection between quantum chaos and thermalization in many-body systems.
Abstract Classical arguments for thermalization of isolated systems do not apply in a straightforward way to the quantum case. Recently, there has been interest in diagnostics of quantum chaos in many-body systems. In the classical case, chaos is a popular explanation for the legitimacy of the methods of statistical physics. In this work, we relate a previously proposed criteria of quantum chaos in the unitary time evolution operator to the entanglement entropy growth for a far-from-equilibrium initial pure state. By mapping the unitary time evolution operator to a doubled state, chaos can be characterized by suppression of mutual information between subsystems of the past and that of the future. We show that when this mutual information is small, a typical unentangled initial state will evolve to a highly entangled final state. Our result provides a more concrete connection between quantum chaos and thermalization in many-body systems.
Statistical mechanics relies on the maximization of entropy in a system at thermal equilibrium. However, an isolated quantum many-body system initialized in a pure state remains pure during Schrödinger evolution, and in this sense it has static, zero entropy. We experimentally studied the emergence of statistical mechanics in a quantum state and observed the fundamental role of quantum entanglement in facilitating this emergence. Microscopy of an evolving quantum system indicates that the full quantum state remains pure, whereas thermalization occurs on a local scale. We directly measured entanglement entropy, which assumes the role of the thermal entropy in thermalization. The entanglement creates local entropy that validates the use of statistical physics for local observables. Our measurements are consistent with the eigenstate thermalization hypothesis.
Classical statistical mechanics relies on the ergodic hypothesis, which states that a system explores the entire allowed phase space during its time evolution. Pure quantum states are at odds with this concept as they remain in a single quantum state even if the system's parameters are suddenly altered. However, in a generic many-body system, coherent dynamics drive local thermalization of its subsystems. In this case, any local observable appears thermal and can be described by a statistical ensemble even though the full state remains pure. The key to understanding the phenomenon of quantum thermalization lies in the entanglement properties of the system: The presence of entanglement creates local entropy that validates the use of statistical physics.\nIn this thesis, we experimentally study the emergence of statistical mechanics in a quantum state and observe the fundamental role of quantum entanglement in facilitating this emergence. We perform microscopy on an evolving quantum system, and we see thermalization occur on a local scale while we measure that the full quantum state remains pure.\nThe only known robust exception from the paradigm of quantum thermalization is provided by disordered systems. In this case, the particle transport ceases through the system, preventing the formation of a sufficient amount of entanglement required for thermalization. However, if the many-body system is interacting, the state develops non-local quantum correlations that are inaccessible to any local observable. These correlations spread exponentially slowly in time throughout the entire system and are considered a hallmark feature of many-body-localized states.\nIn order to study the interplay between thermalization and localization in our system, we develop novel methods for high fidelity state preparation and readout. We achieved an exquisite isolation of our system from the environment, which allows us to monitor coherent many-body dynamics over multiple decades of time evolution.\nWe experimentally realize such a many-body localized system and observe the formation of non-local quantum correlations, while the particle transport is frozen in the system. Our work experimentally establishes many-body localization as a qualitatively distinct phenomenon from localization in non-interacting, disordered systems.
The exchange interaction arising from particle indistinguishability is of central importance in the physics of many-particle quantum systems. Here we study analytically the dynamical generation of quantum entanglement induced by this interaction in an isolated system, namely, an ideal Fermi gas confined in a chaotic cavity, which is described by a non-Gaussian pure state and evolves unitarily from it. We find that the breakdown of the quantum-classical correspondence of particle motion, via the dramatic change in the spatial structure of the many-body wave function, leads to profound changes of the entanglement. Furthermore, for a class of initial states, the changes engender the approach to thermal equilibrium everywhere in the cavity, with the well-known Ehrenfest time in quantum chaos as the thermalization time. Specifically, the quantum expectation values of various correlation functions at different spatial scales are all determined by the Fermi-Dirac distribution. In addition, by using the reduced density matrix (RDM) and the entanglement entropy (EE) as local probes, we find that the gas inside a subsystem is in equilibrium with that outside, and that its thermal entropy is the EE, even though the whole system is in a pure state.
Quantum many-body systems exhibit highly complex interactions that give rise to emergent collective phenomena beyond the behavior of individual particles. One of the most intriguing challenges in modern quantum physics is understanding how isolated quantum systems evolve toward thermal equilibrium despite following fundamentally reversible quantum dynamics. Quantum entanglement has emerged as a central mechanism governing information propagation, thermalization, and the development of statistical equilibrium in isolated many-body systems. Simultaneously, recent advances in quantum information science have enabled researchers to investigate the relationship between entanglement dynamics, information scrambling, and emergent quantum behavior using computational and analytical approaches. This study proposes a Quantum Information Analytics Framework for investigating thermalization processes in isolated many-body quantum systems through the integration of entanglement dynamics, quantum information measures, statistical mechanics, and computational modeling. The proposed framework evaluates system evolution using multiple performance indicators, including entanglement entropy, information propagation, thermal equilibrium, quantum coherence, and computational stability. The findings indicate that quantum entanglement plays a fundamental role in driving thermalization while preserving the underlying unitary evolution of isolated quantum systems. The proposed analytical framework contributes to a deeper understanding of emergent quantum dynamics and provides valuable insights for quantum computing, quantum simulation, condensed matter physics, and next-generation quantum information technologies.
Thermalization conventionally describes local properties of isolated many-body systems at equilibrium. Magic, or nonstabilizerness $\unicode{x2013}$ the resource enabling universal quantum computation $\unicode{x2013}$ is by contrast encoded in the global structure of the many-body wavefunction. We show that, despite its global nature, the magic of equilibrium pure states of chaotic many-body systems, including late-time evolved states and energy eigenstates, is universal: it is captured by the thermal Scrooge ensemble, the minimally informative ensemble of pure states consistent with the Gibbs state at the same effective temperature. Therefore, for systems with no conserved quantities other than the total energy, equilibrium magic is a function of temperature alone, independent of the initial state and other microscopic features of the equilibrium state. This yields concrete universal predictions for the stabilizer Rényi entropies (SREs). At infinite temperature, the SRE is set by Haar-like fluctuations of the Pauli spectrum, while at finite temperature energy conservation induces a volume-law thermodynamic correction controlled by the thermal Pauli spectrum. We support these predictions with analytical arguments and extensive numerical simulations. We further show that chaotic many-body systems at high temperatures possess long-range magic and entanglement that cannot be removed by finite-depth local quantum circuits. Our results establish magic as a thermodynamic property of chaotic many-body systems and suggest that Scrooge ensembles may provide a unified framework for quantum many-body resources.
One key issue of the foundation of statistical mechanics is the emergence of equilibrium ensembles in isolated and closed quantum systems. Recently, it was predicted that in the thermodynamic (N→∞) limit the density matrix emerges for small subsystems from almost all pure states of large quantum many-body systems. This notion of canonical is assumed to originate from the entanglement between subsystem and environment and the resulting intrinsic quantum complexity of the many-body state. We show that quantum chaos plays a crucial role in the emergence of typicality for large but finite quantum systems. We demonstrate that the degree of typicality can be quantitatively controlled and tuned by the degree of quantum chaoticity present in the many-body system.