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arXiv:1805.01895

Quantum physics of the systems with ultrashort potentials: Introduction to a new analytically solvable model

Deepak Kumar, Rajendran Saravanan, Aniruddha Chakraborty

Published May 4, 2018• 0 citations
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Abstract

In this paper, we give a general method to treat one-dimensional quantum systems whose potential are of ultra-short width. We have considered a quantum system with ultrashort potential. The exact analytic forms of the wave function, tunnelling probability and Ramsauer effect (scattering probability) are calculated. The presented results are general and the method is applicable to any symmetric potential. The results have applications in understanding nanodevices.

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On the basis of special mathematical functions they derived the complete quantum mechanical solution for the wave functions and the transmission coefficient. They also analyzed this model semiclassically and compared it with the exact results. This comparison yields interesting implications on the validity and accuracy of semiclassical approximation. In particular, they solved the case of dramatically avoided crossing with exponentially steep potential curves, and obtained the probability of one-way passage through the interaction region. The overall behavior corresponds to the probability of tunneling through the single potential barrier. In addition, there are complete reflection resonances at discrete energies, resulting from the trapping of a wave in the potential well. The formalism of diabatically avoided crossing model is useful in laser control of molecular reactions. 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The formalism above was proved to be extremely efficient taking the example of dissociative recombination H2+ + e- → H + H* because this is a diatomic system, quantum chemical data are easily available in the literature and they could demonstrate the superiority of their approach to the other approaches. Fifth, they suggested applications of basic physical concepts to economics. They introduced aggregate quantities in financial markets and interpreted these quantities as potential energy surfaces. They also formalized interactions between cyclic processes in terms of state to state transitions. Summarizing, they treated the exponential potential model of nonadiabatic transitions, introduced a new exactly solvable model of diabatically avoided crossing, discussed the semiclassical conditions for complete transmission and complete reflection from the viewpoint of laser control, contributed to scattering calculations, and introduced some interdisciplinary applications.

•Sep 29, 2000•0 citations
In this paper, we give a general method to treat one-dimensional quantum systems whose potential are of ultra-short width. We have considered a quantum system with ultrashort potential. The exact analytic forms of the wave function, tunnelling probability and Ramsauer effect (scattering probability) are calculated. The presented results are general and the method is applicable to any symmetric potential. The results have applications in understanding nanodevices.
A Brief History of Quantum Tunneling Some Basic Questions Concerning Quantum Tunneling Simple Solvable Problems Time-Dependence of the Wave Function in One-Dimensional Tunneling Semiclassical Approximations Generalization of the Bohr - Sommerfeld Quantization Rule and its Application to Quantum Tunneling Gamow's Theory, Complex Eigenvalues, and the Wave Function of a Decaying State Tunneling in Symmetric and Asymmetric Local Potentials and Tunneling in Nonlocal and Quasi-Solvable Barriers Classical Descriptions of Tunneling Tunneling in Time-Dependent Barriers Decay Width and Scattering Theory The Method of Variable Reflection Amplitude Applied to Solve Multichannel Tunneling Problems Path Integral and Its Semi-Classical Approximation in Quantum Tunneling Heisenberg's Equations of Motion for Tunneling Wigner Distribution Function in Quantum Tunneling Decay Widths of Siegert States, Complex Scaling and Dilatation Transformation Multidimensional Quantum Tunneling Group and Signal Velocities Time-Delay, Reflection Time Operator and Minimum Tunneling Time More about Tunneling Time Tunneling of a System with Internal Degrees of Freedom Motion of a Particle in a Waveguide with Variable Cross Section and in a Space Bounded by a Dumbbell-Shaped Object Relativistic Formulation of Quantum Tunneling Inverse Problems of Quantum Tunneling Some Examples of Quantum Tunneling in Atomic and Molecular Physics Some Examples from Condensed Matter Physics Alpha Decay.
We describe a method for evaluating analytical long-range contributions to scattering lengths for some potentials used in atomic physics. We assume that an interaction potential between colliding particles consists of two parts. The form of a short-range component, vanishing beyond some distance from the origin (a core radius), need not be given. Instead, we assume that a set of short-range scattering lengths due to that part of the interaction is known. A long-range tail of the potential is chosen to be an inverse power potential, a superposition of two inverse power potentials with suitably chosen exponents or the Lent potential. For these three classes of long-range interactions a radial Schrodinger equation at zero energy may be solved analytically with solutions expressed in terms of the Bessel, Whittaker and Legendre functions, respectively. We utilize this fact and derive exact analytical formulae for the scattering lengths. The expressions depend on the short-range scattering lengths, the core radius and parameters characterizing the long-range part of the interaction. Cases when the long-range potential (or its part) may be treated as a perturbation are also discussed and formulae for scattering lengths linear in strengths of the perturbing potentials are given. It is shown that for some combination of the orbital angular momentum quantum number and an exponent of the leading term of the potential the derived formulae, exact or approximate, take very simple forms and contain only polynomial and trigonometric functions. The expressions obtained in this paper are applicable to scattering of charged particles by neutral targets and to collisions between neutrals. The results are illustrated by accelerating convergence of scattering lengths computed for e - -Xe and Cs-Cs systems.
A method for determining the quantum wave impedance function for a quantum-mechanical system with an arbitrary piecewise constant potential has been developed.Using this method, both the well-known iterative formula [A.N. Khondker, M. R. Khan, A. F. M. Anwar, J. Appl.Phys.63, 5191 (1988)] and an alternative approach for calculating quantum wave impedance were derived.This approach was applied to both scattering and bound state cases.The general form of the wave functions for bound states, as well as the transmission and reection coecients in the scattering case, were obtained for systems with a potential consisting of an arbitrary number of rectangular barriers and wells.The application of the developed method was demonstrated by describing symmetric rectangular double-well and double-barrier quantum-mechanical systems.
They have analytically tested several quantum transitions in molecular dynamics. In addition, they have introduced applications of theoretical formalism in physics to economics. First, they have completed the semiclassical theory of nonadiabatic transitions in the exponential potential model. They treated a two-state quantum system, which commonly appears as a subsystem in many-state problems. They were concerned with one-dimensional Schroedinger equation, although the type or semiclassical approach which they used can be applied to higher-dimension potential surfaces by means of Fourier transform. In particular, they solved the case of repulsive exponentially growing potentials, that is the forward-back scattering. They re-expressed the nonadiabatic transition matrix, which describes the transition between the two states for one-direction passage, in terms of contour integrals in the complex coordinate plane. The integrands are adiabatic momenta derived from the eigenvalues of potential matrix. Such type of concept has the advantage that it can be applied to other models than just the exponential potential model. Based on this, they have obtained an analytical tool for describing one-transition point class of potential curve systems. Examples are Rosen-Zener-Demkov model and Landau-Zener-Stueckelberg model. The formalism, which they contributed to, is useful in describing physical processes such as the charge transfer, and it is suitable for shaping external fields or modulating their frequencies in order to achieve a desired state or a product with the theoretical 100% probability. Second, they have derived the first exact analytical solution for a diabatically avoided crossing model. The physical system is described with one-dimensional coupled potential well and barrier which do not intersect in the whole coordinate range. On the basis of special mathematical functions they derived the complete quantum mechanical solution for the wave functions and the transmission coefficient. They also analyzed this model semiclassically and compared it with the exact results. This comparison yields interesting implications on the validity and accuracy of semiclassical approximation. In particular, they solved the case of dramatically avoided crossing with exponentially steep potential curves, and obtained the probability of one-way passage through the interaction region. The overall behavior corresponds to the probability of tunneling through the single potential barrier. In addition, there are complete reflection resonances at discrete energies, resulting from the trapping of a wave in the potential well. The formalism of diabatically avoided crossing model is useful in laser control of molecular reactions. This is because the potential energy curves in realistic molecular systems can be shifted by the photon energy; the curves are coupled by the field intensity via the dipole moment. That is why the new topology of potential energy curves, which was so far broadly omitted, becomes practically interesting due to the development in lasers techniques. Third, they treated several two-state quantum systems common in molecular physics. The semiclassical conditions for the complete transmission and the complete reflection in one-dimensional scattering were given analytically. They discovered the possibility of these phenomena in energy ranges in which the complete reflection or the complete transmission are not commonly expected to occur. In particular, they have made use of the broadly shared assumption that the transitions between the states are localized phenomena. This enables them to separate the whole coordinate region into distinct subsets and to analyze the physics in each subset separately. Applying this approach, they obtained a fully algebraic problem, which can be treated e.g. by diagrammatic techniques. Let them also mention that the complete transmission or complete reflection conditions simplify the wave function, and hence the mathematical solution. The formalism which they used while deriving the semiclassical conditions for the resonant phenomena mentioned above can be further generalized. This will probably yield a whole spectrum of tools in the laser control of molecular processes. Fourth, they developed a powerful technique for solving integral equations with singular kernel. One of the physical formulations of scattering is the time-independent approach based on the Lippmann-Schwinger equation for the Green operator. They have developed a detailed technique how to treat the singularity in this equation. In particular, any scattering problem can be divided into two parts. The first one is the geometry of the system and the static interaction of its components. The second one is more dynamical: the singular equation for the Green operator including the variable energy of the scattering. They fix the most costly calculations in the static part. Then they solve the singularity analytically and thus obtain the cross section as a function of energy. The so far common approach is quite opposite: to fix the singularity first and then to recalculate heavily all the static part for any new value of energy. Obviously, their approach saves a considerable amount of computational time; therefore it is a good standpoint for treating large systems. The formalism above was proved to be extremely efficient taking the example of dissociative recombination H2+ + e- → H + H* because this is a diatomic system, quantum chemical data are easily available in the literature and they could demonstrate the superiority of their approach to the other approaches. Fifth, they suggested applications of basic physical concepts to economics. They introduced aggregate quantities in financial markets and interpreted these quantities as potential energy surfaces. They also formalized interactions between cyclic processes in terms of state to state transitions. Summarizing, they treated the exponential potential model of nonadiabatic transitions, introduced a new exactly solvable model of diabatically avoided crossing, discussed the semiclassical conditions for complete transmission and complete reflection from the viewpoint of laser control, contributed to scattering calculations, and introduced some interdisciplinary applications.