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arXiv:1802.07468

Can thermal quantum Gibbs states approve as quantum equilibrium states?

Ali Soltanmanesh

Published Feb 21, 2018• 1 citation
arXivHTMLPDF

Abstract

In this study, we investigate a quantum harmonic oscillator interacting with a thermal bath of oscillatory fields in a quantum circuit. By solving the Lindblad master equation, we calculate the resulting interference pattern from measuring the system in the momentum space. Interestingly, we show that even if one considers the decoherence effect, the system will keep some of its quantum properties. Indeed, the equilibration does not completely leave the system in a Gibbs state, and the system remains coherent. Moreover we discuss the requirements of a process that can be called a thermalization. We show that in our system, the quantum thermodynamic equilibration process cannot be considered a thermalization. Also, we discussed that a Lindblad system-bath interaction cannot be explained by a thermalization process. Such an effect strongly can be detected when the frequency of the central system is high and the temperature is low. Then, by introducing an entropy measure, we show that although the system is in maximum entropy, the equilibrium state is far from the Gibbs state.

DOI
10.48550/arxiv.1802.07468

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In this study, we investigate a quantum harmonic oscillator interacting with a thermal bath of oscillatory fields in a quantum circuit. By solving the Lindblad master equation, we calculate the resulting interference pattern from measuring the system in the momentum space. Interestingly, we show that even if one considers the decoherence effect, the system will keep some of its quantum properties. Indeed, the equilibration does not completely leave the system in a Gibbs state, and the system remains coherent. Moreover we discuss the requirements of a process that can be called a thermalization. We show that in our system, the quantum thermodynamic equilibration process cannot be considered a thermalization. Also, we discussed that a Lindblad system-bath interaction cannot be explained by a thermalization process. Such an effect strongly can be detected when the frequency of the central system is high and the temperature is low. Then, by introducing an entropy measure, we show that although the system is in maximum entropy, the equilibrium state is far from the Gibbs state.
Simulations are performed of a small quantum system interacting with a quantum environment. The system consists of various initial states of two harmonic oscillators coupled to give normal modes. The environment is "designed" by its level pattern to have a thermodynamic temperature. A random coupling causes the system and environment to become entangled in the course of time evolution. The approach to a Boltzmann distribution is observed, and effective fitted temperatures close to the designed temperature are obtained. All initial pure states of the system are driven to equilibrium at very similar rates, with quick loss of memory of the initial state. The time evolution of the von Neumann entropy is calculated as a measure of equilibration and of quantum coherence. It is pointed out using spatial density distribution plots that quantum interference is eliminated only with maximal entropy, which corresponds thermally to infinite temperature. Implications of our results for the notion of "classicalizing" behavior in the approach to thermal equilibrium are briefly considered.
We study a generic open quantum system where the coupling between the system and its environment is of an energy-preserving quantum nondemolition (QND) type. We obtain the general master equation for the evolution of such a system under the influence of a squeezed thermal bath of harmonic oscillators. From the master equation it can be seen explicitly that the process involves decoherence or dephasing without any dissipation of energy. We work out the decoherence-causing term in the high- and zero-temperature limits and check that they match with known results for the case of a thermal bath. The decay of the coherence is quantified as well by the dynamics of the linear entropy of the system under various environmental conditions. We make a comparison of the quantum statistical properties between QND and dissipative types of evolution using a two-level atomic system and a harmonic oscillator.
Pseudomode approaches allow for an exact and unapproximated description of a quantum system interacting arbitrarily strongly with a bath. In general, a system coupled to pseudomodes will not thermalize to the system's Gibbs state: This is to be expected when the system-bath coupling is non-perturbative, but conflicts with common thermodynamic intuition when the system-bath coupling is asymptotically weak. We explore under which circumstances pseudomode models satisfy detailed balance (and subsequently thermalize to the system Gibbs state) and how specific choices of parameters can force "weak" detailed balance that is restricted to a limited frequency range. A combination of Hermitian and non-Hermitian pseudomodes that yields a flat effective-temperature profile is also considered. The results and criteria established here are relevant for the construction of pseudomode models in contexts where thermodynamic consistency is required.
We use a canonical quantization procedure to set up a quantum Fokker-Planck-Kramers equation that accounts for quantum dissipation in a thermal environment. The dissipation term is chosen to ensure that the thermodynamic equilibrium is described by the Gibbs state. An expression for the quantum entropy production that properly describes quantum systems in a nonequilibrium stationary state is also provided. The time-dependent solution is given for a quantum harmonic oscillator in contact with a heat bath. We also obtain the stationary solution for a system of two coupled harmonic oscillators in contact with reservoirs at distinct temperatures, from which we obtain the entropy production and the quantum thermal conductance.
The Brownian motion of a quantum particle in a harmonic confining potential and coupled to harmonic quantum thermal bath is exactly solvable. Though this system presents at high temperatures a pedagogic example to explain the laws of thermodynamics, it is shown that at low enough temperatures the stationary state is non-Gibbsian due to an entanglement with the bath. In physical terms, this happens when the cloud of bath modes around the particle starts to play a nontrivial role, namely, when the bath temperature T is smaller than the coupling energy. Indeed, equilibrium thermodynamics of the total system, particle plus bath, does not imply standard equilibrium thermodynamics for the particle itself at low T. Various formulations of the second law are found to be invalid at low T. First, the Clausius inequality can be violated, because heat can be extracted from the zero point energy of the cloud of bath modes. Second, when the width of the confining potential is suddenly changed, there occurs a relaxation to equilibrium during which the entropy production is partly negative. In this process the energy put on the particle does not relax monotonically, but oscillates between particle and bath, even in the limit of strong damping. Third, for nonadiabatic changes of system parameters the rate of energy dissipation can be negative, and, out of equilibrium, cyclic processes are possible which extract work from the bath. Conditions are put forward under which perpetuum mobility of the second kind, having one or several work extraction cycles, enter the realm of condensed matter physics. Fourth, it follows that the equivalence between different formulations of the second law (e.g., those by Clausius and Thomson) can be violated at low temperatures. These effects are the consequence of quantum entanglement in the presence of the slightly off-equilibrium nature of the thermal bath, and become important when the characteristic quantum time scale variant Planck's over 2pi /k(B)T is larger than or comparable to other time scales of the system. They show that there is no general consensus between standard thermodynamics and quantum mechanics. The known agreements occur only due to the weak coupling limit, which does not pertain to low temperatures. Experimental setups for testing the effects are discussed.
The emergence of classical behavior and the origin of thermal equilibrium are two central problems in the foundations of physics. In the standard accounts, both phenomena are typically explained through interactions with an external environment: decoherence suppresses quantum interference, while coupling to a thermal bath drives relaxation toward equilibrium. Over the last decades, however, it has become clear that equilibration and thermalization can arise even in fully isolated quantum systems, in the operational sense that the expectation values of relevant observables remain close to equilibrium values for most of the time. Here, we ask whether the same intrinsic equilibration mechanism can also account for the emergence of classical behavior. Using rigorous bounds on equilibration in closed systems, we derive sufficient conditions under which a time-evolved pure state becomes, for most times, operationally indistinguishable from a classical mixture associated with a chosen physical property. We identify two complementary routes to such operational classicality: either the chosen property almost commutes with the system Hamiltonian or the observables used to probe the system lose access to the remaining coherence after equilibration. Our results show that classical behavior need not be confined to the energy basis and may emerge even when substantial coherence remains present in the equilibrium state. This establishes a direct connection between two foundational questions: the origin of thermalization in isolated quantum systems and the quantum-to-classical transition